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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(2-amino-2-oxoethyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C12H14N4O2S4
    (2S)-2-[[5-(2-amino-2-oxoethyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2R)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-phenylethyl)propanamide —— C24H31N5O3S
    (2R)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-phenylethyl)propanamide
    —— [(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H24FNO3S
    [(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— (2S)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(thiophen-2-ylmethyl)propanamide —— C21H27N5O3S2
    (2S)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(thiophen-2-ylmethyl)propanamide
    —— 3-[2-(2-amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]-N-[(3-chlorophenyl)methyl]propanamide —— C18H21ClN4O2S
    3-[2-(2-amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]-N-[(3-chlorophenyl)methyl]propanamide
    —— (2R)-2-[[5-(2-amino-2-oxoethyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C12H14N4O2S4
    (2R)-2-[[5-(2-amino-2-oxoethyl)sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-methylpropyl)propanamide —— C20H31N5O3S
    (2S)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-methylpropyl)propanamide
    —— [(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl] 2-(4-bromophenyl)sulfanylacetate —— C17H22BrNO3S
    [(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl] 2-(4-bromophenyl)sulfanylacetate
    —— [(2R)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate —— C18H24FNO3S
    [(2R)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— (2R)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-methylpropyl)propanamide —— C20H31N5O3S
    (2R)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-(2-methylpropyl)propanamide
    —— (2S)-1-(azepan-1-yl)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C19H26N4OS
    (2S)-1-(azepan-1-yl)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2S)-1-(azepan-1-yl)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H24N4OS2
    (2S)-1-(azepan-1-yl)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2R)-2-(3-cyanophenoxy)-N-(2-phenylsulfanylphenyl)propanamide —— C22H18N2O2S
    (2R)-2-(3-cyanophenoxy)-N-(2-phenylsulfanylphenyl)propanamide
    —— N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C15H22N2O3S3
    N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2S)-2-(3-cyanophenoxy)-N-(2-phenylsulfanylphenyl)propanamide —— C22H18N2O2S
    (2S)-2-(3-cyanophenoxy)-N-(2-phenylsulfanylphenyl)propanamide
    —— 3-[2-(2-amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]-N-prop-2-enylpropanamide —— C14H20N4O2S
    3-[2-(2-amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]-N-prop-2-enylpropanamide
    —— 2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[5-[(1R,2R)-2-methylcyclopropyl]furan-2-yl]methylideneamino]acetamide —— C16H19N5O4S
    2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[5-[(1R,2R)-2-methylcyclopropyl]furan-2-yl]methylideneamino]acetamide
    —— N-[(Z)-[5-[(1R,2S)-2-methylcyclopropyl]furan-2-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C18H20N2O2S
    N-[(Z)-[5-[(1R,2S)-2-methylcyclopropyl]furan-2-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— [(2S)-1-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C17H23NO5S2
    [(2S)-1-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [(2R)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C17H23NO5S2
    [(2R)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [(2R)-1-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C17H23NO5S2
    [(2R)-1-[[(3S)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [(2R)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(2-chlorophenyl)sulfanylpropanoate —— C18H24ClNO3S
    [(2R)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(2-chlorophenyl)sulfanylpropanoate
    —— 2-(2-fluorophenyl)sulfanyl-N-[(Z)-[5-[(1S,2R)-2-methylcyclopropyl]furan-2-yl]methylideneamino]acetamide —— C17H17FN2O2S
    2-(2-fluorophenyl)sulfanyl-N-[(Z)-[5-[(1S,2R)-2-methylcyclopropyl]furan-2-yl]methylideneamino]acetamide
    —— [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C17H23NO5S2
    [(2S)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(2-chlorophenyl)sulfanylpropanoate —— C18H24ClNO3S
    [(2S)-1-(azepan-1-yl)-1-oxopropan-2-yl] 3-(2-chlorophenyl)sulfanylpropanoate
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[5-[(1S,2R)-2-methylcyclopropyl]furan-2-yl]methanimine —— C18H17ClN4OS
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[5-[(1S,2R)-2-methylcyclopropyl]furan-2-yl]methanimine
    —— 3-(4-fluorophenyl)sulfanyl-N-[(Z)-[5-[(1R,2R)-2-methylcyclopropyl]furan-2-yl]methylideneamino]propanamide —— C18H19FN2O2S
    3-(4-fluorophenyl)sulfanyl-N-[(Z)-[5-[(1R,2R)-2-methylcyclopropyl]furan-2-yl]methylideneamino]propanamide
    —— 3-(3,4-dimethylphenyl)sulfanyl-N'-[2-[(3S)-1,1-dioxothiolan-3-yl]acetyl]propanehydrazide —— C17H24N2O4S2
    3-(3,4-dimethylphenyl)sulfanyl-N'-[2-[(3S)-1,1-dioxothiolan-3-yl]acetyl]propanehydrazide
    —— [(2S)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C16H22BrNO3S
    [(2S)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— [(2R)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C16H22BrNO3S
    [(2R)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— N'-[2-[(3R)-1,1-dioxothiolan-3-yl]acetyl]-3-phenylsulfanylpropanehydrazide —— C15H20N2O4S2
    N'-[2-[(3R)-1,1-dioxothiolan-3-yl]acetyl]-3-phenylsulfanylpropanehydrazide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N'-[2-[(3R)-1,1-dioxothiolan-3-yl]acetyl]pyridine-3-carbohydrazide —— C20H23N3O4S2
    2-(2,4-dimethylphenyl)sulfanyl-N'-[2-[(3R)-1,1-dioxothiolan-3-yl]acetyl]pyridine-3-carbohydrazide
    —— 3-[4-[(Z)-N-[[2-(4-chlorophenyl)sulfanylacetyl]amino]-C-methylcarbonimidoyl]-5-methylfuran-2-yl]propanoate —— C18H18ClN2O4S-
    3-[4-[(Z)-N-[[2-(4-chlorophenyl)sulfanylacetyl]amino]-C-methylcarbonimidoyl]-5-methylfuran-2-yl]propanoate
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide —— C18H15ClFN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide
    —— (3S)-3-[4-methyl-5-[[(2S)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C16H29N4O3S2+
    (3S)-3-[4-methyl-5-[[(2S)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— (2S)-2-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)propanamide —— C13H22N4O4S2
    (2S)-2-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)propanamide
    —— 1-[2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]pyrrolidin-2-one —— C13H18N4O4S2
    1-[2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]pyrrolidin-2-one
    —— 4-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylbutan-1-one —— C15H24N4O4S2
    4-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylbutan-1-one
    —— (3S)-3-[4-methyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C12H16N4O2S3
    (3S)-3-[4-methyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 1-(2,5-dimethylthiophen-3-yl)-2-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C15H19N3O3S3
    1-(2,5-dimethylthiophen-3-yl)-2-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 4-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile —— C11H16N4O2S2
    4-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile
    —— (3R)-3-[4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C13H22N4O2S2
    (3R)-3-[4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— (3S)-3-[4-methyl-5-[2-[(2S)-1-methylpiperidin-1-ium-2-yl]ethylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H27N4O2S2+
    (3S)-3-[4-methyl-5-[2-[(2S)-1-methylpiperidin-1-ium-2-yl]ethylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— (2S)-2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)propanamide —— C13H22N4O4S2
    (2S)-2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)propanamide
    —— 3-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C10H14N4O2S2
    3-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— (2S)-2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C12H20N4O3S2
    (2S)-2-[[5-[(3R)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (3S)-3-[5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]thiolane 1,1-dioxide —— C11H13N3O3S3
    (3S)-3-[5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]thiolane 1,1-dioxide
    —— 2-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C14H22N4O4S2
    2-[[5-[(3S)-1,1-dioxothiolan-3-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— (3S)-3-[5-(methoxymethylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C9H15N3O3S2
    (3S)-3-[5-(methoxymethylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— (3R)-3-[4-methyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C12H16N4O2S3
    (3R)-3-[4-methyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]thiolane 1,1-dioxide