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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(2-Chlorophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole —— C17H15ClN2OS
    2-[(2-Chlorophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole
    —— [2-(2-cyanoethylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C14H16N2O3S
    [2-(2-cyanoethylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C20H20N2O3S2
    [2-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C19H20FNO3S
    [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-(ethoxycarbonylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C14H17NO5S
    [2-(ethoxycarbonylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20ClN3O2S
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C21H22FN3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide —— C18H19N3O2S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide
    —— [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C19H20FNO3S
    [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (3S)-3-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C14H14N2O3S
    (3S)-3-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C18H18ClNO3S
    [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2R)-2-phenylsulfanylpropanoate —— C18H16N2O3S
    (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2R)-2-phenylsulfanylpropanoate
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C18H19N3OS2
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C18H22N2O3S
    [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H24N4O2S
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— [2-(ethoxycarbonylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C14H17NO5S
    [2-(ethoxycarbonylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylacetamide —— C19H25N3O4S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylacetamide
    —— (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H24N4O2S
    (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one —— C19H26N4O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone —— C20H20N2O2S2
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone
    —— N-(1-cyanocyclohexyl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C19H21N3OS2
    N-(1-cyanocyclohexyl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 1-oxidopyridin-1-ium-2-carboxylate —— C20H16N2O4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 1-oxidopyridin-1-ium-2-carboxylate
    —— N-benzyl-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H16N4OS
    N-benzyl-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide —— C15H19N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide
    —— [(1S)-1-[4-benzyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C19H26N5S2+
    [(1S)-1-[4-benzyl-5-[(2-methyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (2S)-N-benzyl-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H21N3O2S
    (2S)-N-benzyl-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C18H23N3O3S
    1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— (2S)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C21H22FN3O2S
    (2S)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C19H25N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— ethyl N-[2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]carbamate —— C15H17N3O4S
    ethyl N-[2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]carbamate
    —— (3S)-3-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C14H14N2O3S
    (3S)-3-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— 2-[[5-(3,5-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetonitrile —— C12H11N3OS
    2-[[5-(3,5-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetonitrile
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C17H24N2OS
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— N-[(1R)-1-phenylethyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C19H23NOS
    N-[(1R)-1-phenylethyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— 1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H17N5OS2
    1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 2-[[5-(Prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylethanone —— C11H16N4OS2
    2-[[5-(Prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylethanone
    —— N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H17ClN4OS2
    N-[(1S)-1-(2-chlorophenyl)ethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(2-methoxyethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C10H16N4O2S2
    N-(2-methoxyethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 5-[(3-fluorophenyl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C12H12FN3S2
    5-[(3-fluorophenyl)methylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— N-cyclopentyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C12H18N4OS2
    N-cyclopentyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C13H16N4OS3
    N-methyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— N-(2-cyanoethyl)-N-methyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C11H15N5OS2
    N-(2-cyanoethyl)-N-methyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(5-Bromothiophen-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C11H10BrN3OS3
    1-(5-Bromothiophen-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-(2-phenylethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H18N4OS2
    N-(2-phenylethyl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H23N5OS2
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 5-[2-(2-fluorophenyl)sulfanylethylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine —— C13H14FN3S3
    5-[2-(2-fluorophenyl)sulfanylethylsulfanyl]-N-prop-2-enyl-1,3,4-thiadiazol-2-amine
    —— (2R)-N-cyclopropyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C11H16N4OS2
    (2R)-N-cyclopropyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C10H16N4OS2
    2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— ethyl 2,4-dimethyl-5-[(2S)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C17H22N4O3S2
    ethyl 2,4-dimethyl-5-[(2S)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— N-benzyl-N-ethyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4OS2
    N-benzyl-N-ethyl-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide