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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoic acid —— C15H20N4O4S
    (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoic acid
    —— 5-[(2-Chlorophenyl)methylsulfanyl]-7-(2,2-dimethylpropyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C20H23ClN4O2S
    5-[(2-Chlorophenyl)methylsulfanyl]-7-(2,2-dimethylpropyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C22H26N4O2S
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-3-methylsulfonylpropan-1-amine —— C12H21NO2S
    N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-3-methylsulfonylpropan-1-amine
    —— (2S)-2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoic acid —— C14H18N4O4S
    (2S)-2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoic acid
    —— N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-3-methylsulfonylpropan-1-amine —— C12H21NO2S
    N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-3-methylsulfonylpropan-1-amine
    —— 3-[[(4R)-1,3-dioxan-4-yl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C15H19N3O3S
    3-[[(4R)-1,3-dioxan-4-yl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— (2R)-1-(3-methylsulfonylpropylamino)-3-octoxypropan-2-ol —— C15H33NO4S
    (2R)-1-(3-methylsulfonylpropylamino)-3-octoxypropan-2-ol
    —— methyl (2S)-2-[7-(2,2-dimethylpropyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C17H24N4O4S
    methyl (2S)-2-[7-(2,2-dimethylpropyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— 1,3-dimethyl-5-[(1R)-1-phenylethyl]sulfanyl-7-propan-2-ylpyrimido[4,5-d]pyrimidine-2,4-dione —— C19H22N4O2S
    1,3-dimethyl-5-[(1R)-1-phenylethyl]sulfanyl-7-propan-2-ylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 3-[(4-chlorophenyl)methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C17H16ClN3OS
    3-[(4-chlorophenyl)methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— tert-butyl 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H21N3O3S
    tert-butyl 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— methyl (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate —— C15H20N4O4S
    methyl (2S)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate
    —— 1,3-Dimethyl-5-(3-methylbutylsulfanyl)-7-thiophen-2-ylpyrimido[4,5-d]pyrimidine-2,4-dione —— C17H20N4O2S2
    1,3-Dimethyl-5-(3-methylbutylsulfanyl)-7-thiophen-2-ylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 5-(benzylthio)-1,3-dimethyl-7-propylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione —— C18H20N4O2S
    5-(benzylthio)-1,3-dimethyl-7-propylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— ethyl (2R)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate —— C17H24N4O4S
    ethyl (2R)-2-(1,3-dimethyl-2,4-dioxo-7-propan-2-ylpyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate
    —— 7-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C13H15N5O3S2
    7-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 3-ethylsulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C12H15N3OS
    3-ethylsulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 3-[2-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C18H24N4O3S
    3-[2-[(2S,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— (2S)-1-(3-methylsulfonylpropylamino)-3-octoxypropan-2-ol —— C15H33NO4S
    (2S)-1-(3-methylsulfonylpropylamino)-3-octoxypropan-2-ol
    —— (1R,2S,3S,4R)-3-(3-methylsulfonylpropylcarbamoyl)bicyclo[2.2.1]hept-5-ene-2-carboxylic acid —— C13H19NO5S
    (1R,2S,3S,4R)-3-(3-methylsulfonylpropylcarbamoyl)bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
    —— (1R,2S,3R,4R)-3-(3-methylsulfonylpropylcarbamoyl)bicyclo[2.2.1]hept-5-ene-2-carboxylic acid —— C13H19NO5S
    (1R,2S,3R,4R)-3-(3-methylsulfonylpropylcarbamoyl)bicyclo[2.2.1]hept-5-ene-2-carboxylic acid
    —— (2S)-2-(7-cyclopropyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoic acid —— C14H16N4O4S
    (2S)-2-(7-cyclopropyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoic acid
    —— ethyl (2R)-2-(1,3-dimethyl-2,4-dioxo-7-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-3-oxobutanoate —— C17H22N4O5S
    ethyl (2R)-2-(1,3-dimethyl-2,4-dioxo-7-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-3-oxobutanoate
    —— propan-2-yl 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H19N3O3S
    propan-2-yl 2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— ethyl (2S)-2-(7-cyclopropyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate —— C17H22N4O4S
    ethyl (2S)-2-(7-cyclopropyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate
    —— N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H22N4O4S2
    N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2R)-butan-2-yl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H22N4O2S
    N-[(2R)-butan-2-yl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-(methylcarbamoyl)-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C14H17N5O3S
    N-(methylcarbamoyl)-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H26N4O2S
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 4-butyl-3-[2-(5-chlorothiophen-2-yl)-2-oxoethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C12H14ClN3O2S2
    4-butyl-3-[2-(5-chlorothiophen-2-yl)-2-oxoethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C16H19N3O2S
    2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one —— C17H15N5O3S
    3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-(2-phenylethyl)-1H-1,2,4-triazol-5-one
    —— 2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C15H26N4O2S
    2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— 2-[(2S)-butan-2-yl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one —— C11H18N2OS
    2-[(2S)-butan-2-yl]sulfanyl-4-propan-2-yl-1H-pyrimidin-6-one
    —— 2-[(2-Aminoethyl)thio]-6-methylpyrimidin-4-ol 893631-10-2 C7H11N3OS
    2-[(2-Aminoethyl)thio]-6-methylpyrimidin-4-ol
    —— (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C18H24N4O3S
    (E)-3-[5-(azepan-1-yl)furan-2-yl]-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— (E)-3-(furan-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid —— C12H13N3O3S
    (E)-3-(furan-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoic acid
    —— N-(1-adamantyl)-2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H28N4O2S
    N-(1-adamantyl)-2-[(4-butyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C16H19N3O2S
    2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— (E)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(furan-2-yl)prop-2-enoic acid —— C11H10N2O4S
    (E)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]-3-(furan-2-yl)prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid —— C17H17N5O3S
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4S)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid
    —— 5-benzyl-4-methyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-1H-pyrimidin-6-one —— C18H24N3O2S+
    5-benzyl-4-methyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-1H-pyrimidin-6-one
    —— 2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C17H21N3O2S
    2-[(6-oxo-4-propan-2-yl-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-morpholin-4-ylfuran-2-yl)prop-2-enoic acid —— C15H18N4O4S
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-morpholin-4-ylfuran-2-yl)prop-2-enoic acid
    —— (E)-3-(5-bromothiophen-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate —— C12H11BrN3O2S2-
    (E)-3-(5-bromothiophen-2-yl)-2-[(5-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]prop-2-enoate
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoic acid —— C17H15N3O3S2
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-(5-phenylsulfanylfuran-2-yl)prop-2-enoic acid
    —— (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid —— C17H17N5O3S
    (Z)-2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-3-[(4R)-3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl]prop-2-enoic acid
    —— 4-butyl-3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C13H15N5O3S
    4-butyl-3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— (2E)-2-[[4-[ethyl(methyl)amino]phenyl]methylidene]-1-benzothiophen-3-one —— C18H17NOS
    (2E)-2-[[4-[ethyl(methyl)amino]phenyl]methylidene]-1-benzothiophen-3-one