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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Methyl-2-(3-methylsulfanyl-4-thiocarbamoyl-phenyl)-malonic acid diethyl ester 138569-06-9 C16H21NO4S2
    2-Methyl-2-(3-methylsulfanyl-4-thiocarbamoyl-phenyl)-malonic acid diethyl ester
    —— S-phenyl 6-oxo-8-phenylthio-4-azaoct-2-enethioate 82896-09-1 C19H19NO2S2
    S-phenyl 6-oxo-8-phenylthio-4-azaoct-2-enethioate
    —— chromium(III) (2Z,2'Z)-1,1'-((ethane-1,2-diylbis(sulfanediyl))bis(2,1-phenylene))bis(3-methyl-3-oxidotriaz-2-en-1-ide) perchlorate 171260-90-5 C16H18N6O2S2*ClO4*Cr
    chromium(III) (2Z,2'Z)-1,1'-((ethane-1,2-diylbis(sulfanediyl))bis(2,1-phenylene))bis(3-methyl-3-oxidotriaz-2-en-1-ide) perchlorate
    —— 2-(eicosane-1-sulfonyl)-prop-2-en-1-ol 63067-97-0 C23H46O3S
    2-(eicosane-1-sulfonyl)-prop-2-en-1-ol
    —— bis-(4-benzenesulfonyl-2-nitro-phenyl)-sulfide 102542-98-3 C24H16N2O8S3
    bis-(4-benzenesulfonyl-2-nitro-phenyl)-sulfide
    —— chloropromazine cation radical 50-53-3 C17H19ClN2S
    chloropromazine cation radical
    —— (E)-2-chlorovinyl 2-pyridinyl sulfide 558438-96-3 C7H6ClNS
    (E)-2-chlorovinyl 2-pyridinyl sulfide
    —— 4,6-Di(2-acetamidophenylthio)-5-nitro-2-dimethylaminopyrimidin 37412-41-2 C22H22N6O4S2
    4,6-Di(2-acetamidophenylthio)-5-nitro-2-dimethylaminopyrimidin
    —— ethyl 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-phenylacetate 108207-45-0 C14H14N2O3S
    ethyl 2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-phenylacetate
    —— 2,4-dimethylpent-2-ene-3-thiol 86748-24-5 C7H13S
    2,4-dimethylpent-2-ene-3-thiol
    —— bromure de crotyl magnesium 36306-56-6 C4H7BrMg
    bromure de crotyl magnesium
    —— 2-but-3-ynylsulfanyl-1H-pyrimidin-6-one 90997-84-5 C8H8N2OS
    2-but-3-ynylsulfanyl-1H-pyrimidin-6-one
    —— trans-[Co(N,N-bis(pyridine-2-carboxamido)-4-methylbenzene(2-))(piperidine)2]ClO4 1071554-32-9 C29H36CoN6O2*ClO4
    trans-[Co(N,N-bis(pyridine-2-carboxamido)-4-methylbenzene(2-))(piperidine)2]ClO4
    —— 1010703-85-1 C13H16O3S
    —— 2-(2,5-dihydroxyphenylsulfanyl)-6-propyl-1H-pyrimidin-4-one 1611453-74-7 C13H14N2O3S
    2-(2,5-dihydroxyphenylsulfanyl)-6-propyl-1H-pyrimidin-4-one
    —— ethyl N-phenylthio-4-methylpent-4-enylcarbamate 1039553-35-9 C15H21NO2S
    ethyl N-phenylthio-4-methylpent-4-enylcarbamate
    —— bis(1-methylheptylidene)-carbonothioic dihydrazide 25183-33-9 C17H34N4S
    bis(1-methylheptylidene)-carbonothioic dihydrazide
    —— 6-Ethyl-1,3-dimethyl-thiocytosin 35218-95-2 C8H13N3OS
    6-Ethyl-1,3-dimethyl-thiocytosin
    —— 3-undecylsulfinyl-2-undecyloxy-1-propanol 1230401-44-1 C25H52O3S
    3-undecylsulfinyl-2-undecyloxy-1-propanol
    —— 2-Cyano-thioacetimidic acid methyl ester; hydrochloride 120634-16-4 C4H6N2S*ClH
    2-Cyano-thioacetimidic acid methyl ester; hydrochloride
    —— 24505-90-6 C22H23OPS2
    —— 2,6,2',6'-tetra-<i>tert</i>-butyl-4,4'-[2,2,2',2'-tetramethyl-3,3'-(6-phenylsulfanyl-[1,3,5]triazine-2,4-diyldiamino)-dipropyl]-bis-phenol 57717-73-4 C47H69N5O2S
    2,6,2',6'-tetra-<i>tert</i>-butyl-4,4'-[2,2,2',2'-tetramethyl-3,3'-(6-phenylsulfanyl-[1,3,5]triazine-2,4-diyldiamino)-dipropyl]-bis-phenol
    —— Ethenesulfonic acid [4-(4-amino-phenylsulfanyl)-phenyl]-amide 92245-93-7 C14H14N2O2S2
    Ethenesulfonic acid [4-(4-amino-phenylsulfanyl)-phenyl]-amide
    —— 6-(p-Bromphenylthio)-1,2,3-benzothiadiazol 23616-03-7 C12H7BrN2S2
    6-(p-Bromphenylthio)-1,2,3-benzothiadiazol
    —— Ag(CN)(1-methyl-2-thiourea) 289908-87-8 Ag*CN*C2H6N2S
    Ag(CN)(1-methyl-2-thiourea)
    —— 3-((4-chlorophenyl)thio)pyridine 28856-78-2 C11H8ClNS
    3-((4-chlorophenyl)thio)pyridine
    —— <4-Bromphenyl>-<bis-(2-hydroxyaethyl)-aminomethyl>-sulfid 22959-45-1 C11H16BrNO2S
    <4-Bromphenyl>-<bis-(2-hydroxyaethyl)-aminomethyl>-sulfid
    —— [1,1,1,3,3,3-hexafluoro-2-(2,3,4,5,6-pentafluorophenyl)sulfanylpropan-2-yl]oxy-trimethylsilane 78550-34-2 C12H9F11OSSi
    [1,1,1,3,3,3-hexafluoro-2-(2,3,4,5,6-pentafluorophenyl)sulfanylpropan-2-yl]oxy-trimethylsilane
    —— [2-(3-Chloro-phenylsulfanyl)-phenyl]-acetic acid 13420-62-7 C14H11ClO2S
    [2-(3-Chloro-phenylsulfanyl)-phenyl]-acetic acid
    —— 2-Octyl-S-(6-hydroxy-4-methyl-2-pyrimidyl)-thioglycolat 21418-98-4 C15H24N2O3S
    2-Octyl-S-(6-hydroxy-4-methyl-2-pyrimidyl)-thioglycolat
    —— 12694-16-5 C23H18N2O2S2
    —— 3,7-Difluor-5-hydroxy-5-oxo-dibenzo<b,e>thiaphosphor(V)-in 31121-34-3 C12H7F2O2PS
    3,7-Difluor-5-hydroxy-5-oxo-dibenzo<b,e>thiaphosphor(V)-in
    —— [BrAg(N,N'-diethylthiourea)3] 891854-80-1 C15H36AgBrN6S3
    [BrAg(N,N'-diethylthiourea)3]
    —— ethyl 2,2-bis(methylthio)cyclohexylacetaldehyde 73434-25-0 C10H18OS2
    ethyl 2,2-bis(methylthio)cyclohexylacetaldehyde
    —— 6-pentyl-6-thiocyanatoundecane 919474-62-7 C17H33NS
    6-pentyl-6-thiocyanatoundecane
    —— N-(4-((6-amino-4-((5-methyl-1H-pyrazol-3-yl)amino)pyrrolo[2,1-f][1,2,4]triazin-2-yl)thio)phenyl)cyclopropanecarboxamide 1334320-78-3 C20H20N8OS
    N-(4-((6-amino-4-((5-methyl-1H-pyrazol-3-yl)amino)pyrrolo[2,1-f][1,2,4]triazin-2-yl)thio)phenyl)cyclopropanecarboxamide
    —— ethyl 2-(1-cyclopentenyl)-2-phenylthioethyl malonate 128886-19-1 C18H22O4S
    ethyl 2-(1-cyclopentenyl)-2-phenylthioethyl malonate
    —— 2-<4-Methyl-thienyl-(2)>-2-pentadecyl-1,3-dithiolan 26448-81-7 C23H40S3
    2-<4-Methyl-thienyl-(2)>-2-pentadecyl-1,3-dithiolan
    —— 4-Methyl-4-phenyl-[1,7,3,5]dioxadithionane 3,3,5,5-tetraoxide 23596-86-3 C12H16O6S2
    4-Methyl-4-phenyl-[1,7,3,5]dioxadithionane 3,3,5,5-tetraoxide
    —— 4-<Methoxy(thiocarbonyl)>allophansaeure-ethylester 78476-54-7 C6H10N2O4S
    4-<Methoxy(thiocarbonyl)>allophansaeure-ethylester
    —— 87464-69-5 C11H24S4*Cu
    —— 4-(2-methylfuran-3-ylthio)-5-(3-(methylsulfonyl)phenyl)thieno[2,3-d]pyrimidine 1370338-33-2 C18H14N2O3S3
    4-(2-methylfuran-3-ylthio)-5-(3-(methylsulfonyl)phenyl)thieno[2,3-d]pyrimidine
    —— methyl 2-{2-[(E)-4-oxopent-2-en-2-ylamino]ethylamino}cyclopent-1-enecarbodithioate 1403783-14-1 C14H22N2OS2
    methyl 2-{2-[(E)-4-oxopent-2-en-2-ylamino]ethylamino}cyclopent-1-enecarbodithioate
    —— zinc;5-methylsulfanyl-2-sulfanylidene-1,3-dithiole-4-thiolate;N,N,N',N'-tetramethylethane-1,2-diamine 221296-76-0 C14H22N2S10Zn
    zinc;5-methylsulfanyl-2-sulfanylidene-1,3-dithiole-4-thiolate;N,N,N',N'-tetramethylethane-1,2-diamine
    —— Methanesulfonic acid (R)-3-[4-(4-acetylamino-phenylsulfanyl)-3-fluoro-phenyl]-2-oxo-oxazolidin-5-ylmethyl ester 771477-18-0 C19H19FN2O6S2
    Methanesulfonic acid (R)-3-[4-(4-acetylamino-phenylsulfanyl)-3-fluoro-phenyl]-2-oxo-oxazolidin-5-ylmethyl ester
    —— 3-{6-[3,3-Bis-(2-hydroxy-ethyl)-thioureido]-hexyl}-1,1-bis-(2-hydroxy-ethyl)-thiourea 56312-26-6 C16H34N4O4S2
    3-{6-[3,3-Bis-(2-hydroxy-ethyl)-thioureido]-hexyl}-1,1-bis-(2-hydroxy-ethyl)-thiourea
    —— 111994-33-3 C28H22N8NiO2S4
    —— N-[4-[[4-cyclopropyl-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]acetamide 1258425-66-9 C18H19N7OS
    N-[4-[[4-cyclopropyl-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]acetamide
    —— (2S)-1-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-ol trifluoroacetate 1156469-48-5 C2HF3O2*C23H27BrN6O4S
    (2S)-1-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-ol trifluoroacetate
    —— 5-<2-cyano-2-(dimethylamino)ethyl>-1-methyl-4-<(phenylmethyl)thio>imidazole 122174-31-6 C16H20N4S
    5-<2-cyano-2-(dimethylamino)ethyl>-1-methyl-4-<(phenylmethyl)thio>imidazole