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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-(4-amino-2-chlorophenyl)sulfanyl-3-methylbutanehydrazide —— C11H16ClN3OS
    (2R)-2-(4-amino-2-chlorophenyl)sulfanyl-3-methylbutanehydrazide
    —— (2S)-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C18H26N4O2S
    (2S)-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2R,5S)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C12H16ClN3O2S
    (2R,5S)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (2S,5S)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C12H16ClN3O2S
    (2S,5S)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (2S)-2-(4-amino-2-chlorophenyl)sulfanyl-3-methylbutanehydrazide —— C11H16ClN3OS
    (2S)-2-(4-amino-2-chlorophenyl)sulfanyl-3-methylbutanehydrazide
    —— (2S)-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C18H26N4O2S
    (2S)-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S,5R)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C12H16ClN3O2S
    (2S,5R)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (4R)-4-(2-amino-4-fluorophenyl)sulfanylpentanehydrazide —— C11H16FN3OS
    (4R)-4-(2-amino-4-fluorophenyl)sulfanylpentanehydrazide
    —— (4S)-4-(2-amino-4-fluorophenyl)sulfanylpentanehydrazide —— C11H16FN3OS
    (4S)-4-(2-amino-4-fluorophenyl)sulfanylpentanehydrazide
    —— (2R,5R)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C12H16ClN3O2S
    (2R,5R)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C16H23N5O2S2
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— 2-phenylsulfanyl-N-[2-(pyridin-4-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide —— C21H17N5OS
    2-phenylsulfanyl-N-[2-(pyridin-4-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide
    —— N-[2-(1-methylpiperidin-1-ium-4-yl)pyrazol-3-yl]-2-phenylsulfanylpyridine-3-carboxamide —— C21H24N5OS+
    N-[2-(1-methylpiperidin-1-ium-4-yl)pyrazol-3-yl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-[(3R)-6-oxopiperidin-3-yl]-2-pyridin-4-ylsulfanylacetamide —— C12H15N3O2S
    N-[(3R)-6-oxopiperidin-3-yl]-2-pyridin-4-ylsulfanylacetamide
    —— (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(1-cyanocyclohexyl)propanamide —— C19H22N4O2S
    (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(1-cyanocyclohexyl)propanamide
    —— 1-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-3-[4-(difluoromethylsulfanyl)phenyl]thiourea —— C15H17F2N3S2
    1-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-3-[4-(difluoromethylsulfanyl)phenyl]thiourea
    —— [2-(Benzylamino)-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C17H19N3O3S
    [2-(Benzylamino)-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-propan-2-yl-1,3,4-thiadiazol-2-amine —— C14H15N5OS2
    5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-propan-2-yl-1,3,4-thiadiazol-2-amine
    —— 2-phenylsulfanyl-N-[2-(pyridin-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide —— C21H17N5OS
    2-phenylsulfanyl-N-[2-(pyridin-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide
    —— ethyl (2R)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-2-phenylacetate —— C14H14F3N3O2S
    ethyl (2R)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-2-phenylacetate
    —— 2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone —— C15H20N5OS2+
    2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone
    —— (3S)-3-[[5-(aminomethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-propylpyrrolidine-2,5-dione —— C11H17N5O2S
    (3S)-3-[[5-(aminomethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-propylpyrrolidine-2,5-dione
    —— (3R)-3-[[5-(aminomethyl)-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidine-2,5-dione —— C10H15N5O2S
    (3R)-3-[[5-(aminomethyl)-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]-1-methylpyrrolidine-2,5-dione
    —— 2-(2-methylanilino)-N-[(E)-[5-[5-[(Z)-[[2-(2-methylanilino)acetyl]hydrazinylidene]methyl]furan-2-yl]sulfanylfuran-2-yl]methylideneamino]acetamide —— C28H28N6O4S
    2-(2-methylanilino)-N-[(E)-[5-[5-[(Z)-[[2-(2-methylanilino)acetyl]hydrazinylidene]methyl]furan-2-yl]sulfanylfuran-2-yl]methylideneamino]acetamide
    —— 4-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-[1]benzofuro[3,2-d]pyrimidine —— C16H8N4O3S
    4-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-[1]benzofuro[3,2-d]pyrimidine
    —— 2-phenylsulfanyl-N-[2-[(1R)-1-pyridin-4-ylethyl]pyrazol-3-yl]pyridine-3-carboxamide —— C22H19N5OS
    2-phenylsulfanyl-N-[2-[(1R)-1-pyridin-4-ylethyl]pyrazol-3-yl]pyridine-3-carboxamide
    —— (2S)-4-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile —— C18H16N4O2S2
    (2S)-4-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile
    —— (2R)-2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylpropanenitrile —— C20H24N4S
    (2R)-2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylpropanenitrile
    —— [2-Oxo-2-(prop-2-enylamino)ethyl] 2-phenylsulfanylacetate —— C13H15NO3S
    [2-Oxo-2-(prop-2-enylamino)ethyl] 2-phenylsulfanylacetate
    —— 1-chloro-4-[(1R)-1,2,2-trichloroethyl]sulfanylbenzene —— C8H6Cl4S
    1-chloro-4-[(1R)-1,2,2-trichloroethyl]sulfanylbenzene
    —— 4-Methyl-2-(2-thiophen-2-ylquinazolin-4-yl)sulfanyl-1,3-thiazole —— C16H11N3S3
    4-Methyl-2-(2-thiophen-2-ylquinazolin-4-yl)sulfanyl-1,3-thiazole
    —— [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 2-(4-methylphenyl)sulfanylacetate —— C16H21NO4S
    [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 2-(4-methylphenyl)sulfanylacetate
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[2-(furan-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide —— C22H20N4O2S
    2-(2,4-dimethylphenyl)sulfanyl-N-[2-(furan-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide
    —— 2-(2,5-dimethylphenyl)sulfanyl-N-(2-propan-2-ylpyrazol-3-yl)pyridine-3-carboxamide —— C20H22N4OS
    2-(2,5-dimethylphenyl)sulfanyl-N-(2-propan-2-ylpyrazol-3-yl)pyridine-3-carboxamide
    —— 2-(4-methylphenyl)sulfanyl-N-[2-(1-methylpiperidin-1-ium-4-yl)pyrazol-3-yl]pyridine-3-carboxamide —— C22H26N5OS+
    2-(4-methylphenyl)sulfanyl-N-[2-(1-methylpiperidin-1-ium-4-yl)pyrazol-3-yl]pyridine-3-carboxamide
    —— N-[[5-[2-[[5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide —— C16H21N4O3S2+
    N-[[5-[2-[[5-(pyrrolidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]thiophen-2-yl]methyl]acetamide
    —— N-(1-cyanocyclohexyl)-2-(4-fluorophenyl)sulfanyl-N-methylacetamide —— C16H19FN2OS
    N-(1-cyanocyclohexyl)-2-(4-fluorophenyl)sulfanyl-N-methylacetamide
    —— N-propyl-5-(thiazol-4-ylmethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C9H12N4S3
    N-propyl-5-(thiazol-4-ylmethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (3S)-N-(4-cyclopentylsulfanylphenyl)oxolan-3-amine —— C15H21NOS
    (3S)-N-(4-cyclopentylsulfanylphenyl)oxolan-3-amine
    —— (3R)-N-(4-cyclopentylsulfanylphenyl)oxolan-3-amine —— C15H21NOS
    (3R)-N-(4-cyclopentylsulfanylphenyl)oxolan-3-amine
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-5-(furan-2-yl)-3-thiophen-2-yl-3,4-dihydropyrazol-2-yl]ethanone —— C15H14N6O2S2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-5-(furan-2-yl)-3-thiophen-2-yl-3,4-dihydropyrazol-2-yl]ethanone
    —— 2-(2,5-dimethylphenyl)sulfanyl-N-[2-(1-methylpiperidin-1-ium-4-yl)pyrazol-3-yl]pyridine-3-carboxamide —— C23H28N5OS+
    2-(2,5-dimethylphenyl)sulfanyl-N-[2-(1-methylpiperidin-1-ium-4-yl)pyrazol-3-yl]pyridine-3-carboxamide
    —— 2-(2,5-dimethylphenyl)sulfanyl-N-[2-(furan-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide —— C22H20N4O2S
    2-(2,5-dimethylphenyl)sulfanyl-N-[2-(furan-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide
    —— (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C12H19N3O3S3
    (2S)-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-prop-2-enylpropanamide —— C9H13N3OS2
    (2R)-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-prop-2-enylpropanamide
    —— (2S)-N-[(4-fluorophenyl)methyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H14FN3OS2
    (2S)-N-[(4-fluorophenyl)methyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C11H14N4O3S3
    (2R)-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C10H15N3O3S3
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-N-tert-butyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C23H27N3O2S
    (2S)-N-benzyl-N-tert-butyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H19N3O4S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide