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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [((E)-Hex-3-enyl)oxy]-phenylsulfanyl-acetic acid ethyl ester 134277-88-6 C16H22O3S
    [((E)-Hex-3-enyl)oxy]-phenylsulfanyl-acetic acid ethyl ester
    —— methyl 2-methyl-1,3-dithiolane-2-carboxylate 61784-35-8 C6H10O2S2
    methyl 2-methyl-1,3-dithiolane-2-carboxylate
    —— 5-<(E)-1-(Phenylthio)-1-propenyl>-1-pyrroline 128845-07-8 C13H15NS
    5-<(E)-1-(Phenylthio)-1-propenyl>-1-pyrroline
    —— N,N'-(hexamethylene)bisdithiocarbamic acid 45131-67-7 C8H16N2S4
    N,N'-(hexamethylene)bisdithiocarbamic acid
    —— N,2-dimethyl-N-hydroxy-1-propanethioamide 105183-87-7 C5H11NOS
    N,2-dimethyl-N-hydroxy-1-propanethioamide
    —— hexamethylenedithiourea 10017-50-2 C8H18N4S2
    hexamethylenedithiourea
    —— 2-(2,4-dichloro-benzenesulfonylamino)-N-methoxy-N-methyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinamide 882500-08-5 C25H26Cl2N4O6S3
    2-(2,4-dichloro-benzenesulfonylamino)-N-methoxy-N-methyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinamide
    —— (3'S,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropyloxazolidin-2-one 236094-48-7 C15H25NO4S2
    (3'S,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropyloxazolidin-2-one
    —— (3'R,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropylooxazolidin-2-one 236094-47-6 C15H25NO4S2
    (3'R,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropylooxazolidin-2-one
    —— N-<2-Phenylmercapto-1-methyl-aethyl>-acetamid 91281-29-7 C11H15NOS
    N-<2-Phenylmercapto-1-methyl-aethyl>-acetamid
    —— 2-(Methylsulfinylmethylsulfanyl)-5-phenyl-1,3,4-thiadiazole 154220-74-3 C10H10N2OS3
    2-(Methylsulfinylmethylsulfanyl)-5-phenyl-1,3,4-thiadiazole
    —— (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxoheptyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 143879-17-8 C20H29NO4S
    (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxoheptyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— trans-3-Ethyl-2,4,5-trithia-6-octene 2-S-oxide 197566-05-5 C7H14OS3
    trans-3-Ethyl-2,4,5-trithia-6-octene 2-S-oxide
    —— Imidodi(thiokohlensaeure-O-ethylester) 77588-28-4 C6H11NO2S2
    Imidodi(thiokohlensaeure-O-ethylester)
    —— (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 143879-16-7 C19H27NO4S
    (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylhexan-1-ol 182824-31-3 C13H20O2S
    (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylhexan-1-ol
    —— (4S)-3-<(2R,3S,4R)-3-Hydroxy-2,5-dimethyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 143879-18-9 C20H29NO4S
    (4S)-3-<(2R,3S,4R)-3-Hydroxy-2,5-dimethyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylheptan-1-ol 143879-19-0 C14H22O2S
    (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylheptan-1-ol
    —— (4S)-3-<(2R,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclododecyl)propyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 154868-38-9 C28H43NO4S
    (4S)-3-<(2R,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclododecyl)propyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— Ethyl {[(2-methoxyethoxy)carbonyl]sulfanyl}acetate 135742-69-7 C8H14O5S
    Ethyl {[(2-methoxyethoxy)carbonyl]sulfanyl}acetate
    —— (3R)-3-mercaptopentan-1-ol 350611-23-3 C5H12OS
    (3R)-3-mercaptopentan-1-ol
    —— 1-[5-(2-methyl-1,3-benzodithiol-2-yl)-1H-pyrrol-3-yl]ethanone 147089-10-9 C14H13NOS2
    1-[5-(2-methyl-1,3-benzodithiol-2-yl)-1H-pyrrol-3-yl]ethanone
    —— 2-(benzylthio)pyrimidine-4,5,6-triamine 95493-97-3 C11H13N5S
    2-(benzylthio)pyrimidine-4,5,6-triamine
    —— bis-(Heptadecafluorooctanesulfonyl)methane 29214-34-4 C17H2F34O4S2
    bis-(Heptadecafluorooctanesulfonyl)methane
    —— 3-ethylsulfanylbenzene-1,2-diamine 872471-97-1 C8H12N2S
    3-ethylsulfanylbenzene-1,2-diamine
    —— Chloromethyl-methyl-thiocarbamic acid S-methyl ester 39073-80-8 C4H8ClNOS
    Chloromethyl-methyl-thiocarbamic acid S-methyl ester
    —— lithium 3-(methylthio)benzenesulfinate 1609560-83-9 C7H7O2S2*Li
    lithium 3-(methylthio)benzenesulfinate
    —— 6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purine 1380333-85-6 C16H16N4OS
    6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purine
    —— 4-Methyl-6-methylsulfanyl-1H-pyridin-2-one 128951-36-0 C7H9NOS
    4-Methyl-6-methylsulfanyl-1H-pyridin-2-one
    —— 2,5-bis(1,3-benzodithiol-2-yl)-3-formylpyrrole 153850-69-2 C19H13NOS4
    2,5-bis(1,3-benzodithiol-2-yl)-3-formylpyrrole
    —— 3,6-Dimethyl-2,5-N,N'-dicyandiimin-2,5-dihydrothieno<3,2-b>thiophen 125594-12-9 C10H6N4S2
    3,6-Dimethyl-2,5-N,N'-dicyandiimin-2,5-dihydrothieno<3,2-b>thiophen
    —— 2-Thioxo-propionaldehyde 132604-58-1 C3H4OS
    2-Thioxo-propionaldehyde
    —— (Z)-2-phenylthio-1-ethenyl acetyl selenide 105590-43-0 C10H10OSSe
    (Z)-2-phenylthio-1-ethenyl acetyl selenide
    —— 2,2-dimethyl-2,3-dihydrobenzothiophene-7-carboxylic acid 123656-28-0 C11H12O2S
    2,2-dimethyl-2,3-dihydrobenzothiophene-7-carboxylic acid
    —— 4-(4-(phenyl)thiazol-2-yl)thio-1-nitrobenzene 228401-28-3 C15H10N2O2S2
    4-(4-(phenyl)thiazol-2-yl)thio-1-nitrobenzene
    —— 2-chloro-6-oxo-7-carboxymethyl-5H-pyrido<2,3-b><1,4>thiazine 96662-19-0 C9H7ClN2O3S
    2-chloro-6-oxo-7-carboxymethyl-5H-pyrido<2,3-b><1,4>thiazine
    —— 2-(3-phenylsulfanylpropyl)cyclopentanone 77516-32-6 C14H18OS
    2-(3-phenylsulfanylpropyl)cyclopentanone
    —— methyl dithiopivalate 40920-16-9 C6H12S2
    methyl dithiopivalate
    —— 3-(5-hexylsulfanyl-3H-imidazol-4-yl)-pyridine 1073552-66-5 C14H19N3S
    3-(5-hexylsulfanyl-3H-imidazol-4-yl)-pyridine
    —— 3-[5-hexylsulfanyl-3-(2-trimethylsilanyl-ethoxymethyl)-3H-imidazol-4-yl]-pyridine 1073552-65-4 C20H33N3OSSi
    3-[5-hexylsulfanyl-3-(2-trimethylsilanyl-ethoxymethyl)-3H-imidazol-4-yl]-pyridine
    —— N-{4-[4-methyl-2-(7-methyl-[1,8]naphthyridin-4-ylamino)-phenylsulfanyl]-phenyl}-2-phenyl-butyramide 943616-43-1 C32H30N4OS
    N-{4-[4-methyl-2-(7-methyl-[1,8]naphthyridin-4-ylamino)-phenylsulfanyl]-phenyl}-2-phenyl-butyramide
    —— 2-allyl-[1,3]dithiane-2-carboxylic acid 71404-66-5 C8H12O2S2
    2-allyl-[1,3]dithiane-2-carboxylic acid
    —— 9-(2-hydroxyethylthio)octadecan-1-ol 1301263-36-4 C20H42O2S
    9-(2-hydroxyethylthio)octadecan-1-ol
    —— 4,6-dimethoxy-7-(p-tolylthio)hept-1-ene 190667-93-7 C16H24O2S
    4,6-dimethoxy-7-(p-tolylthio)hept-1-ene
    —— 5-methyl-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaen-11-ol 144918-78-5 C13H10N4OS
    5-methyl-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaen-11-ol
    —— 2-cyclohex-2-enyl-[1,3]dithiane-2-carboxylic acid 63048-49-7 C11H16O2S2
    2-cyclohex-2-enyl-[1,3]dithiane-2-carboxylic acid
    —— 1,5-bis-butylsulfanyl-pentane 13344-03-1 C13H28S2
    1,5-bis-butylsulfanyl-pentane
    —— 5-p-tolylthio-4-methoxypentan-2-one 95349-76-1 C13H18O2S
    5-p-tolylthio-4-methoxypentan-2-one
    —— 2-Methyl-mercapto-propen 7594-44-7 C4H8S
    2-Methyl-mercapto-propen
    —— 1-Chloro-4-(2-chloro-2-methoxy-ethylsulfanyl)-benzene 103200-21-1 C9H10Cl2OS
    1-Chloro-4-(2-chloro-2-methoxy-ethylsulfanyl)-benzene