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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-bromophenylsulfanyl)benzaldehyde 1339428-87-3 C13H9BrOS
    2-(2-bromophenylsulfanyl)benzaldehyde
    —— 1-cyano-1-thioethyl (1'-ethoxy) cyclopentane 135986-77-5 C10H17NOS
    1-cyano-1-thioethyl (1'-ethoxy) cyclopentane
    —— 2-{[(Pentafluorophenyl)sulfanyl]methyl}pyridine 87578-06-1 C12H6F5NS
    2-{[(Pentafluorophenyl)sulfanyl]methyl}pyridine
    —— N-tert-butyl-2-methyl-2-phenylsulfanylbutanimidoyl cyanide 73172-04-0 C16H22N2S
    N-tert-butyl-2-methyl-2-phenylsulfanylbutanimidoyl cyanide
    —— N-<2-(4-methylphenylthio)-2-methylpropylidene>-2-propylamine 132065-23-7 C14H21NS
    N-<2-(4-methylphenylthio)-2-methylpropylidene>-2-propylamine
    —— 1,4-bis(4',6'-diaminopyrimidinyl-2'-thio)butane 92629-37-3 C12H18N8S2
    1,4-bis(4',6'-diaminopyrimidinyl-2'-thio)butane
    —— tert-butyl-[2-[[2-(4-chlorobutyl)-1,3-dithian-2-yl]methyl]-3-octadecoxypropoxy]-dimethylsilane 113897-23-7 C36H73ClO2S2Si
    tert-butyl-[2-[[2-(4-chlorobutyl)-1,3-dithian-2-yl]methyl]-3-octadecoxypropoxy]-dimethylsilane
    —— 2-(4-chlorobutyl)-3-methylthio-5-oxo-(2H)-1,2,4-triazine 179756-88-8 C8H12ClN3OS
    2-(4-chlorobutyl)-3-methylthio-5-oxo-(2H)-1,2,4-triazine
    —— 1-isothiocyano-1-ethyl-cyclohexane 68288-81-3 C9H15NS
    1-isothiocyano-1-ethyl-cyclohexane
    —— 7-(4-chlorobutyl)-9-isopropyl-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione 175143-36-9 C14H21ClN2O2S
    7-(4-chlorobutyl)-9-isopropyl-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione
    —— n-butyl 3-chloropropyl sulfide 14856-63-4 C7H15ClS
    n-butyl 3-chloropropyl sulfide
    —— (5-Chloro-1-phenylsulfanylpentyl)sulfanylbenzene 89593-92-0 C17H19ClS2
    (5-Chloro-1-phenylsulfanylpentyl)sulfanylbenzene
    —— 4-chloro-1-butanethiol 98019-02-4 C4H9ClS
    4-chloro-1-butanethiol
    —— (2S)-diethyl 1,1-difluoro-2-hydroxy-6-methyl-3-(4-methylphenylsulfenyl)-hept-5-enylphosphonate 246028-23-9 C19H29F2O4PS
    (2S)-diethyl 1,1-difluoro-2-hydroxy-6-methyl-3-(4-methylphenylsulfenyl)-hept-5-enylphosphonate
    —— 1-(2-morpholin-4-ylethyl)-3-[6-([1,2,4]triazolo[4,3-b]pyridazin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]urea 1116743-50-0 C19H20N8O2S2
    1-(2-morpholin-4-ylethyl)-3-[6-([1,2,4]triazolo[4,3-b]pyridazin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]urea
    —— 1-[6-(imidazo[1,2-a]pyrimidin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]-3-[2-(morpholin-4-yl)ethyl]urea 1205121-76-1 C20H21N7O2S2
    1-[6-(imidazo[1,2-a]pyrimidin-3-ylsulphanyl)-1,3-benzothiazol-2-yl]-3-[2-(morpholin-4-yl)ethyl]urea
    —— 1-<Bis(phenylthio)methyl>4-(dimethylamino)benzene 81162-82-5 C21H21NS2
    1-<Bis(phenylthio)methyl>4-(dimethylamino)benzene
    —— (4S,2E)-O-4,5-dihydroxyxypent-2-enyl S-methyl dithiocarbonate 172369-74-3 C7H12O3S2
    (4S,2E)-O-4,5-dihydroxyxypent-2-enyl S-methyl dithiocarbonate
    —— 3-Methylbut-3-ene-2-thione 81509-12-8 C5H8S
    3-Methylbut-3-ene-2-thione
    —— 7-(4-chlorobutyl)-9-methyl-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione 175143-24-5 C12H17ClN2O2S
    7-(4-chlorobutyl)-9-methyl-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione
    —— 7-(4-chlorobutyl)-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione 175143-40-5 C11H15ClN2O2S
    7-(4-chlorobutyl)-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione
    —— 9-benzyl-7-(4-chlorobutyl)-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione 175143-30-3 C18H21ClN2O2S
    9-benzyl-7-(4-chlorobutyl)-3,4-dihydro-2H,6H-pyrimido[6,1-b][1,3]thiazine-6,8(7H)-dione
    —— 3-[(2-amino-1,3-benzothiazol-6-yl)sulphanyl]-N-(tetrahydro-2H-pyran-4-yl)-[1,2,4]triazolo[4,3-b]pyridazin-6-amine 1239704-01-8 C17H17N7OS2
    3-[(2-amino-1,3-benzothiazol-6-yl)sulphanyl]-N-(tetrahydro-2H-pyran-4-yl)-[1,2,4]triazolo[4,3-b]pyridazin-6-amine
    —— 6-[(4-{3-[(2-amino-1,3-benzothiazol-6-yl)sulphanyl]-7,8-dihydro[1,2,4]triazolo[4,3-b]pyridazin-6-yl}phenyl)sulphanyl]-1,3-benzothiazol-2-amine 1116743-45-3 C25H18N8S4
    6-[(4-{3-[(2-amino-1,3-benzothiazol-6-yl)sulphanyl]-7,8-dihydro[1,2,4]triazolo[4,3-b]pyridazin-6-yl}phenyl)sulphanyl]-1,3-benzothiazol-2-amine
    —— N-(6-{[6-(tetrahydro-2H-pyran-4-ylamino)[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulphanyl}-1,3-benzothiazol-2-yl)acetamide 1239704-05-2 C19H19N7O2S2
    N-(6-{[6-(tetrahydro-2H-pyran-4-ylamino)[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulphanyl}-1,3-benzothiazol-2-yl)acetamide
    —— 6-{[6-(1-methyl-1H-pyrazol-4-yl)[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulphanyl}-1,3-benzothiazol-2-amine 1150888-60-0 C16H12N8S2
    6-{[6-(1-methyl-1H-pyrazol-4-yl)[1,2,4]triazolo[4,3-b]pyridazin-3-yl]sulphanyl}-1,3-benzothiazol-2-amine
    —— Dithiocarbonic acid O-cyclohex-2-enylmethyl ester S-methyl ester 126384-17-6 C9H14OS2
    Dithiocarbonic acid O-cyclohex-2-enylmethyl ester S-methyl ester
    —— 1-(3-naphthylsulfanyl)-2-vinylbenzene 1181645-55-5 C18H14S
    1-(3-naphthylsulfanyl)-2-vinylbenzene
    —— 2-(4-chlorobutylthio)pyridine 155967-80-9 C9H12ClNS
    2-(4-chlorobutylthio)pyridine
    —— Dithiocarbonic acid S-methyl ester O-(1-methyl-cyclopent-2-enylmethyl) ester 134889-53-5 C9H14OS2
    Dithiocarbonic acid S-methyl ester O-(1-methyl-cyclopent-2-enylmethyl) ester
    —— [(4-chlorobutyl)sulfanyl]-4-methyl-5-(4-methyl-1,3-oxazol-5-yl)-4H-1,2,4-triazole 1016977-06-2 C11H15ClN4OS
    [(4-chlorobutyl)sulfanyl]-4-methyl-5-(4-methyl-1,3-oxazol-5-yl)-4H-1,2,4-triazole
    —— N-{[6-(imidazo[1,2-a]pyridin-3-yl)sulphanyl]-1,3-benzothiazol-2-yl}cyclopropanecarboxamide 1205744-28-0 C18H14N4OS2
    N-{[6-(imidazo[1,2-a]pyridin-3-yl)sulphanyl]-1,3-benzothiazol-2-yl}cyclopropanecarboxamide
    —— 5-Methylspiro[1-benzothiophene-2,3'-oxolane]-2',3-dione 79003-40-0 C12H10O3S
    5-Methylspiro[1-benzothiophene-2,3'-oxolane]-2',3-dione
    —— 5-Nitrospiro[1-benzothiophene-2,1'-cyclopropane]-3-one 79003-11-5 C10H7NO3S
    5-Nitrospiro[1-benzothiophene-2,1'-cyclopropane]-3-one
    —— 2-benzyl-5-ethylsulfanyl-[1,3,4]thiadiazole 64837-43-0 C11H12N2S2
    2-benzyl-5-ethylsulfanyl-[1,3,4]thiadiazole
    —— (E)-2-Methyl-8-phenyl-5-phenylsulfanyl-5-trimethylsilanyl-non-3-en-2-ol 79409-75-9 C25H36OSSi
    (E)-2-Methyl-8-phenyl-5-phenylsulfanyl-5-trimethylsilanyl-non-3-en-2-ol
    —— 5-phenyl-3,4-dihydro-2H-1,6-benzothiazocine 76293-51-1 C16H15NS
    5-phenyl-3,4-dihydro-2H-1,6-benzothiazocine
    —— (Bicyclo[2.2.1]hept-5-en-2-yl)methanethiol 632325-23-6 C8H12S
    (Bicyclo[2.2.1]hept-5-en-2-yl)methanethiol
    —— n-butyl dithioacetate 69380-59-2 C6H12S2
    n-butyl dithioacetate
    —— 4-[((E)-2-Non-4-enyl)-[1,3]dithian-2-yl]-butyraldehyde 918343-96-1 C17H30OS2
    4-[((E)-2-Non-4-enyl)-[1,3]dithian-2-yl]-butyraldehyde
    —— 5-(Trifluoromethylthio)-2-(2,5-difluorophenylthio)benzaldehyde 83975-71-7 C14H7F5OS2
    5-(Trifluoromethylthio)-2-(2,5-difluorophenylthio)benzaldehyde
    —— [5-Chloro-2-(2,5-difluoro-phenylsulfanyl)-phenyl]-(1-methyl-piperidin-4-yl)-methanol 83986-23-6 C19H20ClF2NOS
    [5-Chloro-2-(2,5-difluoro-phenylsulfanyl)-phenyl]-(1-methyl-piperidin-4-yl)-methanol
    —— methyl R-(5',6'-dihydro-2'-oxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate 859911-65-2 C8H8O3S4
    methyl R-(5',6'-dihydro-2'-oxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate
    —— methyl (R)-(5',6'-dihydro-2'-thioxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate 859911-64-1 C8H8O2S5
    methyl (R)-(5',6'-dihydro-2'-thioxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate
    —— 2-Phenylsulfanylpent-4-enoic acid 84363-42-8 C11H12O2S
    2-Phenylsulfanylpent-4-enoic acid
    —— 8-Chloro-6-<1-(2-decanoyloxyethyl)-4-piperidyl>-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin 83975-88-6 C30H39ClFNO3S
    8-Chloro-6-<1-(2-decanoyloxyethyl)-4-piperidyl>-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin
    —— 2-(2,5-Difluorophenylthio)-5-methoxy-α-(1-methyl-4-piperidyl)benzyl Alcohol 83975-61-5 C20H23F2NO2S
    2-(2,5-Difluorophenylthio)-5-methoxy-α-(1-methyl-4-piperidyl)benzyl Alcohol
    —— 2-fluoro-8-methoxy-6H-dibenz<b,e>-1,4-oxathiepin 83975-60-4 C20H22FNO2S
    2-fluoro-8-methoxy-6H-dibenz<b,e>-1,4-oxathiepin
    —— 8-chloro-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin 84884-57-1 C13H8ClFOS
    8-chloro-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin
    —— [2-(2,5-Difluoro-phenylsulfanyl)-5-trifluoromethylsulfanyl-phenyl]-(1-methyl-piperidin-4-yl)-methanol 83975-66-0 C20H20F5NOS2
    [2-(2,5-Difluoro-phenylsulfanyl)-5-trifluoromethylsulfanyl-phenyl]-(1-methyl-piperidin-4-yl)-methanol