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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(E)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]phenol —— C16H13ClN4OS
    3-[(E)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]phenol
    —— (E)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(4-methylphenyl)methanimine —— C17H15ClN4S
    (E)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(4-methylphenyl)methanimine
    —— (E)-1-(2-chloro-6-fluorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H11Cl2FN4S
    (E)-1-(2-chloro-6-fluorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (E)-1-(3-chlorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C16H12Cl2N4S
    (E)-1-(3-chlorophenyl)-N-[3-[(2-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 3-butyl-5-[(1S)-1-[[5-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C18H26N6O2S3
    3-butyl-5-[(1S)-1-[[5-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 3-butyl-5-[(1R)-1-[[5-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C18H26N6O2S3
    3-butyl-5-[(1R)-1-[[5-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 3-butyl-5-[(1R)-1-[[5-[(1R)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C18H26N6O2S3
    3-butyl-5-[(1R)-1-[[5-[(1R)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-3-(dimethylamino)benzohydrazide —— C20H18ClN3O2S
    N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-3-(dimethylamino)benzohydrazide
    —— (1E)-1-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-phenylhydrazine —— C18H16N2OS
    (1E)-1-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-2-phenylhydrazine
    —— N'-[(1Z)-1-(4-aminophenyl)ethylidene]-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide —— C12H14N6OS2
    N'-[(1Z)-1-(4-aminophenyl)ethylidene]-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide
    —— 5-[(1S)-1-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C17H21N5OS2
    5-[(1S)-1-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— 5-[(1S)-1-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-3-butyl-1,2,4-oxadiazole —— C19H25N5OS
    5-[(1S)-1-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-3-butyl-1,2,4-oxadiazole
    —— 5-[(1S)-1-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C17H23N5O2S
    5-[(1S)-1-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C17H21N5OS2
    5-[(1R)-1-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C17H23N5O2S
    5-[(1R)-1-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— 3-butyl-5-[(1R)-1-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C14H22N4OS3
    3-butyl-5-[(1R)-1-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 3-butyl-5-[(1S)-1-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-1,2,4-oxadiazole —— C14H22N4OS3
    3-butyl-5-[(1S)-1-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-1,2,4-oxadiazole
    —— 5-[(1S)-1-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C18H24N6O2S
    5-[(1S)-1-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— 2-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-(3,5-dimethylphenyl)-1,3,4-oxadiazole —— C18H22N4O2S
    2-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-5-(3,5-dimethylphenyl)-1,3,4-oxadiazole
    —— 5-[(1R)-1-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C18H24N6O2S
    5-[(1R)-1-[[4-(furan-2-ylmethyl)-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— N-cyclopropyl-N-[5-[(1R)-1-(3-propyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide —— C14H19N5O2S2
    N-cyclopropyl-N-[5-[(1R)-1-(3-propyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]acetamide
    —— 5-[(1R)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C17H21N5OS2
    5-[(1R)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— 5-[(1S)-1-[[4-cyclopropyl-5-(4-methylpiperidin-1-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole —— C18H28N6OS
    5-[(1S)-1-[[4-cyclopropyl-5-(4-methylpiperidin-1-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propyl-1,2,4-oxadiazole
    —— N,N-dimethyl-4-[(E)-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)iminomethyl]aniline —— C13H15N7S
    N,N-dimethyl-4-[(E)-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)iminomethyl]aniline
    —— 5-[(1S)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propan-2-yl-1,2,4-oxadiazole —— C22H30N6OS
    5-[(1S)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propan-2-yl-1,2,4-oxadiazole
    —— 5-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C17H21N5OS2
    5-[(1S)-1-(3-butyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— 1-(4-Amino-furazan-3-yl)-5-(4-chloro-phenylsulfanylmethyl)-1H-[1,2,3]triazole-4-carboxylic acid [1-phenyl-meth-(E)-ylidene]-hydrazide —— C19H15ClN8O2S
    1-(4-Amino-furazan-3-yl)-5-(4-chloro-phenylsulfanylmethyl)-1H-[1,2,3]triazole-4-carboxylic acid [1-phenyl-meth-(E)-ylidene]-hydrazide
    —— N-[(E)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]pyridine-4-carboxamide —— C18H12N4O2S2
    N-[(E)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]pyridine-4-carboxamide
    —— N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-2-(2-nitrophenyl)acetohydrazide —— C19H13BrClN3O4S
    N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-2-(2-nitrophenyl)acetohydrazide
    —— 5-[(1R)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propan-2-yl-1,2,4-oxadiazole —— C22H30N6OS
    5-[(1R)-1-[[4-benzyl-5-(piperidin-1-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-propan-2-yl-1,2,4-oxadiazole
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-chloro-2-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C19H15ClN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-chloro-2-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— (2E)-N-methyl-2-[3-nitro-4-(pyrimidin-2-ylsulfanyl)benzylidene]hydrazinecarbothioamide —— C13H12N6O2S2
    (2E)-N-methyl-2-[3-nitro-4-(pyrimidin-2-ylsulfanyl)benzylidene]hydrazinecarbothioamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-[(2R)-oxolan-2-yl]ethyl]acetamide —— C18H24N4O2S
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-[(2R)-oxolan-2-yl]ethyl]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[2-[(2R)-oxolan-2-yl]ethyl]acetamide —— C16H22BrNO2S
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[2-[(2R)-oxolan-2-yl]ethyl]acetamide
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-(3,5-dimethyl-1,2-oxazol-4-yl)methylideneamino]thiourea —— C14H14F2N4OS2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-(3,5-dimethyl-1,2-oxazol-4-yl)methylideneamino]thiourea
    —— 3-(difluoromethyl)-5-(methylsulfanyl)-N-[(E)-{5-[(4-nitro-1H-pyrazol-1-yl)methyl]furan-2-yl}methylidene]-4H-1,2,4-triazol-4-amine —— C13H11F2N7O3S
    3-(difluoromethyl)-5-(methylsulfanyl)-N-[(E)-{5-[(4-nitro-1H-pyrazol-1-yl)methyl]furan-2-yl}methylidene]-4H-1,2,4-triazol-4-amine
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[2-[(2S)-oxolan-2-yl]ethyl]acetamide —— C16H22BrNO2S
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[2-[(2S)-oxolan-2-yl]ethyl]acetamide
    —— (Z)-3-amino-2-[2-(4,6-diaminopyrimidin-2-yl)sulfanylacetyl]but-2-enenitrile —— C10H12N6OS
    (Z)-3-amino-2-[2-(4,6-diaminopyrimidin-2-yl)sulfanylacetyl]but-2-enenitrile
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-[(2S)-oxolan-2-yl]ethyl]acetamide —— C18H24N4O2S
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[2-[(2S)-oxolan-2-yl]ethyl]acetamide
    —— (Z)-3-amino-2-[2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetyl]but-2-enenitrile —— C13H16N4OS
    (Z)-3-amino-2-[2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylacetyl]but-2-enenitrile
    —— N'-((E)-{2-[(4-Methylphenyl)sulfanyl]-4-oxo-4H-pyrido[1,2-A]pyrimidin-3-YL}methylidene)-4-nitrobenzohydrazide —— C23H17N5O4S
    N'-((E)-{2-[(4-Methylphenyl)sulfanyl]-4-oxo-4H-pyrido[1,2-A]pyrimidin-3-YL}methylidene)-4-nitrobenzohydrazide
    —— N'-{[5-(1H-benzimidazol-2-ylsulfanyl)-2-furyl]methylene}-4-(decyloxy)benzohydrazide —— C29H34N4O3S
    N'-{[5-(1H-benzimidazol-2-ylsulfanyl)-2-furyl]methylene}-4-(decyloxy)benzohydrazide
    —— 2-(4-ethylphenoxy)-N-[(E)-[5-(4-oxo-3-phenylquinazolin-2-yl)sulfanylfuran-2-yl]methylideneamino]acetamide —— C29H24N4O4S
    2-(4-ethylphenoxy)-N-[(E)-[5-(4-oxo-3-phenylquinazolin-2-yl)sulfanylfuran-2-yl]methylideneamino]acetamide
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-4-phenyl-1,3-thiazol-2-amine —— C17H15N3S2
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-4-phenyl-1,3-thiazol-2-amine
    —— (E)-N-(3-benzylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-phenylmethanimine —— C17H14N6S
    (E)-N-(3-benzylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-phenylmethanimine
    —— 5-[(1-benzylimidazol-2-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C18H21N5OS2
    5-[(1-benzylimidazol-2-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C16H14ClFN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— 5-[(1-benzylimidazol-2-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C18H21N5OS2
    5-[(1-benzylimidazol-2-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 2-(2-methylphenoxy)-N'-[(E)-{5-[(4-oxo-3-phenyl-3,4-dihydroquinazolin-2-yl)sulfanyl]furan-2-yl}methylidene]acetohydrazide —— C28H22N4O4S
    2-(2-methylphenoxy)-N'-[(E)-{5-[(4-oxo-3-phenyl-3,4-dihydroquinazolin-2-yl)sulfanyl]furan-2-yl}methylidene]acetohydrazide
    —— 2-{[4-allyl-5-(anilinomethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N'-(3-bromobenzylidene)propanohydrazide —— C22H23BrN6OS
    2-{[4-allyl-5-(anilinomethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N'-(3-bromobenzylidene)propanohydrazide