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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Propylsulfanyl-5-thiocyanatomethylsulfanyl-[1,3,4]thiadiazole 56492-69-4 C7H9N3S4
    2-Propylsulfanyl-5-thiocyanatomethylsulfanyl-[1,3,4]thiadiazole
    —— (2S)-1-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-3H-purin-3-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-ol trifluoroacetate 1156469-49-6 C2HF3O2*C23H27BrN6O4S
    (2S)-1-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-3H-purin-3-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-ol trifluoroacetate
    —— 3-(8-methyl-2-pyrido[2,3-b]pyrazin-7-ylsulfanyl-9H-pyrimido[4,5-b]indol-4-yl)-3-azabicyclo[3.1.0]hexan-6-amine 1400801-31-1 C23H20N8S
    3-(8-methyl-2-pyrido[2,3-b]pyrazin-7-ylsulfanyl-9H-pyrimido[4,5-b]indol-4-yl)-3-azabicyclo[3.1.0]hexan-6-amine
    —— 11-(4-chlorobutanoyl)-2,20-dimethyl-11-octanoyl[9,10,11,12,13,14]hexahydro-6H-dibenzo[1,7,4,10,13,16]dioxathiatriazaoctadecin-7,15(8H,16H)dione 1345977-71-0 C26H32ClN3O5S
    11-(4-chlorobutanoyl)-2,20-dimethyl-11-octanoyl[9,10,11,12,13,14]hexahydro-6H-dibenzo[1,7,4,10,13,16]dioxathiatriazaoctadecin-7,15(8H,16H)dione
    —— (2-Nitro-5-(phenylthio)benzyl) phenyl sulfide 93304-90-6 C19H15NO2S2
    (2-Nitro-5-(phenylthio)benzyl) phenyl sulfide
    —— N-Methyl-Na(2)-(2-methyl-3-oxobutyl)thiourea 3088-89-9 C7H14N2OS
    N-Methyl-Na(2)-(2-methyl-3-oxobutyl)thiourea
    —— 6-methylsulfanyl-[1,3,5]triazine-2,4-dicarboxylic acid diethyl ester 5516-49-4 C10H13N3O4S
    6-methylsulfanyl-[1,3,5]triazine-2,4-dicarboxylic acid diethyl ester
    —— Thiophosphoric acid S-(2,2-bis-p-tolylsulfanyl-propyl) ester O,O'-diethyl ester 100407-96-3 C21H29O3PS3
    Thiophosphoric acid S-(2,2-bis-p-tolylsulfanyl-propyl) ester O,O'-diethyl ester
    —— (4-Chloro-phenylsulfanyl)-(ethyl-methoxy-phosphinothioylsulfanyl)-acetic acid ethyl ester 60178-14-5 C13H18ClO3PS3
    (4-Chloro-phenylsulfanyl)-(ethyl-methoxy-phosphinothioylsulfanyl)-acetic acid ethyl ester
    —— 4-Thiocyanato-benzaldehydthiosemicarbzon 40104-28-7 C9H8N4S2
    4-Thiocyanato-benzaldehydthiosemicarbzon
    —— (R)-<1-2H>putrescine dihydrochloride 83544-62-1 C4H12N2*2ClH
    (R)-<1-2H>putrescine dihydrochloride
    —— Malonsaeuredi-S-2-chlorethylester 27980-99-0 C7H10Cl2O2S2
    Malonsaeuredi-S-2-chlorethylester
    —— 3-(eicosane-1-sulfonyl)-prop-2-en-1-ol 63067-96-9 C23H46O3S
    3-(eicosane-1-sulfonyl)-prop-2-en-1-ol
    —— 4-(4-nitro-phenylsulfanyl)-pyridine-1-oxide 853916-60-6 C11H8N2O3S
    4-(4-nitro-phenylsulfanyl)-pyridine-1-oxide
    —— 1-Chlor-4-<4-chlor-phenylmercapto>-butan 14366-69-9 C10H12Cl2S
    1-Chlor-4-<4-chlor-phenylmercapto>-butan
    —— 3,5-bis(trifluoromethyl)phenyl 4-chlorophenyl sulfide 1393715-60-0 C14H7ClF6S
    3,5-bis(trifluoromethyl)phenyl 4-chlorophenyl sulfide
    —— 3,6-bis(thiocyanato)-2,7,7-trimethyl-2,5-octadiene 234773-55-8 C13H18N2S2
    3,6-bis(thiocyanato)-2,7,7-trimethyl-2,5-octadiene
    —— 2-(1-chloro-ethylsulfanyl)-2-methyl-propane 72961-47-8 C6H13ClS
    2-(1-chloro-ethylsulfanyl)-2-methyl-propane
    —— [(Z)-2-[(2R,3S,6R)-3-(2-methoxypropan-2-yloxy)-6-[(2-methylpropan-2-yl)oxy]oxan-2-yl]-1-phenylsulfanylethenyl]-trimethylsilane 107108-71-4 C24H40O4SSi
    [(Z)-2-[(2R,3S,6R)-3-(2-methoxypropan-2-yloxy)-6-[(2-methylpropan-2-yl)oxy]oxan-2-yl]-1-phenylsulfanylethenyl]-trimethylsilane
    —— Phenyl-(5-prop-2-ynylsulfanyl-[1,3,4]thiadiazol-2-yl)-amine 53918-25-5 C11H9N3S2
    Phenyl-(5-prop-2-ynylsulfanyl-[1,3,4]thiadiazol-2-yl)-amine
    —— 3-(5-nitro-thiazol-2-ylsulfanyl)-5,6-diphenyl-[1,2,4]triazine 40045-65-6 C18H11N5O2S2
    3-(5-nitro-thiazol-2-ylsulfanyl)-5,6-diphenyl-[1,2,4]triazine
    —— Pd{bis{o-(methylthio)phenyl}phenylphosphino}Br2 141446-47-1 C20H19Br2PPdS2
    Pd{bis{o-(methylthio)phenyl}phenylphosphino}Br2
    —— Aethylcadmium-thiocyanat 24697-46-9 C3H5CdNS
    Aethylcadmium-thiocyanat
    —— [2-(2-Benzylsulfanylphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]oxy-tert-butyl-dimethylsilane 185030-87-9 C22H26F6OSSi
    [2-(2-Benzylsulfanylphenyl)-1,1,1,3,3,3-hexafluoropropan-2-yl]oxy-tert-butyl-dimethylsilane
    —— indium(III) tris(di-n-propyldithiocarbamate) 87052-01-5 C21H42InN3S6
    indium(III) tris(di-n-propyldithiocarbamate)
    —— 2,2-dimethyl-butyryl isothiocyanate 118873-27-1 C7H11NOS
    2,2-dimethyl-butyryl isothiocyanate
    —— 5-methylsulfanyl-selenophene-2-carboxylic acid 36710-44-8 C6H6O2SSe
    5-methylsulfanyl-selenophene-2-carboxylic acid
    —— [3aR-(3aα,4α,6α,6aα)]-6-[[5-amino-6-chloro-2-(propylthio)-4-pyrimidinyl]amino]-tetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxole-4-carboxylic acid 209737-59-7 C16H23ClN4O4S
    [3aR-(3aα,4α,6α,6aα)]-6-[[5-amino-6-chloro-2-(propylthio)-4-pyrimidinyl]amino]-tetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxole-4-carboxylic acid
    —— 4-Chlor-1-<2-heptylmercapto-aethylmercapto>-benzol 29960-09-6 C15H23ClS2
    4-Chlor-1-<2-heptylmercapto-aethylmercapto>-benzol
    —— 4-Chlor-1-<2-isopropylmercapto-aethylmercapto>-benzol 29960-03-0 C11H15ClS2
    4-Chlor-1-<2-isopropylmercapto-aethylmercapto>-benzol
    —— (4-Bromphenyl)-dimethylaminomethyl-sulfid 22959-42-8 C9H12BrNS
    (4-Bromphenyl)-dimethylaminomethyl-sulfid
    —— 3-acetylamino-3-deoxy-D-allose-diethyldithioacetal 22617-60-3 C12H25NO5S2
    3-acetylamino-3-deoxy-D-allose-diethyldithioacetal
    —— 2-[1-(2-Fluoro-phenyl)-meth-(Z)-ylidene]-5-nitro-benzo[b]thiophen-3-one 38387-62-1 C15H8FNO3S
    2-[1-(2-Fluoro-phenyl)-meth-(Z)-ylidene]-5-nitro-benzo[b]thiophen-3-one
    —— 4-(3-chlorophenylthio)quinazoline 93354-26-8 C14H9ClN2S
    4-(3-chlorophenylthio)quinazoline
    —— Dithiokohlensaeure-S-<2-chlor-aethylester>-S'-propylester 91313-04-1 C6H11ClOS2
    Dithiokohlensaeure-S-<2-chlor-aethylester>-S'-propylester
    —— 13420-61-6 C14H10ClNS
    —— Aethyl-<3-chlor-phenyl>-trithiocarbonat 91367-20-3 C9H9ClS3
    Aethyl-<3-chlor-phenyl>-trithiocarbonat
    —— di-1-(1,3-butadienyl) sulfide (cis,cis) 75299-04-6 C8H10S
    di-1-(1,3-butadienyl) sulfide (cis,cis)
    —— 4-Phenyl-2-phenylsulfanylmethyl-cyclopentanone 127869-20-9 C18H18OS
    4-Phenyl-2-phenylsulfanylmethyl-cyclopentanone
    —— 1,1,1,3,3,3-hexafluoro-2-<(phenylthio)methyl>-2-propanol 99562-43-3 C10H8F6OS
    1,1,1,3,3,3-hexafluoro-2-<(phenylthio)methyl>-2-propanol
    —— tris(2-isothiocyanatoethyl)amine 355850-96-3 C9H12N4S3
    tris(2-isothiocyanatoethyl)amine
    —— 2-(dimethyl-d6-amino)ethanethiol 1093060-02-6 C4H11NS
    2-(dimethyl-d6-amino)ethanethiol
    —— Azo-thiodicarbonsaeure-O,S-diaethylester 118728-36-2 C6H10N2O3S
    Azo-thiodicarbonsaeure-O,S-diaethylester
    —— Methyl-9,10-tetraoxy-thianthrenylacetat-2 36036-47-2 C15H12O6S2
    Methyl-9,10-tetraoxy-thianthrenylacetat-2
    —— (1S-cis)-4-[[5-Amino-6-chloro-2-(propylthio)pyrimidin-4-yl]amino]-2-cyclopenten-1-ol 220348-88-9 C12H17ClN4OS
    (1S-cis)-4-[[5-Amino-6-chloro-2-(propylthio)pyrimidin-4-yl]amino]-2-cyclopenten-1-ol
    —— (3-Methyl-allyl)-thiocyanat 2253-92-1 C5H7NS
    (3-Methyl-allyl)-thiocyanat
    —— ethyl 2H-1,4-benzoxathiane-2-carboximidoate hydrochloride 116158-94-2 C11H13NO2S*ClH
    ethyl 2H-1,4-benzoxathiane-2-carboximidoate hydrochloride
    —— 1-Dithiobenzoyloxyethylphenylsulfid 37912-40-6 C15H14S3
    1-Dithiobenzoyloxyethylphenylsulfid
    —— (p-Chlorphenylthio)essigsaeure-butylester 15446-19-2 C12H15ClO2S
    (p-Chlorphenylthio)essigsaeure-butylester
    —— {(2,2'-bipyridine)cadmium bis(BuSCSS)} 104506-94-7 C20H26CdN2S6
    {(2,2'-bipyridine)cadmium bis(BuSCSS)}