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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C19H21FN4OS2
    (2S)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-prop-2-enyl-N-(thiophen-2-ylmethyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H16N4OS3
    N-prop-2-enyl-N-(thiophen-2-ylmethyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile —— C23H20N4S2
    (2S)-2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C14H15F4N5OS
    (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-[[5-[2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C17H14ClN3O3S2
    N-[[5-[2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H21N3O3S
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C19H17ClFN3O2S
    (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— 2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C16H21N3O3S
    2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide —— C21H22FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-3-methyl-1-phenylbutyl]acetamide
    —— [2-[5-(Acetamidomethyl)thiophen-2-yl]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C18H18ClNO4S2
    [2-[5-(Acetamidomethyl)thiophen-2-yl]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C13H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— N-[[5-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C17H15N3O3S2
    N-[[5-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C19H18N4S2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C20H21FN4OS2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C18H22N2O2S
    N-[(1S)-3-methyl-1-phenylbutyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 2,2-dimethyl-N-[[5-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]thiophen-2-yl]methyl]propanamide —— C17H20N2O3S2
    2,2-dimethyl-N-[[5-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]thiophen-2-yl]methyl]propanamide
    —— 6-Amino-1-benzyl-3-ethyl-5-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]pyrimidine-2,4-dione —— C20H20N4O4S
    6-Amino-1-benzyl-3-ethyl-5-[2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetyl]pyrimidine-2,4-dione
    —— 6-Amino-1-benzyl-3-ethyl-5-(2-pyrimidin-2-ylsulfanylacetyl)pyrimidine-2,4-dione —— C19H19N5O3S
    6-Amino-1-benzyl-3-ethyl-5-(2-pyrimidin-2-ylsulfanylacetyl)pyrimidine-2,4-dione
    —— (2R)-2-[decyl(methyl)amino]propanethioamide —— C14H30N2S
    (2R)-2-[decyl(methyl)amino]propanethioamide
    —— (1'S,5'S)-N-(1-adamantyl)spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-carboxamide —— C21H31NOS2
    (1'S,5'S)-N-(1-adamantyl)spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-carboxamide
    —— (1'R,5'R)-N-(1-adamantyl)spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-carboxamide —— C21H31NOS2
    (1'R,5'R)-N-(1-adamantyl)spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-carboxamide
    —— 2,2-dimethyl-N-[[5-(2-pyrimidin-2-ylsulfanylacetyl)thiophen-2-yl]methyl]propanamide —— C16H19N3O2S2
    2,2-dimethyl-N-[[5-(2-pyrimidin-2-ylsulfanylacetyl)thiophen-2-yl]methyl]propanamide
    —— (6E)-6-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-2-heptyl-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C23H23ClN4O2S2
    (6E)-6-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-2-heptyl-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (2S)-2-[decyl(methyl)amino]propanethioamide —— C14H30N2S
    (2S)-2-[decyl(methyl)amino]propanethioamide
    —— (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C13H15FN4OS2
    (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile —— C12H12N4S2
    (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C13H15FN4OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (1R,5R)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-9-oxobicyclo[3.3.1]nonane-3-carboxamide —— C24H27NO2S
    (1R,5R)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-9-oxobicyclo[3.3.1]nonane-3-carboxamide
    —— (1S,5S)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-9-oxobicyclo[3.3.1]nonane-3-carboxamide —— C24H27NO2S
    (1S,5S)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-9-oxobicyclo[3.3.1]nonane-3-carboxamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(cyclohexen-1-yl)-N-ethylacetamide —— C12H18N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(cyclohexen-1-yl)-N-ethylacetamide
    —— 2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C18H18N2O2S3
    2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 1-(5-Ethylthiophen-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C13H15N3OS3
    1-(5-Ethylthiophen-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (5Z)-2-amino-5-[(5-phenylsulfanylfuran-2-yl)methylidene]-1,3-thiazol-4-one —— C14H10N2O2S2
    (5Z)-2-amino-5-[(5-phenylsulfanylfuran-2-yl)methylidene]-1,3-thiazol-4-one
    —— 4-butyl-3-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C16H18N4O2S
    4-butyl-3-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— (5Z)-2-amino-5-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-1,3-thiazol-4-one —— C14H8BrClN2O2S2
    (5Z)-2-amino-5-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-1,3-thiazol-4-one
    —— 4-butyl-3-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C19H24N4O2S
    4-butyl-3-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C15H19N3O2S3
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— methyl 2,4-dimethyl-5-[(2S)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C16H21N3O3S3
    methyl 2,4-dimethyl-5-[(2S)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-(1-adamantylmethyl)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C18H27N3OS3
    N-(1-adamantylmethyl)-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C19H29N3OS3
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1R)-1-phenylethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H19N3OS3
    N-[(1R)-1-phenylethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H16FN3OS3
    N-[(4-fluorophenyl)methyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C16H21N3OS3
    N-[2-(2-methylphenyl)ethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-phenylethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H19N3OS3
    N-[(1S)-1-phenylethyl]-2-[(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-4-(difluoromethylsulfanyl)aniline —— C15H17F2NS
    N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-4-(difluoromethylsulfanyl)aniline
    —— N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-4-(difluoromethylsulfanyl)aniline —— C15H17F2NS
    N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-4-(difluoromethylsulfanyl)aniline
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-(5-methylthiophen-2-yl)ethanone —— C16H16O3S2
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-1-(5-methylthiophen-2-yl)ethanone
    —— 2-[[5-(3,4-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C17H16N2O2S2
    2-[[5-(3,4-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 2-[[5-(3-Methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C16H14N2O2S2
    2-[[5-(3-Methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 1-(5-Methylthiophen-2-yl)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C15H15N3OS3
    1-(5-Methylthiophen-2-yl)-2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone