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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(3S)-2-oxooxolan-3-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C18H17NO4S
    [(3S)-2-oxooxolan-3-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(Benzylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C22H20N2O3S
    [2-(Benzylamino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(N-methylanilino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C22H20N2O3S
    [2-(N-methylanilino)-2-oxoethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[2-Cyanoethyl(methyl)amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C20H21N3O3S
    [2-[2-Cyanoethyl(methyl)amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [(3R)-2-oxooxolan-3-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C18H17NO4S
    [(3R)-2-oxooxolan-3-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C23H25N3O3S
    [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C22H26N2O4S
    [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-(Methylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C13H17NO3S
    [2-(Methylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(6-Amino-2,4-dioxo-1-propylpyrimidin-5-yl)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H23N3O5S
    [2-(6-Amino-2,4-dioxo-1-propylpyrimidin-5-yl)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(2-Methoxyethylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C15H21NO4S
    [2-(2-Methoxyethylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(2S)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C17H24BrNO3S
    [2-[[(2S)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C16H20BrNO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C19H27NO3S
    [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(2-Cyanoethylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C15H18N2O3S
    [2-(2-Cyanoethylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-(2-Methylpropylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C16H23NO3S
    [2-(2-Methylpropylamino)-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C18H24N2O3S
    [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C12H14ClN5OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-methyl-N-[(2-methylphenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H16N4OS
    N-methyl-N-[(2-methylphenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— ethyl 2,4-dimethyl-5-[(2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate —— C14H18N4O3S
    ethyl 2,4-dimethyl-5-[(2R)-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanoyl]-1H-pyrrole-3-carboxylate
    —— 2-(4-bromophenyl)sulfanyl-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide —— C16H15BrClNOS
    2-(4-bromophenyl)sulfanyl-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C18H18N4OS2
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13ClN4OS
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide —— C15H21N5OS
    (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-N-[(2R)-4-phenylbutan-2-yl]propanamide
    —— Methyl 3-[2,5-dimethyl-3-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]pyrrol-1-yl]propanoate —— C14H19N5O3S
    Methyl 3-[2,5-dimethyl-3-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]pyrrol-1-yl]propanoate
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C16H24N4OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide —— C13H15FN4OS
    (2R)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide
    —— (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide —— C13H20N4OS
    (2R)-N-[2-(cyclohexen-1-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C12H14N4O2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— 1-[2,5-dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone —— C12H13F3N4OS
    1-[2,5-dimethyl-1-(2,2,2-trifluoroethyl)pyrrol-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)ethanone
    —— (2R)-N-benzyl-N-methyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide —— C13H16N4OS
    (2R)-N-benzyl-N-methyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)propanamide
    —— N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C9H11N5O2S3
    N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C17H22BrNO3S
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H13N5OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(4-methylphenyl)-4-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3-thiazole —— C13H12N4S2
    2-(4-methylphenyl)-4-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3-thiazole
    —— [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C17H19BrN2O3S
    [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— 2-benzylsulfanyl-N-[2-(4-chlorophenyl)sulfanylphenyl]acetamide —— C21H18ClNOS2
    2-benzylsulfanyl-N-[2-(4-chlorophenyl)sulfanylphenyl]acetamide
    —— 6-amino-3-methyl-1-(2-methylpropyl)-5-[2-(1H-1,2,4-triazol-5-ylsulfanyl)acetyl]pyrimidine-2,4-dione —— C13H18N6O3S
    6-amino-3-methyl-1-(2-methylpropyl)-5-[2-(1H-1,2,4-triazol-5-ylsulfanyl)acetyl]pyrimidine-2,4-dione
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H13N5OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(2R)-2-(furan-2-yl)-2-pyrrolidin-1-ium-1-ylethyl]acetamide —— C18H22BrN2O2S+
    2-(4-bromophenyl)sulfanyl-N-[(2R)-2-(furan-2-yl)-2-pyrrolidin-1-ium-1-ylethyl]acetamide
    —— 2-(3,5-dimethylpyrazol-1-yl)-N'-(2-phenylsulfanylacetyl)acetohydrazide —— C15H18N4O2S
    2-(3,5-dimethylpyrazol-1-yl)-N'-(2-phenylsulfanylacetyl)acetohydrazide
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (1R,2S)-2-methylcyclopropane-1-carboxylate —— C19H19NO3S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (1R,2S)-2-methylcyclopropane-1-carboxylate
    —— 2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C17H18N4OS3
    2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-(4-Methylsulfonyl-2-nitrophenyl)sulfanylnaphthalene —— C17H13NO4S2
    2-(4-Methylsulfonyl-2-nitrophenyl)sulfanylnaphthalene
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide —— C18H20N4OS3
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)acetamide
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (1S,2R)-2-methylcyclopropane-1-carboxylate —— C19H19NO3S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (1S,2R)-2-methylcyclopropane-1-carboxylate
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(Z)-[(5S)-3,3,5-trimethylcyclohexylidene]amino]thiourea —— C17H23F2N3S2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(Z)-[(5S)-3,3,5-trimethylcyclohexylidene]amino]thiourea
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H17ClN2O3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]acetamide —— C14H13ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]acetamide
    —— [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C21H24N2O3S
    [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [2-Oxo-2-(thiophen-2-ylmethylamino)ethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C20H18N2O3S2
    [2-Oxo-2-(thiophen-2-ylmethylamino)ethyl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate