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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1344734-80-0 C27H54Br2S2
    —— 4-amino-2-((3-chlorophenyl)thio)benzonitrile 1352622-27-5 C13H9ClN2S
    4-amino-2-((3-chlorophenyl)thio)benzonitrile
    —— [(Isopropoxy-methyl-phosphinoyl)-(pyridin-2-ylsulfanyl)-methyl]-phosphonic acid diethyl ester 120457-10-5 C14H25NO5P2S
    [(Isopropoxy-methyl-phosphinoyl)-(pyridin-2-ylsulfanyl)-methyl]-phosphonic acid diethyl ester
    —— 2-(4-Methoxy-phenylsulfanyl)-5-(3-p-tolyl-thioureido)-benzoic acid 78160-53-9 C22H20N2O3S2
    2-(4-Methoxy-phenylsulfanyl)-5-(3-p-tolyl-thioureido)-benzoic acid
    —— 2-Carboxymethylmercapto-1-benzyl-4,7-dihydroxy-1H-imidazo<4,5-d>pyridazin 5012-82-8 C14H12N4O4S
    2-Carboxymethylmercapto-1-benzyl-4,7-dihydroxy-1H-imidazo<4,5-d>pyridazin
    —— ((E)-N-Propenyl)-thioacetamide 56634-58-3 C5H9NS
    ((E)-N-Propenyl)-thioacetamide
    —— (2R,3S)-(+)-2-ethyl-2-(3'-hydroxy-5'-phenylthio-amyl)-3-hydroxy-cyclopentanone 101750-89-4 C18H26O3S
    (2R,3S)-(+)-2-ethyl-2-(3'-hydroxy-5'-phenylthio-amyl)-3-hydroxy-cyclopentanone
    —— 1-Cyanocyclobutane-1-sulfonyl fluoride 2361636-16-8 C5H6FNO2S
    1-Cyanocyclobutane-1-sulfonyl fluoride
    —— 2,3-Di(1-adamantyl)thiaziridin-1,1-dioxid 78077-02-8 C21H31NO2S
    2,3-Di(1-adamantyl)thiaziridin-1,1-dioxid
    —— 1-Thiocyanato-4-isothiocyanato-benzol 18879-74-8 C8H4N2S2
    1-Thiocyanato-4-isothiocyanato-benzol
    —— (E,E)-54,7-nonadien-1-thiol 86869-84-3 C9H16S
    (E,E)-54,7-nonadien-1-thiol
    —— 3-(4-fluorophenylthio)-2-(phenylthio)-2-propenoic acid 1154687-73-6 C15H11FO2S2
    3-(4-fluorophenylthio)-2-(phenylthio)-2-propenoic acid
    —— N-(3-(6-amino-8-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)propyl)isobutyramide 1402546-14-8 C19H21IN6O3S
    N-(3-(6-amino-8-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)propyl)isobutyramide
    —— 5-(5-amino-6-methylamino-pyrimidin-4-ylsulfanyl)-pentanoic acid 27032-56-0 C10H16N4O2S
    5-(5-amino-6-methylamino-pyrimidin-4-ylsulfanyl)-pentanoic acid
    —— (S)-N-<<3-<4-<(fluoromethyl)thio>phenyl>-2-oxo-5-oxazolidinyl>methyl>acetamide 128781-59-9 C13H15FN2O3S
    (S)-N-<<3-<4-<(fluoromethyl)thio>phenyl>-2-oxo-5-oxazolidinyl>methyl>acetamide
    —— [Sm(nitrate)3(2-(N-indole-2-one)amino-3-carboxyethyl-4,5,6,7-tetrahydrobenzo[b]thiophene)] 1000623-59-5 C19H18N5O12SSm
    [Sm(nitrate)3(2-(N-indole-2-one)amino-3-carboxyethyl-4,5,6,7-tetrahydrobenzo[b]thiophene)]
    —— 2,3-bis((3-chlorophenyl)thio)-6-hydroxy-9-methyl-1H-carbazole-1,4(9H)-dione 1265166-55-9 C25H15Cl2NO3S2
    2,3-bis((3-chlorophenyl)thio)-6-hydroxy-9-methyl-1H-carbazole-1,4(9H)-dione
    —— acetic acid 3-[6-amino-8-(2-iodo-5-methoxy-phenylsulfanyl)purin-9-yl]propyl ester 839725-86-9 C17H18IN5O3S
    acetic acid 3-[6-amino-8-(2-iodo-5-methoxy-phenylsulfanyl)purin-9-yl]propyl ester
    —— 2-(4-chloro-phenylsulfanyl)-3H-pyrimidin-4-one 31170-29-3 C10H7ClN2OS
    2-(4-chloro-phenylsulfanyl)-3H-pyrimidin-4-one
    —— 3-(m-tolylthio)-1H-indole 32884-75-6 C15H13NS
    3-(m-tolylthio)-1H-indole
    —— Dimethyl-<2,3-bis-guanylmercapto-propyl>-amin 45123-41-9 C7H17N5S2
    Dimethyl-<2,3-bis-guanylmercapto-propyl>-amin
    —— 56717-69-2 C9H6F5NOS
    —— (1-Chloro-2-methyl-2-vinyl-cyclopropylsulfanyl)-benzene 34678-56-3 C12H13ClS
    (1-Chloro-2-methyl-2-vinyl-cyclopropylsulfanyl)-benzene
    —— 3-((3-chlorophenyl)thio)-1H-indole 1369558-80-4 C14H10ClNS
    3-((3-chlorophenyl)thio)-1H-indole
    —— 2-[4-(1-adamantyl)benzylsulfanyl]-6-methyl-pyrimidin-4(3H)-one 911838-00-1 C22H26N2OS
    2-[4-(1-adamantyl)benzylsulfanyl]-6-methyl-pyrimidin-4(3H)-one
    —— (1-tert-butylsulfanyl)-2-(2,2-dichlorovinyl)benzenethiol 1191415-85-6 C12H14Cl2S
    (1-tert-butylsulfanyl)-2-(2,2-dichlorovinyl)benzenethiol
    —— 4-anilino-3-cyano-2-ethoxycarbonylmethylthiopyridine 147992-90-3 C16H15N3O2S
    4-anilino-3-cyano-2-ethoxycarbonylmethylthiopyridine
    —— 3,6-difluoro-1,2-bis(p-tolylthio)benzene 1055876-49-7 C20H16F2S2
    3,6-difluoro-1,2-bis(p-tolylthio)benzene
    —— Dithiokohlensaeure-O-(3-dimethylamino-propylester)-S-methylester 89855-30-1 C7H15NOS2
    Dithiokohlensaeure-O-(3-dimethylamino-propylester)-S-methylester
    —— O-(2-methylpropyl) N-(sulfanylidenemethylidene)carbamothioate 885475-09-2 C6H9NOS2
    O-(2-methylpropyl) N-(sulfanylidenemethylidene)carbamothioate
    —— 5-((4-isopropylphenyl)thio)-3-(1-methylpiperidin-4-yl)-1H-indazole 1172131-12-2 C22H27N3S
    5-((4-isopropylphenyl)thio)-3-(1-methylpiperidin-4-yl)-1H-indazole
    —— ethyl 4-(((4-chlorophenyl)thio)methyl)-1,2,3-thiadiazole-5-carboxylate 1369849-04-6 C12H11ClN2O2S2
    ethyl 4-(((4-chlorophenyl)thio)methyl)-1,2,3-thiadiazole-5-carboxylate
    —— (5-amino-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol 1062599-70-5 C14H15NO2S
    (5-amino-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol
    —— N,N-dimethyl-2-(4'-acetoxymethyl-2'-nitrophenylthio)-5-fluoro-benzamide 1005412-90-7 C18H17FN2O5S
    N,N-dimethyl-2-(4'-acetoxymethyl-2'-nitrophenylthio)-5-fluoro-benzamide
    —— (4S)-3-[(2S,3S,4S)-3-hydroxy-2,4-dimethyl-5-phenylsulfanylpentanoyl]-4-propan-2-yl-1,3-oxazolidin-2-one 116776-75-1 C19H27NO4S
    (4S)-3-[(2S,3S,4S)-3-hydroxy-2,4-dimethyl-5-phenylsulfanylpentanoyl]-4-propan-2-yl-1,3-oxazolidin-2-one
    —— Ethyl 4-(3-chlorophenyl)sulfanyl-5,6,7,8-tetrahydroisoquinoline-1-carboxylate 1357186-83-4 C18H18ClNO2S
    Ethyl 4-(3-chlorophenyl)sulfanyl-5,6,7,8-tetrahydroisoquinoline-1-carboxylate
    —— 3-methylthio-5-(4-fluorophenyl)-6-phenyl-1,2,4-triazine 1616468-86-0 C16H12FN3S
    3-methylthio-5-(4-fluorophenyl)-6-phenyl-1,2,4-triazine
    —— (3R,E)-2-iodo-4-methyl-1-phenylthio-1-nonen-3-ol 1316858-25-9 C15H21IOS
    (3R,E)-2-iodo-4-methyl-1-phenylthio-1-nonen-3-ol
    —— (2-hexylcyclopent-1-en-1-yl)(phenyl)sulfane 58567-72-9 C17H24S
    (2-hexylcyclopent-1-en-1-yl)(phenyl)sulfane
    —— (2S)-12-<2'-Hydroxy-3'-(phenylthio)phenyl>-2-dodecanol 107495-65-8 C24H34O2S
    (2S)-12-<2'-Hydroxy-3'-(phenylthio)phenyl>-2-dodecanol
    —— 2,12-Dihexyl-5,6,7,8,15,16,17,18-octakis(phenylsulfanyl)-10,20-dithiapentacyclo[11.7.0.03,11.04,9.014,19]icosa-1(13),2,4(9),5,7,11,14(19),15,17-nonaene 1043877-67-3 C78H66S10
    2,12-Dihexyl-5,6,7,8,15,16,17,18-octakis(phenylsulfanyl)-10,20-dithiapentacyclo[11.7.0.03,11.04,9.014,19]icosa-1(13),2,4(9),5,7,11,14(19),15,17-nonaene
    —— Dithiocarbonic acid O-((Z)-(3aR,6aR,9aS,10S,10aR)-6,10a-dimethyl-1,2,3,3a,4,6a,9,9a,10,10a-decahydro-dicyclopenta[a,d]cycloocten-10-yl) ester S-methyl ester 94137-66-3 C18H26OS2
    Dithiocarbonic acid O-((Z)-(3aR,6aR,9aS,10S,10aR)-6,10a-dimethyl-1,2,3,3a,4,6a,9,9a,10,10a-decahydro-dicyclopenta[a,d]cycloocten-10-yl) ester S-methyl ester
    —— 1-(2,6-dichloro-benzyl)-5-(2,4-dinitro-phenylsulfanyl)-1,4-dihydro-pyridine-3-carboxylic acid amide 109693-61-0 C19H14Cl2N4O5S
    1-(2,6-dichloro-benzyl)-5-(2,4-dinitro-phenylsulfanyl)-1,4-dihydro-pyridine-3-carboxylic acid amide
    —— 2,5-dimethyl-7-methylsulfanyl-5<i>H</i>-pyrazolo[1,5-<i>d</i>][1,2,4]triazin-4-one 40535-04-4 C8H10N4OS
    2,5-dimethyl-7-methylsulfanyl-5<i>H</i>-pyrazolo[1,5-<i>d</i>][1,2,4]triazin-4-one
    —— 4-Acetamido-2-amino-7-phenyl-6-phenylthiopteridin 56107-52-9 C20H16N6OS
    4-Acetamido-2-amino-7-phenyl-6-phenylthiopteridin
    —— 4-Phenylthiocyclohexanon-semicarbazon 34259-62-6 C13H17N3OS
    4-Phenylthiocyclohexanon-semicarbazon
    —— 2,2'-Bis-(pyridyl-3'-thio)-diethylsulfid 21910-78-1 C14H16N2S3
    2,2'-Bis-(pyridyl-3'-thio)-diethylsulfid
    —— -(5-Ethyl-2-methylsulfanyl-thiophen-3-yl)-N,N'-di-pyridin-2-yl-methanediamine 38059-35-7 C18H20N4S2
    -(5-Ethyl-2-methylsulfanyl-thiophen-3-yl)-N,N'-di-pyridin-2-yl-methanediamine
    —— 39891-69-5 C10H10OS
    —— 3-Phenylthio-3-propylthio-1-(2-thienyl)-2-propen-1-on 35308-30-6 C16H16OS3
    3-Phenylthio-3-propylthio-1-(2-thienyl)-2-propen-1-on