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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(R)-phenyl(thiophen-2-yl)methyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C19H15N3O2S3
    N-[(R)-phenyl(thiophen-2-yl)methyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(furan-2-yl)ethyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C14H13N3O3S2
    N-[(1S)-1-(furan-2-yl)ethyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(2S)-5-methylhexan-2-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C15H21N3O2S2
    N-[(2S)-5-methylhexan-2-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N,N-dimethylpropanamide —— C12H13N5OS
    (2R)-2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N,N-dimethylpropanamide
    —— [5-[4-[(1S)-1-hydroxyethyl]phenyl]furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium —— C17H22N5O2S+
    [5-[4-[(1S)-1-hydroxyethyl]phenyl]furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium
    —— (2R)-2-[[4-amino-5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C13H24N6O2S2
    (2R)-2-[[4-amino-5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— N-[4-[4-chloro-6-[(5-methyl-4H-pyrazol-3-yl)amino]pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide —— C18H17ClN6OS
    N-[4-[4-chloro-6-[(5-methyl-4H-pyrazol-3-yl)amino]pyrimidin-2-yl]sulfanylphenyl]cyclopropanecarboxamide
    —— N'-acetyl-2-(3,4-dimethylphenyl)sulfanylacetohydrazide —— C12H16N2O2S
    N'-acetyl-2-(3,4-dimethylphenyl)sulfanylacetohydrazide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(3,4-dimethylphenyl)sulfanylacetamide —— C16H20N2OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(3,4-dimethylphenyl)sulfanylacetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(furan-2-ylmethyl)-N-methylacetamide —— C10H12N4O2S2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(furan-2-ylmethyl)-N-methylacetamide
    —— 5-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-1,3,4-thiadiazol-2-amine —— C12H9ClN4S3
    5-({[2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-1,3,4-thiadiazol-2-amine
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]ethanone —— C18H17N5O2S2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]ethanone
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(4-chlorophenyl)methyl]-N-methylacetamide —— C12H13ClN4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(4-chlorophenyl)methyl]-N-methylacetamide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]cyclohexan-1-one —— C8H11N3OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]cyclohexan-1-one
    —— (2R)-2-(3,4-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H22FNOS
    (2R)-2-(3,4-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— 2-(2,4-difluorophenyl)sulfanyl-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide —— C19H15F2NOS2
    2-(2,4-difluorophenyl)sulfanyl-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide
    —— (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]propan-1-one —— C16H18N4O2S2
    (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]propan-1-one
    —— (2R)-N-(1-adamantyl)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C15H22N4OS2
    (2R)-N-(1-adamantyl)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-butyl-N-ethyl-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H21FN4OS2
    N-butyl-N-ethyl-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide —— C12H20N4OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide
    —— N-[(1S)-1-cyclopropylethyl]-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17FN4OS2
    N-[(1S)-1-cyclopropylethyl]-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-5-nitro-2-oxopyridine-3-carbonitrile —— C14H10ClN3O3S
    1-[2-(4-Chlorophenyl)sulfanylethyl]-5-nitro-2-oxopyridine-3-carbonitrile
    —— N-(1-adamantyl)-N-(2-cyanoethyl)-2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H27N5OS2
    N-(1-adamantyl)-N-(2-cyanoethyl)-2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C16H24N4OS2
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]propanamide —— C12H20N4OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]propanamide
    —— N-[(4-ethylphenyl)methyl]-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide —— C20H21FN4OS2
    N-[(4-ethylphenyl)methyl]-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dipropylacetamide —— C16H21FN4OS2
    2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dipropylacetamide
    —— 2-(3-cyano-5-nitro-2-oxopyridin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide —— C20H14N4O4S
    2-(3-cyano-5-nitro-2-oxopyridin-1-yl)-N-(2-phenylsulfanylphenyl)acetamide
    —— (2S)-1-methylsulfonyldodecan-2-ol —— C13H28O3S
    (2S)-1-methylsulfonyldodecan-2-ol
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(2-bromophenyl)ethyl]acetamide —— C12H13BrN4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(2-bromophenyl)ethyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C10H12N4OS3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— 2-[(5-cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)acetamide —— C16H26N4O4S2
    2-[(5-cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]acetamide —— C12H18N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]acetamide
    —— 3-(2-chloroprop-2-enylsulfanyl)-4-propyl-1H-1,2,4-triazol-5-one —— C8H12ClN3OS
    3-(2-chloroprop-2-enylsulfanyl)-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-(2-oxopropylsulfanyl)-4-propyl-1H-1,2,4-triazol-5-one —— C8H13N3O2S
    3-(2-oxopropylsulfanyl)-4-propyl-1H-1,2,4-triazol-5-one
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19ClN4O2S
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-N-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19FN4O2S
    N-[(4-fluorophenyl)methyl]-N-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H26N4O4S2
    N-[(2R)-butan-2-yl]-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[4-amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C14H17N7OS2
    2-[[4-amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— 2-[[4-amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide —— C17H27N7OS
    2-[[4-amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-methyl-N-(4-methylcyclohexyl)acetamide
    —— 3-[(5-Cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(furan-2-yl)-1,2-oxazole —— C15H16N4O2S
    3-[(5-Cyclopropyl-4-ethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-(furan-2-yl)-1,2-oxazole
    —— 2-[[4-amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethanone —— C20H23N7OS
    2-[[4-amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethanone
    —— 3-(2-methylsulfanylethylsulfanyl)-4-propyl-1H-1,2,4-triazol-5-one —— C8H15N3OS2
    3-(2-methylsulfanylethylsulfanyl)-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C10H17N3O3S
    3-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] (E)-3-phenylsulfanylprop-2-enoate —— C16H19NO5S2
    [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]amino]-1-oxopropan-2-yl] (E)-3-phenylsulfanylprop-2-enoate
    —— 3-[[2-(3-bromophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C15H15BrN4OS2
    3-[[2-(3-bromophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— ethyl 2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetate —— C9H15N3O3S
    ethyl 2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetate
    —— 2-[[4-Amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-(azocan-1-yl)ethanone —— C16H25N7OS
    2-[[4-Amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-(azocan-1-yl)ethanone
    —— 2-[[4-Amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C18H20N8OS
    2-[[4-Amino-5-(3,5-dimethylpyrazol-1-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— (2S)-N-ethyl-1-methylsulfonyldecan-2-amine —— C13H29NO2S
    (2S)-N-ethyl-1-methylsulfonyldecan-2-amine