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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2S)-1-(4-acetylpiperazin-1-yl)-1-oxopropan-2-yl] (2S)-2,3-dihydro-1-benzothiophene-2-carboxylate —— C18H22N2O4S
    [(2S)-1-(4-acetylpiperazin-1-yl)-1-oxopropan-2-yl] (2S)-2,3-dihydro-1-benzothiophene-2-carboxylate
    —— N-[(E)-benzylideneamino]-2-(4,6-dimethoxypyrimidin-2-yl)sulfanylacetamide —— C15H16N4O3S
    N-[(E)-benzylideneamino]-2-(4,6-dimethoxypyrimidin-2-yl)sulfanylacetamide
    —— N-(1-cyanocycloheptyl)-2-[[5-(4-methylpiperidin-1-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C23H36N6O2S
    N-(1-cyanocycloheptyl)-2-[[5-(4-methylpiperidin-1-yl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-bromo-N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide —— C21H16BrN3O3S2
    3-bromo-N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide
    —— 4-([(3Z)-5-(4-Chloroanilino)-4-(4-chlorophenyl)-4,5-dihydro-3H-1,2,4-triazol-3-ylidene]amino)-6-methyl-3-(methylsulfanyl)-1,2,4-triazin-5(4H)-one —— C19H16Cl2N8OS
    4-([(3Z)-5-(4-Chloroanilino)-4-(4-chlorophenyl)-4,5-dihydro-3H-1,2,4-triazol-3-ylidene]amino)-6-methyl-3-(methylsulfanyl)-1,2,4-triazin-5(4H)-one
    —— N'-[(E)-{5-[(4,5-diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl}methylidene]pyridine-4-carbohydrazide —— C25H18N6O2S
    N'-[(E)-{5-[(4,5-diphenyl-4H-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl}methylidene]pyridine-4-carbohydrazide
    —— 3-(benzylsulfanyl)-5-[(2E)-2-(4-bromobenzylidene)hydrazinyl]-1,2-thiazole-4-carbonitrile —— C18H13BrN4S2
    3-(benzylsulfanyl)-5-[(2E)-2-(4-bromobenzylidene)hydrazinyl]-1,2-thiazole-4-carbonitrile
    —— 4-fluoro-N'-[(E)-{5-[(4-oxo-3-phenyl-3,4-dihydroquinazolin-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide —— C26H17FN4O3S
    4-fluoro-N'-[(E)-{5-[(4-oxo-3-phenyl-3,4-dihydroquinazolin-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide
    —— N'-[(E)-[4-(1,3-Benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]-3-hydroxybenzohydrazide —— C21H14N4O4S2
    N'-[(E)-[4-(1,3-Benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene]-3-hydroxybenzohydrazide
    —— (2R)-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4O2S
    (2R)-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4O2S
    (2S)-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 3-nitro-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide —— C19H11N5O6S2
    3-nitro-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide
    —— N',N''-{sulfanediylbis[furan-5,2-diyl(E)methylylidene]}bis[2-(2-bromo-4-methoxyphenoxy)acetohydrazide] —— C28H24Br2N4O8S
    N',N''-{sulfanediylbis[furan-5,2-diyl(E)methylylidene]}bis[2-(2-bromo-4-methoxyphenoxy)acetohydrazide]
    —— (2R)-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4O2S
    (2R)-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (R)-[1-[2-(4-chlorophenyl)sulfanylethyl]piperidin-4-yl]-phenylmethanol —— C20H24ClNOS
    (R)-[1-[2-(4-chlorophenyl)sulfanylethyl]piperidin-4-yl]-phenylmethanol
    —— (S)-[1-[2-(4-chlorophenyl)sulfanylethyl]piperidin-4-yl]-phenylmethanol —— C20H24ClNOS
    (S)-[1-[2-(4-chlorophenyl)sulfanylethyl]piperidin-4-yl]-phenylmethanol
    —— (2S)-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4O2S
    (2S)-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-[(3-butyl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H22N4O2S
    2-[(3-butyl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-(Phenylsulfanyl)-N'-[(E)-(pyridin-4-YL)methylidene]propanehydrazide —— C15H15N3OS
    2-(Phenylsulfanyl)-N'-[(E)-(pyridin-4-YL)methylidene]propanehydrazide
    —— 2-[(3-butyl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H22N4O2S
    2-[(3-butyl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(1S,2S)-2-(trifluoromethyl)cyclohexyl]propanamide —— C18H24F3NOS
    3-(3,4-dimethylphenyl)sulfanyl-N-[(1S,2S)-2-(trifluoromethyl)cyclohexyl]propanamide
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(1R,2S)-2-(trifluoromethyl)cyclohexyl]propanamide —— C18H24F3NOS
    3-(3,4-dimethylphenyl)sulfanyl-N-[(1R,2S)-2-(trifluoromethyl)cyclohexyl]propanamide
    —— (2S)-N-[(1S,2S)-2-methylcyclohexyl]-2-methylsulfonylpropanamide —— C11H21NO3S
    (2S)-N-[(1S,2S)-2-methylcyclohexyl]-2-methylsulfonylpropanamide
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(1S,2R)-2-(trifluoromethyl)cyclohexyl]propanamide —— C18H24F3NOS
    3-(3,4-dimethylphenyl)sulfanyl-N-[(1S,2R)-2-(trifluoromethyl)cyclohexyl]propanamide
    —— 3-(3,4-dimethylphenyl)sulfanyl-N-[(1R,2R)-2-(trifluoromethyl)cyclohexyl]propanamide —— C18H24F3NOS
    3-(3,4-dimethylphenyl)sulfanyl-N-[(1R,2R)-2-(trifluoromethyl)cyclohexyl]propanamide
    —— 3-[3-[2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazol-4-yl]propanamide —— C17H22N6O3S
    3-[3-[2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazol-4-yl]propanamide
    —— 3-[3-[2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazol-4-yl]propanamide —— C17H22N6O3S
    3-[3-[2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl]sulfanyl-5-(furan-2-yl)-1,2,4-triazol-4-yl]propanamide
    —— N-(2-ethyl-6-methylphenyl)-5-[(1R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C16H19N5OS2
    N-(2-ethyl-6-methylphenyl)-5-[(1R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— (1R)-5-methoxy-1-methyl-3-methylsulfanyl-1-oxo-1λ6-thia-2-azacyclohexa-1,3,5-triene-4-carbonitrile —— C8H10N2O2S2
    (1R)-5-methoxy-1-methyl-3-methylsulfanyl-1-oxo-1λ6-thia-2-azacyclohexa-1,3,5-triene-4-carbonitrile
    —— N-(2-ethyl-6-methylphenyl)-5-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C16H19N5OS2
    N-(2-ethyl-6-methylphenyl)-5-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 7-tert-butyl-1,3-dimethyl-5-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C17H22N6O3S
    7-tert-butyl-1,3-dimethyl-5-[(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 5-[(1S)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C20H26N6OS
    5-[(1S)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C20H26N6OS
    5-[(1R)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— (2E,5E)-2-[2-(furan-2-yl)-2-oxoethylidene]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C17H13NO3S2
    (2E,5E)-2-[2-(furan-2-yl)-2-oxoethylidene]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— 5-[(1S)-1-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C20H17N5OS
    5-[(1S)-1-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C20H17N5OS
    5-[(1R)-1-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— 7-tert-butyl-1,3-dimethyl-5-[(1R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C17H22N6O3S
    7-tert-butyl-1,3-dimethyl-5-[(1R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 5-[(1R)-1-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C18H17N5O2S
    5-[(1R)-1-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— [(E)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-methylcarbamate —— C13H18N2O2S2
    [(E)-(6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)amino] N-methylcarbamate
    —— 2-(4-cyano-5-methylsulfanyl-3-thiophen-2-ylpyrazol-1-yl)-N-[(E)-thiophen-2-ylmethylideneamino]acetamide —— C16H13N5OS3
    2-(4-cyano-5-methylsulfanyl-3-thiophen-2-ylpyrazol-1-yl)-N-[(E)-thiophen-2-ylmethylideneamino]acetamide
    —— (E)-2-tert-butylsulfonyl-3-[(2E)-2-(2,2-dimethylpropylidene)hydrazinyl]prop-2-enenitrile —— C12H21N3O2S
    (E)-2-tert-butylsulfonyl-3-[(2E)-2-(2,2-dimethylpropylidene)hydrazinyl]prop-2-enenitrile
    —— (2E)-2-[(5Z)-3-ethyl-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-4,4-dimethyl-3-oxopentanenitrile —— C20H22N2O2S2
    (2E)-2-[(5Z)-3-ethyl-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-4,4-dimethyl-3-oxopentanenitrile
    —— 5-[(1S)-1-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole —— C18H17N5O2S
    5-[(1S)-1-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-methyl-1,2,4-oxadiazole
    —— [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(4-chlorophenyl)carbamate —— C13H9Cl3N4O2S
    [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(4-chlorophenyl)carbamate
    —— N,N-dimethyl-N'-(5-{[2-nitro-4-(trifluoromethyl)phenyl]thio}-1H-1,2,4-triazol-3-yl)iminoformamide —— C12H11F3N6O2S
    N,N-dimethyl-N'-(5-{[2-nitro-4-(trifluoromethyl)phenyl]thio}-1H-1,2,4-triazol-3-yl)iminoformamide
    —— N,N-dimethyl-N'-[5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide —— C12H10F3N5O2S2
    N,N-dimethyl-N'-[5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide
    —— 3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime —— C20H14Cl2N2O3S
    3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime
    —— 2-methyl-2-[(4-methylphenyl)sulfanyl]propanal O-methyloxime —— C12H17NOS
    2-methyl-2-[(4-methylphenyl)sulfanyl]propanal O-methyloxime
    —— [(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino] thiophene-2-carboxylate —— C18H10ClF3N2O2S2
    [(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino] thiophene-2-carboxylate
    —— 3-[[2-(furan-2-yl)-1,3-thiazol-4-yl]methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C15H16N4O3S2
    3-[[2-(furan-2-yl)-1,3-thiazol-4-yl]methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one