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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N,N-dimethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H17N3O2S
    (2S)-N,N-dimethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— [(1R)-2-(2-chloro-4-nitroanilino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C28H18ClN3O5S
    [(1R)-2-(2-chloro-4-nitroanilino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— [(1S)-2-(2-chloro-4-nitroanilino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C28H18ClN3O5S
    [(1S)-2-(2-chloro-4-nitroanilino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— 3-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazol-4-amine —— C16H15ClN4O3S
    3-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-5-(furan-2-yl)-1,2,4-triazol-4-amine
    —— (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C13H14BrN3O2S
    (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— 2-(4-fluorophenyl)-5-[(1R)-1-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole —— C19H15FN4O2S
    2-(4-fluorophenyl)-5-[(1R)-1-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1,3,4-oxadiazole
    —— [2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C29H20ClN3O4S
    [2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— 2-(furan-2-yl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole —— C17H14N4O3S
    2-(furan-2-yl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-oxadiazole
    —— (2R)-N,N-dimethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H17N3O2S
    (2R)-N,N-dimethyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-cyclopentyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H21N3O5S2
    N-cyclopentyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-1-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ylpropan-2-ol —— C17H24N4O2S2
    (2R)-1-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-morpholin-4-ylpropan-2-ol
    —— (2S)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ylpropan-2-ol —— C15H20N4O2S2
    (2S)-1-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-morpholin-4-ylpropan-2-ol
    —— 2-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C18H14ClFN2O3S
    2-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— N-phenyl-5-(2-pyridin-4-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C15H14N4S2
    N-phenyl-5-(2-pyridin-4-ylethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (2S)-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C11H14N4OS2
    (2S)-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide —— C15H20N4OS
    (2R)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-ethylpropanamide
    —— (2R)-N-cycloheptyl-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4OS
    (2R)-N-cycloheptyl-2-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-(4-methylphenyl)-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C17H15N5OS2
    2-(4-methylphenyl)-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— 3-[5-[2-(2-Fluorophenyl)sulfanylethylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]propanamide —— C14H17FN4OS2
    3-[5-[2-(2-Fluorophenyl)sulfanylethylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[Cyclohexen-1-yl(cyclopropyl)amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C17H25N5O2S
    3-[5-[2-[Cyclohexen-1-yl(cyclopropyl)amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide —— C20H21ClN4O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide
    —— 3-[4-Methyl-5-[2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C12H17N5O3S
    3-[4-Methyl-5-[2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]propanamide —— C16H19ClN4O3S
    3-[5-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— (2R)-2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]propanamide —— C19H27N5O2S
    (2R)-2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]propanamide
    —— 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[3-(N-methylanilino)propyl]acetamide —— C20H21ClN4O2S
    2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[3-(N-methylanilino)propyl]acetamide
    —— 3-[4-Methyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propanamide —— C10H14N6O2S
    3-[4-Methyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-methyl-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]propanamide —— C11H18N4O2S
    3-[4-methyl-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[Cyclohexen-1-yl(ethyl)amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C16H25N5O2S
    3-[5-[2-[Cyclohexen-1-yl(ethyl)amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— (2S)-2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide —— C17H27N5O2S
    (2S)-2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(cyclohexen-1-yl)ethyl]propanamide
    —— [2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C29H23ClN2O4S
    [2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[5-[2-[[(1S)-1-(2-chlorophenyl)ethyl]amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C16H20ClN5O2S
    3-[5-[2-[[(1S)-1-(2-chlorophenyl)ethyl]amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-methyl-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C17H20N6O2S
    3-[4-methyl-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— (2R)-2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]propanamide —— C15H24N6O2S
    (2R)-2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]propanamide
    —— [2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C29H23ClN2O4S
    [2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[5-[(1S)-1-cyanoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C9H13N5OS
    3-[5-[(1S)-1-cyanoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-Methyl-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propanamide —— C14H18N4OS2
    3-[4-Methyl-5-[(4-methylsulfanylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-methyl-5-[2-oxo-2-[[(2R)-4-phenylbutan-2-yl]amino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C18H25N5O2S
    3-[4-methyl-5-[2-oxo-2-[[(2R)-4-phenylbutan-2-yl]amino]ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-methyl-5-[2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C15H25N5O2S
    3-[4-methyl-5-[2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— 5-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine —— C12H13N5O2S2
    5-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— 3-[4-methyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]propanamide —— C12H20N4O2S
    3-[4-methyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]propanamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide —— C14H18N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide
    —— N-[(2-bromophenyl)methyl]-N-methyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C13H15BrN4OS2
    N-[(2-bromophenyl)methyl]-N-methyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 5-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine —— C13H14ClN3O2S2
    5-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— [2-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C29H23ClN2O4S
    [2-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— 3-[4-Methyl-5-[(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propanamide —— C13H14N6O2S2
    3-[4-Methyl-5-[(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[[4-(Dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C18H26N6O2S
    3-[5-[2-[[4-(Dimethylamino)phenyl]methyl-methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-(2-Ethoxyethylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]propanamide —— C10H18N4O2S
    3-[5-(2-Ethoxyethylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C13H16N4OS3
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 1-[1-(3-Methoxypropyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C15H22N4O2S2
    1-[1-(3-Methoxypropyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— Ethyl 2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C10H16N4O3S
    Ethyl 2-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetate