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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-Trifluoroacetyl-1-thia-10-aza<2.2>metacyclophane 157556-75-7 C16H12F3NOS
    N-Trifluoroacetyl-1-thia-10-aza<2.2>metacyclophane
    —— trans-2,3-di(ethylthio)-2-butene 110468-65-0 C8H16S2
    trans-2,3-di(ethylthio)-2-butene
    —— 4-Methylsulfanyl-8-propyl-imidazo[1,5-d][1,2,4]triazine 97751-13-8 C9H12N4S
    4-Methylsulfanyl-8-propyl-imidazo[1,5-d][1,2,4]triazine
    —— 1-[4-(4-Ethoxyphenyl)-4-methylpentyl]-3-(phenylsulfanyl)benzene 89764-71-6 C26H30OS
    1-[4-(4-Ethoxyphenyl)-4-methylpentyl]-3-(phenylsulfanyl)benzene
    —— trans-2,3-di(propylthio)-2-butene 132064-54-1 C10H20S2
    trans-2,3-di(propylthio)-2-butene
    —— 1,3-bis(4-amino-1,2,4-triazol-3-ylsulfanylmethyl)benzene 1001126-56-2 C12H14N8S2
    1,3-bis(4-amino-1,2,4-triazol-3-ylsulfanylmethyl)benzene
    —— 1,3-bis(4-amino-5-benzyl-1,2,4-triazol-3-ylsulfanylmethyl)benzene 1001126-58-4 C26H26N8S2
    1,3-bis(4-amino-5-benzyl-1,2,4-triazol-3-ylsulfanylmethyl)benzene
    —— 3-(p-tolylthio)butan-2-one 54091-17-7 C11H14OS
    3-(p-tolylthio)butan-2-one
    —— 2,3-dihydro-2,5,6-trimethyl-1,4-dithiin 55789-63-4 C7H12S2
    2,3-dihydro-2,5,6-trimethyl-1,4-dithiin
    —— O-isopropyl S-3-oxobutan-2-yl dithiocarbonate 958649-73-5 C8H14O2S2
    O-isopropyl S-3-oxobutan-2-yl dithiocarbonate
    —— 4a,5,6,7,8,8a-hexahydro-2,3-dimethyl-1,4-benzodithiin 55789-69-0 C10H16S2
    4a,5,6,7,8,8a-hexahydro-2,3-dimethyl-1,4-benzodithiin
    —— 3-((4-bromophenyl)thio)butan-2-one 14207-14-8 C10H11BrOS
    3-((4-bromophenyl)thio)butan-2-one
    —— 2-[1-[3-(2-Pyridin-2-ylsulfanylbut-3-enyl)phenyl]but-3-en-2-ylsulfanyl]pyridine 479196-16-2 C24H24N2S2
    2-[1-[3-(2-Pyridin-2-ylsulfanylbut-3-enyl)phenyl]but-3-en-2-ylsulfanyl]pyridine
    —— α,α'-bis((o-aminophenyl)thio)-meta-xylene 354579-75-2 C20H20N2S2
    α,α'-bis((o-aminophenyl)thio)-meta-xylene
    —— 2,6-dimethyl-4-(methylthio)-3-nitropyridine 215589-46-1 C8H10N2O2S
    2,6-dimethyl-4-(methylthio)-3-nitropyridine
    —— 3-amino-2,6-dimethyl-4-(methylthio)pyridine 215589-47-2 C8H12N2S
    3-amino-2,6-dimethyl-4-(methylthio)pyridine
    —— 4-(furan-2-ylmethylsulfanyl)pyridine 71831-73-7 C10H9NOS
    4-(furan-2-ylmethylsulfanyl)pyridine
    —— Methyl 2-(pyridin-4-ylthio)acetate 78526-48-4 C8H9NO2S
    Methyl 2-(pyridin-4-ylthio)acetate
    —— methyl 3-(pyridin-4-ylthio)propanoate 78526-49-5 C9H11NO2S
    methyl 3-(pyridin-4-ylthio)propanoate
    —— 4-methyl-2-(phenylthio)thiazole 33342-68-6 C10H9NS2
    4-methyl-2-(phenylthio)thiazole
    —— 2-fluoro-4-(phenylthio)phenol 1350814-80-0 C12H9FOS
    2-fluoro-4-(phenylthio)phenol
    —— N-[2-(Diethylamino)ethyl]-N'-methylthiourea 109315-06-2 C8H19N3S
    N-[2-(Diethylamino)ethyl]-N'-methylthiourea
    —— (E)-methyl 2-phenylthio-3-pentenoate 109542-08-7 C12H14O2S
    (E)-methyl 2-phenylthio-3-pentenoate
    —— 4-[(6,7-propylenedithio-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-85-4 C15H16N2S8
    4-[(6,7-propylenedithio-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— 3-methylthio-5-nitro-1,2,4-triazole 346631-19-4 C3H4N4O2S
    3-methylthio-5-nitro-1,2,4-triazole
    —— Trithiocarbonic acid allyl ester dodecyl ester 89622-75-3 C16H30S3
    Trithiocarbonic acid allyl ester dodecyl ester
    —— 1,2-dimethyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene 1314918-58-5 C10H12F6O4S2
    1,2-dimethyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene
    —— 1-methyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene 1314918-53-0 C9H10F6O4S2
    1-methyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene
    —— methyl 2-acetyl-5-((2,4-dimethylphenyl)thio)-5-(phenylthio)pentanoate 1266617-56-4 C22H26O3S2
    methyl 2-acetyl-5-((2,4-dimethylphenyl)thio)-5-(phenylthio)pentanoate
    —— 2,2-dimethyl-3,6-dithiaheptane 115171-99-8 C7H16S2
    2,2-dimethyl-3,6-dithiaheptane
    —— 4-[(6,7-ethylenedithio-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-81-0 C14H14N2S8
    4-[(6,7-ethylenedithio-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— (E)-methyl 2-methyl-2-phenylthiohex-3-enoate 109542-09-8 C14H18O2S
    (E)-methyl 2-methyl-2-phenylthiohex-3-enoate
    —— bis((2,4-dimethylphenyl)thio)methane 1266253-61-5 C17H20S2
    bis((2,4-dimethylphenyl)thio)methane
    —— (2-(2,4-dimethylphenylthio)ethyl)diphenylphosphine 864228-26-2 C22H23PS
    (2-(2,4-dimethylphenylthio)ethyl)diphenylphosphine
    —— 121781-86-0 C5H6OS2
    —— methyl 2-acetyl-5,5-bis((2,4-dimethylphenyl)thio)pentanoate 1266617-45-1 C24H30O3S2
    methyl 2-acetyl-5,5-bis((2,4-dimethylphenyl)thio)pentanoate
    —— 4-chloro-3-(2,4-dimethylphenylthio)-9H-thioxanthen-9-one 1372152-27-6 C21H15ClOS2
    4-chloro-3-(2,4-dimethylphenylthio)-9H-thioxanthen-9-one
    —— ethyl 2-acetyl-5-[(2,4-dimethylphenyl)thio]-5-(p-tolyl)pentanoate 1338781-69-3 C24H30O3S
    ethyl 2-acetyl-5-[(2,4-dimethylphenyl)thio]-5-(p-tolyl)pentanoate
    —— bis[4-(2,4-dimethylphenylsulfanyl)phenyl)sulfoxide 1112460-46-4 C28H26OS3
    bis[4-(2,4-dimethylphenylsulfanyl)phenyl)sulfoxide
    —— 2-((2,4 dimethylphenyl)thio)benzaldehyde 710961-37-8 C15H14OS
    2-((2,4 dimethylphenyl)thio)benzaldehyde
    —— 3-hydroxy-5-(methylsulfanyl)thiophene 128889-84-9 C5H6OS2
    3-hydroxy-5-(methylsulfanyl)thiophene
    —— 4-[(2,6,7-tris(methylthio)-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-78-5 C14H16N2S8
    4-[(2,6,7-tris(methylthio)-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— 2-mercapto-4-methylsulfanyl-6-oxo-1,6-dihydro-pyridine-3-carbonitrile 726695-79-0 C7H6N2OS2
    2-mercapto-4-methylsulfanyl-6-oxo-1,6-dihydro-pyridine-3-carbonitrile
    —— 4-[(6,7-benzo-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-79-6 C16H14N2S6
    4-[(6,7-benzo-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— (E)-1-[(2-pyridyl)thio]-1-propene 51388-93-3 C8H9NS
    (E)-1-[(2-pyridyl)thio]-1-propene
    —— 2-((3-(triethoxysilyl)propyl)thio)pyridine 656230-07-8 C14H25NO3SSi
    2-((3-(triethoxysilyl)propyl)thio)pyridine
    —— O-Propyl-N-<2-propylthiolcarbonato-ethyl>-carbamat 93480-41-2 C10H19NO4S
    O-Propyl-N-<2-propylthiolcarbonato-ethyl>-carbamat
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(thiophen-2-ylmethylthiomethyl)-pyridin-2(1H)-one 1025830-77-6 C20H20INOS3
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(thiophen-2-ylmethylthiomethyl)-pyridin-2(1H)-one
    —— (5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)carbamic acid phenyl ester 417722-25-9 C22H18N2O4S2
    (5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)carbamic acid phenyl ester
    —— N-(5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)-N'-(4-hydroxymethylphenyl)urea 417715-31-2 C23H21N3O4S2
    N-(5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)-N'-(4-hydroxymethylphenyl)urea