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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide —— C15H20FN5OS
    2-[(4-amino-5-tert-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(4-fluorophenyl)methyl]acetamide
    —— N-[(2R)-4-phenylbutan-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide —— C19H26N4OS
    N-[(2R)-4-phenylbutan-2-yl]-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetamide
    —— (7R)-3-cyclohexyl-6-(3,4-dimethylphenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C19H24N4S
    (7R)-3-cyclohexyl-6-(3,4-dimethylphenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— N-[(2R)-butan-2-yl]-2-(2-chlorophenyl)sulfanylpyridine-3-carboxamide —— C16H17ClN2OS
    N-[(2R)-butan-2-yl]-2-(2-chlorophenyl)sulfanylpyridine-3-carboxamide
    —— 3-Tert-butyl-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C15H18N6OS
    3-Tert-butyl-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— (7S)-3-cyclohexyl-6-(3,4-difluorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C17H18F2N4S
    (7S)-3-cyclohexyl-6-(3,4-difluorophenyl)-7-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (2R)-2-[[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C8H12N4O2S3
    (2R)-2-[[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]propanamide —— C16H22N4OS
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]propanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]acetamide —— C13H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]acetamide
    —— Methyl 3-[2,5-dimethyl-3-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]pyrrol-1-yl]propanoate —— C15H20N4O3S
    Methyl 3-[2,5-dimethyl-3-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]pyrrol-1-yl]propanoate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 3-(2-methoxyphenyl)propanoate —— C24H23NO4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 3-(2-methoxyphenyl)propanoate
    —— (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C13H22N4OS
    (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 6-Amino-5-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione —— C12H16N6O3S
    6-Amino-5-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione
    —— N-[(3-chlorophenyl)methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H13ClN4OS
    N-[(3-chlorophenyl)methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(2-bromophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H15BrN4OS
    N-[(1R)-1-(2-bromophenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(1-adamantyl)-N-[(4-fluorophenyl)methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C22H27FN4OS
    N-(1-adamantyl)-N-[(4-fluorophenyl)methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(3-methylphenyl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H17N3S3
    N-(3-methylphenyl)-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide —— C19H28N4OS2
    2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-bis(2-methylpropyl)acetamide
    —— 3-[[5-(3-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanenitrile —— C12H12N4S2
    3-[[5-(3-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanenitrile
    —— 2-[[5-(3-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C20H19N5OS2
    2-[[5-(3-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— N,N-bis(2-methoxyethyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H24N4O3S2
    N,N-bis(2-methoxyethyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 3-Methyl-7-{[(5-phenyl-1,3,4-oxadiazol-2-YL)sulfanyl]methyl}-5H-[1,3]thiazolo[3,2-A]pyrimidin-5-one —— C16H12N4O2S2
    3-Methyl-7-{[(5-phenyl-1,3,4-oxadiazol-2-YL)sulfanyl]methyl}-5H-[1,3]thiazolo[3,2-A]pyrimidin-5-one
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] propanoate —— C17H17NO3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] propanoate
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C20H22N4O2S
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-1-(1-adamantyl)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C17H22F3N3OS
    (2S)-1-(1-adamantyl)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— N-[(Z)-(3-bromophenyl)methylideneamino]-3-ethylsulfanyl-1H-1,2,4-triazol-5-amine —— C11H12BrN5S
    N-[(Z)-(3-bromophenyl)methylideneamino]-3-ethylsulfanyl-1H-1,2,4-triazol-5-amine
    —— 2-(3-chlorophenoxy)-N-[2-(4-chlorophenyl)sulfanylphenyl]acetamide —— C20H15Cl2NO2S
    2-(3-chlorophenoxy)-N-[2-(4-chlorophenyl)sulfanylphenyl]acetamide
    —— 3-[2-(2-fluorophenyl)sulfanylethylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H12FN3S3
    3-[2-(2-fluorophenyl)sulfanylethylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 2-(3-chlorophenoxy)-N-(2-phenylsulfanylphenyl)acetamide —— C20H16ClNO2S
    2-(3-chlorophenoxy)-N-(2-phenylsulfanylphenyl)acetamide
    —— ethyl 2-[[5-[(2Z)-2-[(3-bromophenyl)methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H14BrN5O2S
    ethyl 2-[[5-[(2Z)-2-[(3-bromophenyl)methylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-[(2S)-1-methoxypropan-2-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H16N4O2S2
    N-[(2S)-1-methoxypropan-2-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(Z)-benzylideneamino]-3-ethylsulfanyl-1H-1,2,4-triazol-5-amine —— C11H13N5S
    N-[(Z)-benzylideneamino]-3-ethylsulfanyl-1H-1,2,4-triazol-5-amine
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H21N5OS2
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2R)-butan-2-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H16N4OS2
    N-[(2R)-butan-2-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(Z)-benzylideneamino]-3-propylsulfanyl-1H-1,2,4-triazol-5-amine —— C12H15N5S
    N-[(Z)-benzylideneamino]-3-propylsulfanyl-1H-1,2,4-triazol-5-amine
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H16N4O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-N-benzyl-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C20H22N4OS2
    (2S)-N-benzyl-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— N-benzyl-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C16H14ClN3S2
    N-benzyl-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-benzyl-5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C16H14FN3S2
    N-benzyl-5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] propanoate —— C17H16ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] propanoate
    —— 1-[(5R)-5-hydroxy-3-methyl-5-phenyl-4H-pyrazol-1-yl]-2-[[5-[2-[(5R)-5-hydroxy-3-methyl-5-phenyl-4H-pyrazol-1-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C26H26N6O4S3
    1-[(5R)-5-hydroxy-3-methyl-5-phenyl-4H-pyrazol-1-yl]-2-[[5-[2-[(5R)-5-hydroxy-3-methyl-5-phenyl-4H-pyrazol-1-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-(2-chlorophenyl)ethyl]acetamide —— C14H16ClN5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-(2-chlorophenyl)ethyl]acetamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N,N-diethylacetamide —— C10H17N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N,N-diethylacetamide
    —— (2R)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropylpropanamide —— C9H15N5OS
    (2R)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropylpropanamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide —— C15H19N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-2-phenylpropyl]acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzyl-N-ethylacetamide —— C14H16F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-benzyl-N-ethylacetamide
    —— 3-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine —— C14H12F3N5S2
    3-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C13H14F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide —— C18H17N5O2S2
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylsulfanylphenyl)acetamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-tert-butylacetamide —— C10H17N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-tert-butylacetamide