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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide —— C18H31N5O2S
    (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide
    —— (2R)-N-cyclohexyl-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C21H30N4OS2
    (2R)-N-cyclohexyl-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C21H31N5O2S
    (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide —— C18H31N5O2S
    (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexylpropanamide
    —— 4-(2,3-dihydro-1H-inden-5-ylsulfanyl)thieno[2,3-d]pyrimidine —— C15H12N2S2
    4-(2,3-dihydro-1H-inden-5-ylsulfanyl)thieno[2,3-d]pyrimidine
    —— 2-(2,3-dihydro-1H-inden-5-ylsulfanyl)-3-nitropyridine —— C14H12N2O2S
    2-(2,3-dihydro-1H-inden-5-ylsulfanyl)-3-nitropyridine
    —— (2S)-N-cyclohexyl-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C21H30N4OS2
    (2S)-N-cyclohexyl-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— [2-[[(1S)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C17H18BrNO4S
    [2-[[(1S)-1-(furan-2-yl)ethyl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzylpropanamide —— C19H27N5O2S
    (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzylpropanamide
    —— [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C17H14BrNO4S
    [5-(Furan-2-yl)-1,2-oxazol-3-yl]methyl 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide —— C21H31N5O2S
    (2R)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide
    —— 3-[4-(2-methylpropyl)-5-[2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C21H31N5O2S
    3-[4-(2-methylpropyl)-5-[2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 2-phenyl-5-[(1S)-1-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,3,4-oxadiazole —— C25H23N5OS2
    2-phenyl-5-[(1S)-1-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,3,4-oxadiazole
    —— 4,5,6-Trimethyl-2-(4-methylsulfonyl-2-nitrophenyl)sulfanylpyridine-3-carbonitrile —— C16H15N3O4S2
    4,5,6-Trimethyl-2-(4-methylsulfonyl-2-nitrophenyl)sulfanylpyridine-3-carbonitrile
    —— 2-phenyl-5-[(1R)-1-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,3,4-oxadiazole —— C25H23N5OS2
    2-phenyl-5-[(1R)-1-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,3,4-oxadiazole
    —— 2-[[5-(2-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C13H14N4O3S3
    2-[[5-(2-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-(2,4-Dinitrophenyl)sulfanyl-4,5,6-trimethylpyridine-3-carbonitrile —— C15H12N4O4S
    2-(2,4-Dinitrophenyl)sulfanyl-4,5,6-trimethylpyridine-3-carbonitrile
    —— 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C22H35N5OS2
    2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 4-(3-Chloro-4-fluorophenyl)sulfanylthieno[2,3-d]pyrimidine —— C12H6ClFN2S2
    4-(3-Chloro-4-fluorophenyl)sulfanylthieno[2,3-d]pyrimidine
    —— 2-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C17H14N4OS3
    2-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(7-Thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H11N5OS4
    2-[[5-(7-Thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-(3,5-Dimethoxyphenyl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C19H18N4O3S2
    2-(3,5-Dimethoxyphenyl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C15H17N5OS4
    2-[[5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— 2-[[5-(2-Chloro-4-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C10H7ClN4O3S3
    2-[[5-(2-Chloro-4-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole —— C18H21N5OS2
    2-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole
    —— 5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C13H13N5S3
    5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(2-Methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile —— C12H11N5O3S2
    2-[[5-(2-Methoxyethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile
    —— 2-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C14H14N4OS3
    2-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— [(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl] 3-(3,4-dimethylphenyl)sulfanylpropanoate —— C21H22N2O3S
    [(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl] 3-(3,4-dimethylphenyl)sulfanylpropanoate
    —— 2-Cyclohexyl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C14H14N4OS2
    2-Cyclohexyl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— N-(2-methoxyethyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C16H19N5OS3
    N-(2-methoxyethyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— [5,6-Dimethyl-4-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]thieno[2,3-d]pyrimidin-2-yl]methyl-diethylazanium —— C18H25N6S3+
    [5,6-Dimethyl-4-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]thieno[2,3-d]pyrimidin-2-yl]methyl-diethylazanium
    —— 2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C22H35N5OS2
    2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 2-[5,6-Dimethyl-3-(2-methylpropyl)-4-oxothieno[2,3-d]pyrimidin-2-yl]sulfanyl-5-nitrobenzonitrile —— C19H18N4O3S2
    2-[5,6-Dimethyl-3-(2-methylpropyl)-4-oxothieno[2,3-d]pyrimidin-2-yl]sulfanyl-5-nitrobenzonitrile
    —— 5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C16H17N5S3
    5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 5-(2-nitrophenyl)sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C11H10N4O2S2
    5-(2-nitrophenyl)sulfanyl-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— 2-[5-(4-Methylphenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazole —— C20H20N5OS2+
    2-[5-(4-Methylphenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazole
    —— 2-[5-(4-Methylphenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole —— C20H19N5OS2
    2-[5-(4-Methylphenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-(pyrrolidin-1-ylmethyl)-1,3,4-oxadiazole
    —— 2-(4-Chloro-2-nitrophenyl)sulfanyl-5-(2-methylpropylsulfanyl)-1,3,4-thiadiazole —— C12H12ClN3O2S3
    2-(4-Chloro-2-nitrophenyl)sulfanyl-5-(2-methylpropylsulfanyl)-1,3,4-thiadiazole
    —— 1-[[5-[(10-Methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one —— C17H17N5O2S2
    1-[[5-[(10-Methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazol-2-yl]methyl]pyrrolidin-2-one
    —— 2-(3,5-Dimethoxyphenyl)-5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C18H16N4O3S2
    2-(3,5-Dimethoxyphenyl)-5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-Cyclohexyl-5-[5-(4-fluorophenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-1,3,4-oxadiazole —— C20H17FN4OS2
    2-Cyclohexyl-5-[5-(4-fluorophenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-1,3,4-oxadiazole
    —— 2-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-5-(2-nitrophenyl)sulfanyl-1,3,4-oxadiazole —— C17H15N3O3S2
    2-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-5-(2-nitrophenyl)sulfanyl-1,3,4-oxadiazole
    —— 2-(4-Chloro-2-nitrophenyl)sulfanyl-5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazole —— C13H14ClN4O3S+
    2-(4-Chloro-2-nitrophenyl)sulfanyl-5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(4-methylphenyl)-1,3,4-oxadiazole —— C15H10ClN3O3S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— 3-[[5-Benzyl-4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-5-phenyl-1,2-oxazole —— C22H22N4O2S
    3-[[5-Benzyl-4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-5-phenyl-1,2-oxazole
    —— 2-(2,4-Dinitrophenyl)sulfanyl-5-(2-methylphenyl)-1,3,4-oxadiazole —— C15H10N4O5S
    2-(2,4-Dinitrophenyl)sulfanyl-5-(2-methylphenyl)-1,3,4-oxadiazole
    —— 2-(4-Chloro-2-nitrophenyl)sulfanyl-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole —— C16H12ClN3O3S
    2-(4-Chloro-2-nitrophenyl)sulfanyl-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole
    —— 2-(Pyrrolidin-1-ium-1-ylmethyl)-5-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)-1,3,4-oxadiazole —— C17H20N5OS2+
    2-(Pyrrolidin-1-ium-1-ylmethyl)-5-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(2-methylphenyl)-1,3,4-oxadiazole —— C17H14N4OS2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(2-methylphenyl)-1,3,4-oxadiazole