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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide —— C19H17Cl2N3O2S
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— (2R)-N-[(1R)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C20H20ClNOS
    (2R)-N-[(1R)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2S)-N-[(1S)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C20H20ClNOS
    (2S)-N-[(1S)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2R)-N-[(1S)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C20H20ClNOS
    (2R)-N-[(1S)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2R)-N-[(5-bromo-2-fluorophenyl)methyl]-N-ethyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C18H17BrFNOS
    (2R)-N-[(5-bromo-2-fluorophenyl)methyl]-N-ethyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2S)-N-[(5-bromo-2-fluorophenyl)methyl]-N-ethyl-2,3-dihydro-1-benzothiophene-2-carboxamide —— C18H17BrFNOS
    (2S)-N-[(5-bromo-2-fluorophenyl)methyl]-N-ethyl-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C21H26ClN3OS
    N-[(1S)-1-(4-chlorophenyl)ethyl]-N-cyclopropyl-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— (2R)-4-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile —— C22H18N2O3S2
    (2R)-4-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile
    —— (2S)-4-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile —— C22H18N2O3S2
    (2S)-4-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-3-oxo-2-(4-phenyl-1,3-thiazol-2-yl)butanenitrile
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methanimine —— C20H24ClN5S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methanimine
    —— 1-[(2S)-4-methyl-2-morpholin-4-ylpentyl]-3-(3-phenylsulfanylpropyl)urea —— C20H33N3O2S
    1-[(2S)-4-methyl-2-morpholin-4-ylpentyl]-3-(3-phenylsulfanylpropyl)urea
    —— 1-[(2R)-4-methyl-2-morpholin-4-ylpentyl]-3-(3-phenylsulfanylpropyl)urea —— C20H33N3O2S
    1-[(2R)-4-methyl-2-morpholin-4-ylpentyl]-3-(3-phenylsulfanylpropyl)urea
    —— 2-(4-Propan-2-ylsulfanylphenyl)ethanesulfonyl chloride —— C11H15ClO2S2
    2-(4-Propan-2-ylsulfanylphenyl)ethanesulfonyl chloride
    —— 5-[(1S)-1-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C15H13N5O2S2
    5-[(1S)-1-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— N-cyclopropyl-N-[5-[(1R)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide —— C15H15N5O2S3
    N-cyclopropyl-N-[5-[(1R)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-butan-2-yl]-N-methylacetamide —— C20H24N4O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-butan-2-yl]-N-methylacetamide
    —— 5-[(1S)-1-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C22H26N6O2S2
    5-[(1S)-1-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 5-[(1S)-1-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C22H26N6O2S2
    5-[(1S)-1-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-butan-2-yl]-N-methylacetamide —— C20H24N4O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-butan-2-yl]-N-methylacetamide
    —— 4-[4-benzyl-5-[(1R)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine —— C21H22N6O2S2
    4-[4-benzyl-5-[(1R)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine
    —— 5-[(1S)-1-[[5-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C22H26N6O2S2
    5-[(1S)-1-[[5-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 4-[4-benzyl-5-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine —— C21H22N6O2S2
    4-[4-benzyl-5-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]morpholine
    —— N-cyclopropyl-N-[5-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide —— C15H15N5O2S3
    N-cyclopropyl-N-[5-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide
    —— 5-[(1R)-1-[[4-(furan-2-ylmethyl)-5-(4-methylpiperidin-1-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C21H24N6O2S2
    5-[(1R)-1-[[4-(furan-2-ylmethyl)-5-(4-methylpiperidin-1-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 5-[(1S)-1-[[4-(furan-2-ylmethyl)-5-(4-methylpiperidin-1-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C21H24N6O2S2
    5-[(1S)-1-[[4-(furan-2-ylmethyl)-5-(4-methylpiperidin-1-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 2-(4-Ethylsulfanylphenyl)ethanesulfonyl chloride —— C10H13ClO2S2
    2-(4-Ethylsulfanylphenyl)ethanesulfonyl chloride
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-(dimethylamino)-2-thiophen-3-ylethyl]acetamide —— C23H25N5O2S2
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-2-(dimethylamino)-2-thiophen-3-ylethyl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-(dimethylamino)-2-thiophen-3-ylethyl]acetamide —— C23H25N5O2S2
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-2-(dimethylamino)-2-thiophen-3-ylethyl]acetamide
    —— N-[(E)-(2-chlorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H12ClFN2OS
    N-[(E)-(2-chlorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]acetamide —— C14H12FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]acetamide
    —— (NE)-N-[(2R)-2-cyclohexylsulfonylcyclooctylidene]hydroxylamine —— C14H25NO3S
    (NE)-N-[(2R)-2-cyclohexylsulfonylcyclooctylidene]hydroxylamine
    —— 2-[[5-(2-methylpropyl)-1,2,4-oxadiazol-3-yl]methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H22N4O2S
    2-[[5-(2-methylpropyl)-1,2,4-oxadiazol-3-yl]methylsulfanyl]-5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 2-[[5-(2-methylpropyl)-1,2,4-oxadiazol-3-yl]methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole —— C18H22N4O2S
    2-[[5-(2-methylpropyl)-1,2,4-oxadiazol-3-yl]methylsulfanyl]-5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazole
    —— 1-[5-[(1-benzylimidazol-2-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine —— C24H32N6OS
    1-[5-[(1-benzylimidazol-2-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine
    —— 1-[5-[(1-benzylimidazol-2-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine —— C24H32N6OS
    1-[5-[(1-benzylimidazol-2-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine
    —— 3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-furan-2-ylmethylideneamino]-1H-1,2,4-triazol-5-amine —— C14H12FN5OS
    3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-furan-2-ylmethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N,N-diethyl-4-[(E)-(2-{5-[(pyridin-2-ylmethyl)sulfanyl]-4H-1,2,4-triazol-3-yl}hydrazinylidene)methyl]aniline —— C19H23N7S
    N,N-diethyl-4-[(E)-(2-{5-[(pyridin-2-ylmethyl)sulfanyl]-4H-1,2,4-triazol-3-yl}hydrazinylidene)methyl]aniline
    —— N-[(E)-furan-2-ylmethylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C17H19N5OS
    N-[(E)-furan-2-ylmethylideneamino]-3-[(2,4,6-trimethylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 3-[(2E)-2-(3-bromobenzylidene)hydrazinyl]-5-(prop-2-en-1-ylsulfanyl)-4H-1,2,4-triazole —— C12H12BrN5S
    3-[(2E)-2-(3-bromobenzylidene)hydrazinyl]-5-(prop-2-en-1-ylsulfanyl)-4H-1,2,4-triazole
    —— N-[(E)-[4-(dimethylamino)phenyl]methylideneamino]-3-(2-methylpropylsulfanyl)-1H-1,2,4-triazol-5-amine —— C15H22N6S
    N-[(E)-[4-(dimethylamino)phenyl]methylideneamino]-3-(2-methylpropylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-methylphenyl)methanimine —— C18H18N4S
    (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-methylphenyl)methanimine
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-phenylmethanimine —— C16H14N4S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-phenylmethanimine
    —— (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-thiophen-2-ylmethanimine —— C15H14N4S2
    (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-thiophen-2-ylmethanimine
    —— (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine —— C17H15ClN4S
    (E)-N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-4-ylmethanimine —— C15H12ClN5S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-4-ylmethanimine
    —— 4-[(2E)-2-{1-[(4-chlorophenyl)sulfanyl]propan-2-ylidene}hydrazinyl]pyrimidin-2(1H)-one —— C13H13ClN4OS
    4-[(2E)-2-{1-[(4-chlorophenyl)sulfanyl]propan-2-ylidene}hydrazinyl]pyrimidin-2(1H)-one
    —— (E)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine —— C14H11ClN4S2
    (E)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine
    —— (E,Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine —— C19H17ClN4S
    (E,Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine —— C14H11ClN4OS
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine
    —— (E)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine —— C14H11ClN4OS
    (E)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(furan-2-yl)methanimine