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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-benzyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-pyrimidin-2-ylsulfanylacetamide —— C17H17N3O3S2
    N-benzyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(2-methylphenyl)methyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H15N3OS
    N-[(2-methylphenyl)methyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-(2-methylbutan-2-yl)-2-pyrimidin-2-ylsulfanylacetamide —— C11H17N3OS
    N-(2-methylbutan-2-yl)-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-pyrimidin-2-ylsulfanylacetamide —— C13H19N3O4S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-pyrimidin-2-ylsulfanylacetamide —— C16H20N4OS
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-pyrimidin-2-ylsulfanylacetamide
    —— [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] cyclopentanecarboxylate —— C16H20BrNO3S
    [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] cyclopentanecarboxylate
    —— N-(6-amino-1-butyl-2,4-dioxopyrimidin-5-yl)-N-cyclopentyl-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C19H28N6O3S
    N-(6-amino-1-butyl-2,4-dioxopyrimidin-5-yl)-N-cyclopentyl-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— 3-[(1-Methylimidazol-2-yl)sulfanylmethyl]-5-phenyl-1,2-oxazole —— C14H13N3OS
    3-[(1-Methylimidazol-2-yl)sulfanylmethyl]-5-phenyl-1,2-oxazole
    —— N-(1-adamantyl)-N-(2-cyanoethyl)-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C19H26N4OS
    N-(1-adamantyl)-N-(2-cyanoethyl)-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C16H22N4OS
    N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— 2-[(2-Chlorophenyl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole —— C16H13ClN2OS
    2-[(2-Chlorophenyl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole
    —— 2-((5-Amino-1,3,4-thiadiazol-2-yl)thio)-N-methyl-N-(thiophen-3-ylmethyl)acetamide —— C10H12N4OS3
    2-((5-Amino-1,3,4-thiadiazol-2-yl)thio)-N-methyl-N-(thiophen-3-ylmethyl)acetamide
    —— N-benzyl-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide —— C19H18ClNO3S2
    N-benzyl-2-(2-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[2-(2-fluorophenyl)ethyl]acetamide —— C16H15ClFNOS
    2-(2-chlorophenyl)sulfanyl-N-[2-(2-fluorophenyl)ethyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(4-bromophenyl)sulfanylethyl]acetamide —— C12H13BrN4OS3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(4-bromophenyl)sulfanylethyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(4-methylphenyl)methyl]-N-propylacetamide —— C15H20N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(4-methylphenyl)methyl]-N-propylacetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide —— C19H16ClNOS2
    2-(2-chlorophenyl)sulfanyl-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-butan-2-yl]-N-[(2S)-butan-2-yl]acetamide —— C12H22N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-butan-2-yl]-N-[(2S)-butan-2-yl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-cyclopropylethyl]acetamide —— C9H14N4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-cyclopropylethyl]acetamide
    —— 5-(((5-(Furan-2-yl)isoxazol-3-yl)methyl)thio)-1,3,4-thiadiazol-2-amine —— C10H8N4O2S2
    5-(((5-(Furan-2-yl)isoxazol-3-yl)methyl)thio)-1,3,4-thiadiazol-2-amine
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-[(3-methylthiophen-2-yl)methyl]acetamide —— C11H14N4OS3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-[(3-methylthiophen-2-yl)methyl]acetamide
    —— (Z)-3-amino-2-[2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C15H14N4O2S
    (Z)-3-amino-2-[2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 1,3-Dichloro-2-(4-methylsulfonyl-2-nitrophenyl)sulfanylbenzene —— C13H9Cl2NO4S2
    1,3-Dichloro-2-(4-methylsulfonyl-2-nitrophenyl)sulfanylbenzene
    —— (2S)-1-[3-fluoro-4-(1-methylpyrazol-4-yl)sulfanylphenyl]butan-2-amine —— C14H18FN3S
    (2S)-1-[3-fluoro-4-(1-methylpyrazol-4-yl)sulfanylphenyl]butan-2-amine
    —— 1,3,5-Trimethyl-2-(4-methylsulfonyl-2-nitrophenyl)sulfanylbenzene —— C16H17NO4S2
    1,3,5-Trimethyl-2-(4-methylsulfonyl-2-nitrophenyl)sulfanylbenzene
    —— (2S)-1-(5-fluoro-2-pyrimidin-4-ylsulfanylphenyl)butan-2-amine —— C14H16FN3S
    (2S)-1-(5-fluoro-2-pyrimidin-4-ylsulfanylphenyl)butan-2-amine
    —— (2R)-1-[2-(1-methylpyrazol-4-yl)sulfanylphenyl]propan-2-amine —— C13H17N3S
    (2R)-1-[2-(1-methylpyrazol-4-yl)sulfanylphenyl]propan-2-amine
    —— (2R)-1-[3-fluoro-4-(1-methylpyrazol-4-yl)sulfanylphenyl]butan-2-amine —— C14H18FN3S
    (2R)-1-[3-fluoro-4-(1-methylpyrazol-4-yl)sulfanylphenyl]butan-2-amine
    —— (2R)-1-(5-fluoro-2-pyrimidin-4-ylsulfanylphenyl)butan-2-amine —— C14H16FN3S
    (2R)-1-(5-fluoro-2-pyrimidin-4-ylsulfanylphenyl)butan-2-amine
    —— (2S)-1-[2-(1-methylpyrazol-4-yl)sulfanylphenyl]propan-2-amine —— C13H17N3S
    (2S)-1-[2-(1-methylpyrazol-4-yl)sulfanylphenyl]propan-2-amine
    —— (2R)-1-(1,3-dimethyl-5-pyrimidin-4-ylsulfanylpyrazol-4-yl)propan-2-amine —— C12H17N5S
    (2R)-1-(1,3-dimethyl-5-pyrimidin-4-ylsulfanylpyrazol-4-yl)propan-2-amine
    —— (2S)-1-(1,3-dimethyl-5-pyrimidin-4-ylsulfanylpyrazol-4-yl)propan-2-amine —— C12H17N5S
    (2S)-1-(1,3-dimethyl-5-pyrimidin-4-ylsulfanylpyrazol-4-yl)propan-2-amine
    —— (1S)-1-(4-methylsulfanylphenyl)-N-[2-(1,3-thiazol-4-yl)ethyl]ethanamine —— C14H18N2S2
    (1S)-1-(4-methylsulfanylphenyl)-N-[2-(1,3-thiazol-4-yl)ethyl]ethanamine
    —— 4-Chloro-5-(2-fluorophenyl)sulfanyl-2-phenylpyridazin-3-one —— C16H10ClFN2OS
    4-Chloro-5-(2-fluorophenyl)sulfanyl-2-phenylpyridazin-3-one
    —— (2S)-1-(4-pyrimidin-4-ylsulfanylphenyl)propan-2-amine —— C13H15N3S
    (2S)-1-(4-pyrimidin-4-ylsulfanylphenyl)propan-2-amine
    —— (1R)-1-(4-methylsulfanylphenyl)-N-[2-(1,3-thiazol-4-yl)ethyl]ethanamine —— C14H18N2S2
    (1R)-1-(4-methylsulfanylphenyl)-N-[2-(1,3-thiazol-4-yl)ethyl]ethanamine
    —— 4-(2-fluorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]-3-nitrobenzenesulfonamide —— C16H17FN2O5S2
    4-(2-fluorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]-3-nitrobenzenesulfonamide
    —— (2S)-1-(4-pyrimidin-4-ylsulfanylphenyl)butan-2-amine —— C14H17N3S
    (2S)-1-(4-pyrimidin-4-ylsulfanylphenyl)butan-2-amine
    —— (2R)-1-(4-pyrimidin-4-ylsulfanylphenyl)butan-2-amine —— C14H17N3S
    (2R)-1-(4-pyrimidin-4-ylsulfanylphenyl)butan-2-amine
    —— N,N-diethyl-4-(2-fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide —— C16H17FN2O4S2
    N,N-diethyl-4-(2-fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 4-[(3S)-1-[[(1S)-cyclohex-3-en-1-yl]methyl]piperidin-3-yl]-2-(2-pyrrolidin-1-ylethylsulfanyl)pyrimidine —— C22H34N4S
    4-[(3S)-1-[[(1S)-cyclohex-3-en-1-yl]methyl]piperidin-3-yl]-2-(2-pyrrolidin-1-ylethylsulfanyl)pyrimidine
    —— 1-[4-(2-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonyl-4-methylpiperazin-4-ium —— C17H19FN3O4S2+
    1-[4-(2-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonyl-4-methylpiperazin-4-ium
    —— (2S)-1-[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-3-methylphenyl]propan-2-amine —— C14H20N4S
    (2S)-1-[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-3-methylphenyl]propan-2-amine
    —— (2R)-1-[5-(cyclopentylmethylsulfanyl)-1,3-dimethylpyrazol-4-yl]butan-2-amine —— C15H27N3S
    (2R)-1-[5-(cyclopentylmethylsulfanyl)-1,3-dimethylpyrazol-4-yl]butan-2-amine
    —— (2S)-1-[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-3-fluorophenyl]propan-2-amine —— C13H17FN4S
    (2S)-1-[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-3-fluorophenyl]propan-2-amine
    —— (2R)-1-[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-3-methylphenyl]propan-2-amine —— C14H20N4S
    (2R)-1-[4-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-3-methylphenyl]propan-2-amine
    —— (2R)-1-(5-fluoro-2-pyrazin-2-ylsulfanylphenyl)butan-2-amine —— C14H16FN3S
    (2R)-1-(5-fluoro-2-pyrazin-2-ylsulfanylphenyl)butan-2-amine
    —— (2S)-1-[5-(3-methoxypropylsulfanyl)-1,3-dimethylpyrazol-4-yl]propan-2-amine —— C12H23N3OS
    (2S)-1-[5-(3-methoxypropylsulfanyl)-1,3-dimethylpyrazol-4-yl]propan-2-amine
    —— (2S)-1-[6-(oxan-4-ylsulfanyl)imidazo[2,1-b][1,3]thiazol-5-yl]propan-2-amine —— C13H19N3OS2
    (2S)-1-[6-(oxan-4-ylsulfanyl)imidazo[2,1-b][1,3]thiazol-5-yl]propan-2-amine
    —— (2R)-1-[5-(3-methoxypropylsulfanyl)-1,3-dimethylpyrazol-4-yl]propan-2-amine —— C12H23N3OS
    (2R)-1-[5-(3-methoxypropylsulfanyl)-1,3-dimethylpyrazol-4-yl]propan-2-amine