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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Oct-2-ynylsulfanyl-benzene 194856-56-9 C14H18S
    Oct-2-ynylsulfanyl-benzene
    —— 2-(phenylthio)ethyl-acetylacetate 100303-72-8 C12H14O3S
    2-(phenylthio)ethyl-acetylacetate
    —— 2,2-bis(phenylthio)heptane 77815-67-9 C19H24S2
    2,2-bis(phenylthio)heptane
    —— (Z)-Hept-1-en-1-yl-phenyl-sulfid 66967-47-3 C13H18S
    (Z)-Hept-1-en-1-yl-phenyl-sulfid
    —— 2-((methylthio)methoxy)acetaldehyde 1268389-77-0 C4H8O2S
    2-((methylthio)methoxy)acetaldehyde
    —— 8,8-ethylenedioxy-4,4-trimethylenedithiononan-1-ol 148705-76-4 C14H26O3S2
    8,8-ethylenedioxy-4,4-trimethylenedithiononan-1-ol
    —— 1-methoxy-1-methylsulfanyl-ethane 98026-18-7 C4H10OS
    1-methoxy-1-methylsulfanyl-ethane
    —— 1,1-bis(phenylthio)-2,2,3,3,3-pentafluoropropylbenzene 137504-63-3 C21H15F5S2
    1,1-bis(phenylthio)-2,2,3,3,3-pentafluoropropylbenzene
    —— (E)-1-((methylthio)methoxy)dec-3-en-2-one 1268389-81-6 C12H22O2S
    (E)-1-((methylthio)methoxy)dec-3-en-2-one
    —— 1-Methyl-2-[3-(2-methyl-1,3-dioxolan-2-yl)propylsulfanyl]imidazole 239078-72-9 C11H18N2O2S
    1-Methyl-2-[3-(2-methyl-1,3-dioxolan-2-yl)propylsulfanyl]imidazole
    —— pinacol 1-(phenylthio)ethane-1-boronate 66080-24-8 C14H21BO2S
    pinacol 1-(phenylthio)ethane-1-boronate
    —— 5,7-dimethyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidinylium; bromide 15068-61-8 Br*C8H11N2S
    5,7-dimethyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidinylium; bromide
    —— [(E)-1-fluoro-1-phenylbut-1-en-2-yl]sulfanylbenzene 129762-14-7 C16H15FS
    [(E)-1-fluoro-1-phenylbut-1-en-2-yl]sulfanylbenzene
    —— 3-n-butyl-2-(phenylthio)-1-propene 123431-95-8 C13H18S
    3-n-butyl-2-(phenylthio)-1-propene
    —— 4,4-(Ethylenedioxy)pentyl phenyl sulfide 97600-68-5 C13H18O2S
    4,4-(Ethylenedioxy)pentyl phenyl sulfide
    —— 2-methylthio-6-(tricyanoethenyl)-4,4-diphenyldithienosilole 1263314-90-4 C26H15N3S3Si
    2-methylthio-6-(tricyanoethenyl)-4,4-diphenyldithienosilole
    —— 2,2'-Sulfanediylbis(4-ethylpyridine) 923279-85-0 C14H16N2S
    2,2'-Sulfanediylbis(4-ethylpyridine)
    —— Bis(4-hydroxyphenylthio)methane 104884-57-3 C13H12O2S2
    Bis(4-hydroxyphenylthio)methane
    —— 4,6-dimethyl-2-pyrimidinyl-N-(2,6-diethylphenyl)-N-(4,6-dimethyl-2-pyrimidinylthiomethyl)thiolcarbanilate 113708-02-4 C24H29N5OS2
    4,6-dimethyl-2-pyrimidinyl-N-(2,6-diethylphenyl)-N-(4,6-dimethyl-2-pyrimidinylthiomethyl)thiolcarbanilate
    —— 2-Ethylsulfanyladamantane 65566-33-8 C12H20S
    2-Ethylsulfanyladamantane
    —— 5-(4,6-dimethylpyrimidine-2-thiomethyl)-4-amino-3-mercapto-1,2,4-triazole 938159-39-8 C9H12N6S2
    5-(4,6-dimethylpyrimidine-2-thiomethyl)-4-amino-3-mercapto-1,2,4-triazole
    —— 3-chloro-5-[(5-chloro-2-methoxyphenyl)thio]benzonitrile 895572-43-7 C14H9Cl2NOS
    3-chloro-5-[(5-chloro-2-methoxyphenyl)thio]benzonitrile
    —— Decane-2-sulfonoperoxoic acid 132258-11-8 C10H22O4S
    Decane-2-sulfonoperoxoic acid
    —— 3-[(4-Methylsulfanylphenyl)methyl]-6-(2,3,4-trichlorophenyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole 1144110-73-5 C17H11Cl3N4S2
    3-[(4-Methylsulfanylphenyl)methyl]-6-(2,3,4-trichlorophenyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— (1-Chloro-non-2-ynylsulfanyl)-benzene 153940-39-7 C15H19ClS
    (1-Chloro-non-2-ynylsulfanyl)-benzene
    —— Non-2-ynylsulfanyl-benzene 133188-94-0 C15H20S
    Non-2-ynylsulfanyl-benzene
    —— 1-N-(4,6-dimethylpyrimidin-2-yl)-4-N,4-N-dimethyl-2-methylsulfanylbenzene-1,4-diamine 1026628-37-4 C15H20N4S
    1-N-(4,6-dimethylpyrimidin-2-yl)-4-N,4-N-dimethyl-2-methylsulfanylbenzene-1,4-diamine
    —— Pyrimidine, 4,6-dimethyl-2-[(3-pyridinylmethyl)thio]- 88579-43-5 C12H13N3S
    Pyrimidine, 4,6-dimethyl-2-[(3-pyridinylmethyl)thio]-
    —— 2-(1,2,4-triazin-3-ylthio)-N,N-diethylethan-1-amine 1255789-68-4 C9H16N4S
    2-(1,2,4-triazin-3-ylthio)-N,N-diethylethan-1-amine
    —— 4-Bromacetylamino-4'-methoxydiphenylsulfid 38007-64-6 C15H14BrNO2S
    4-Bromacetylamino-4'-methoxydiphenylsulfid
    —— 4-chloro-1-(3-fluoro-phenylsulfanyl)-2-methoxybenzene 791642-71-2 C13H10ClFOS
    4-chloro-1-(3-fluoro-phenylsulfanyl)-2-methoxybenzene
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-4-N,4-N-dimethylbenzene-1,4-diamine 1027964-23-3 C14H18N4S
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-4-N,4-N-dimethylbenzene-1,4-diamine
    —— 4,6-dimethyl-2-trifluoromethylthiopyrimidine 70558-90-6 C7H7F3N2S
    4,6-dimethyl-2-trifluoromethylthiopyrimidine
    —— 2-Acetylmercapto-4,6-dimethyl-pyrimidin 41041-23-0 C8H10N2OS
    2-Acetylmercapto-4,6-dimethyl-pyrimidin
    —— 2-(4,6-Dimethyl-pyrimidin-2-ylsulfanyl)-4-isopropyl-phenylamine 169883-28-7 C15H19N3S
    2-(4,6-Dimethyl-pyrimidin-2-ylsulfanyl)-4-isopropyl-phenylamine
    —— 4,6-dimethyl-2-((4-nitrophenyl)thio)pyrimidine 28176-19-4 C12H11N3O2S
    4,6-dimethyl-2-((4-nitrophenyl)thio)pyrimidine
    —— 4-[(4,6-Dimethylpyrimidin-2-yl)sulfanylmethyl]-2-(2,3,5-trichlorophenyl)-1,3-thiazole 1018688-16-8 C16H12Cl3N3S2
    4-[(4,6-Dimethylpyrimidin-2-yl)sulfanylmethyl]-2-(2,3,5-trichlorophenyl)-1,3-thiazole
    —— 4,4',6,6'-tetramethyl-2,2'-(ethane-1,4-diyldithio)dipyrimidine 14961-45-6 C14H18N4S2
    4,4',6,6'-tetramethyl-2,2'-(ethane-1,4-diyldithio)dipyrimidine
    —— 2(1H)-Pyridinone, 4-((4,6-dimethyl-2-pyrimidinyl)thio)-5-methyl-3-nitro- 172469-83-9 C12H12N4O3S
    2(1H)-Pyridinone, 4-((4,6-dimethyl-2-pyrimidinyl)thio)-5-methyl-3-nitro-
    —— 2,2'-[1,6-hexanediylbis(thio)]bis(4,6-dimethylpyrimidine) 14961-49-0 C18H26N4S2
    2,2'-[1,6-hexanediylbis(thio)]bis(4,6-dimethylpyrimidine)
    —— 4,4'-sulfanediyl-bis-benzenesulfinic acid 133838-69-4 C12H10O4S3
    4,4'-sulfanediyl-bis-benzenesulfinic acid
    —— 4,4'-sulfanediyl-bis-benzenesulfonic acid dihydrazide 52408-79-4 C12H14N4O4S3
    4,4'-sulfanediyl-bis-benzenesulfonic acid dihydrazide
    —— 7-phenyl-2H-thiazolo[3,2-a]pyrimidine-3-one[5,6:5',6']-2H-thiazolo[3-,2-a]pyrimidine-3,7-dione 1341192-69-5 C16H10N4O3S2
    7-phenyl-2H-thiazolo[3,2-a]pyrimidine-3-one[5,6:5',6']-2H-thiazolo[3-,2-a]pyrimidine-3,7-dione
    —— 2-((difluoromethyl)thio)-4,6-dimethylpyrimidine 56228-50-3 C7H8F2N2S
    2-((difluoromethyl)thio)-4,6-dimethylpyrimidine
    —— methyl 6-oxo-2,4-dithioxo-2,4,6,7-tetrahydrothiazolo[3,2-c][1,3,5]thiadiazine-7-carbodithioate 1334177-04-6 C7H4N2OS6
    methyl 6-oxo-2,4-dithioxo-2,4,6,7-tetrahydrothiazolo[3,2-c][1,3,5]thiadiazine-7-carbodithioate
    —— S-2-amino-4-chloro-6-fluorophenyl dimethylthiocarbamate 131105-66-3 C9H10ClFN2OS
    S-2-amino-4-chloro-6-fluorophenyl dimethylthiocarbamate
    —— 1,8-bis(o-hydroxyphenylthio)-3,6-dioxaoctane 169053-02-5 C18H22O4S2
    1,8-bis(o-hydroxyphenylthio)-3,6-dioxaoctane
    —— Perfluoro-2-methyl-2-pentene-3-thiocyanate 127479-30-5 C7F11NS
    Perfluoro-2-methyl-2-pentene-3-thiocyanate
    —— 2-(2-Methanesulfinyl-2-methylsulfanyl-ethyl)-cyclohexanone 51534-67-9 C10H18O2S2
    2-(2-Methanesulfinyl-2-methylsulfanyl-ethyl)-cyclohexanone
    —— (R)-3-(2-(5-amino-1,3,4-thiadiazol-2-ylthio)acetamido)-2-hydroxy-3,4-dihydro-2H-benzo[e][1,2]oxaborinine-8-carboxylic acid 1617542-46-7 C13H13BN4O5S2
    (R)-3-(2-(5-amino-1,3,4-thiadiazol-2-ylthio)acetamido)-2-hydroxy-3,4-dihydro-2H-benzo[e][1,2]oxaborinine-8-carboxylic acid