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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C20H20ClN3O3S
    [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C19H21ClN2O3S
    [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-(2-Methylpropylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C19H22N2O3S
    [2-(2-Methylpropylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(Butylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C19H22N2O3S
    [2-(Butylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— (2-Morpholin-4-yl-2-oxoethyl) 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H17ClN2O4S
    (2-Morpholin-4-yl-2-oxoethyl) 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C20H20ClN3O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— (2-Oxo-2-piperidin-1-ylethyl) 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C19H19ClN2O3S
    (2-Oxo-2-piperidin-1-ylethyl) 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2S)-1-amino-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C15H13ClN2O3S
    [(2S)-1-amino-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H17ClN2O3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H17ClN2O3S
    [(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C20H21ClN2O4S
    [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-(2-Methoxyethylamino)-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C17H17ClN2O4S
    [2-(2-Methoxyethylamino)-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-(Tert-butylamino)-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H19ClN2O3S
    [2-(Tert-butylamino)-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C20H18ClN3O3S
    [2-[(1-Cyanocyclopentyl)amino]-2-oxoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(1R)-1-cyanoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate —— C15H11ClN2O2S
    [(1R)-1-cyanoethyl] 2-(4-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-(Dimethylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C17H18N2O3S
    [2-(Dimethylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— (2-Benzamido-2-oxoethyl) 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C22H18N2O4S
    (2-Benzamido-2-oxoethyl) 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(1,3-Benzodioxol-5-yl)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C22H17NO5S
    [2-(1,3-Benzodioxol-5-yl)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[2-Cyanoethyl(methyl)amino]-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H16ClN3O3S
    [2-[2-Cyanoethyl(methyl)amino]-2-oxoethyl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2,3-dimethylbenzoate —— C23H21NO3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 2,3-dimethylbenzoate
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 2-thiophen-3-ylacetate —— C22H21NO3S2
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 2-thiophen-3-ylacetate
    —— 2-[(3S)-2-oxooxolan-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C11H14N2O3S
    2-[(3S)-2-oxooxolan-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-[(3R)-2-oxooxolan-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C11H14N2O3S
    2-[(3R)-2-oxooxolan-3-yl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C19H26N4O2S
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C19H25N3O2S
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C19H22ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— (2S)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]propanamide —— C20H27N3O2S
    (2S)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]propanamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-bis(2-cyanoethyl)acetamide —— C10H12N6OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-bis(2-cyanoethyl)acetamide
    —— (2R)-N-benzyl-N-methyl-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide —— C18H23N3O2S
    (2R)-N-benzyl-N-methyl-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-(2-chlorophenyl)sulfanylacetamide —— C20H26ClNOS
    N-[(1R)-1-(1-adamantyl)ethyl]-2-(2-chlorophenyl)sulfanylacetamide
    —— ethyl 5-[(2S)-2-(2-chlorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C18H20ClNO3S
    ethyl 5-[(2S)-2-(2-chlorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C15H18N4O3S3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]ethanone —— C12H13F3N4OS2
    2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]ethanone
    —— Ethyl {[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl}carbamate —— C7H10N4O3S2
    Ethyl {[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl}carbamate
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-cyanoethyl)-N-methylacetamide —— C8H11N5OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-cyanoethyl)-N-methylacetamide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C15H20N4OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— 2-[(3aR,5R,7aR)-3a,4,5,6,7,7a-hexahydro-1,3-benzodioxol-5-yl]-1,3-dithiane-2-carboxylate —— C12H17O4S2-
    2-[(3aR,5R,7aR)-3a,4,5,6,7,7a-hexahydro-1,3-benzodioxol-5-yl]-1,3-dithiane-2-carboxylate
    —— 4-[[5-(4-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one —— C17H17N3OS3
    4-[[5-(4-Methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— 5-[(4-chlorophenyl)methylsulfanyl]-N-(3,4-dimethylphenyl)-1,3,4-thiadiazol-2-amine —— C17H16ClN3S2
    5-[(4-chlorophenyl)methylsulfanyl]-N-(3,4-dimethylphenyl)-1,3,4-thiadiazol-2-amine
    —— 5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine —— C17H16ClN3S2
    5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— 5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C17H16FN3S2
    5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-(3,4-dimethylphenyl)-5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-amine —— C14H19N3S2
    N-(3,4-dimethylphenyl)-5-(2-methylpropylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (2R)-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C15H17N3OS2
    (2R)-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2S)-N-benzyl-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C21H24N4OS2
    (2S)-N-benzyl-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H26N4OS2
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-[(2S)-1-methoxypropan-2-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H20N4O2S2
    N-[(2S)-1-methoxypropan-2-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C19H26N4OS2
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— N-[2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide —— C18H19N5O2S2
    N-[2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide
    —— Tert-butyl 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H21N3O2S2
    Tert-butyl 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— 5-[(4-chlorophenyl)methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine —— C16H14ClN3S2
    5-[(4-chlorophenyl)methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine