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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(3R)-3-(1H-imidazol-2-ylsulfanyl)-2-oxopyrrolidin-1-yl]thiophene-3-carbonitrile —— C12H10N4OS2
    2-[(3R)-3-(1H-imidazol-2-ylsulfanyl)-2-oxopyrrolidin-1-yl]thiophene-3-carbonitrile
    —— N-[(2S,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2S,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide —— C13H25NO3S
    N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide
    —— N-[(2R,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2R,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2R,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2R,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide —— C12H23NO3S
    N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide
    —— N-[(2S,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2S,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide —— C13H25NO3S
    N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide
    —— N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide —— C12H23NO3S
    N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide
    —— 3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]propanamide —— C16H24BrNO3S2
    3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]propanamide
    —— (1S)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1S)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— 2-cyclopentylsulfonyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide —— C13H25NO5S2
    2-cyclopentylsulfonyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide
    —— (1R)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1R)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— (1S)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1S)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— 2-(cyclohexen-1-yl)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]acetamide —— C15H27NO3S
    2-(cyclohexen-1-yl)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]acetamide
    —— (1R)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1R)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— 2-cyclopentylsulfonyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide —— C13H25NO5S2
    2-cyclopentylsulfonyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide
    —— 3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]propanamide —— C16H24BrNO3S2
    3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]propanamide
    —— (2R)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide —— C15H25NO3S
    (2R)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide
    —— 2-(cyclohexen-1-yl)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]acetamide —— C15H27NO3S
    2-(cyclohexen-1-yl)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]acetamide
    —— (2S)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide —— C15H15FN6OS
    (2S)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide
    —— (2R)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide —— C15H15FN6OS
    (2R)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide
    —— (2S)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide —— C15H25NO3S
    (2S)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide
    —— (2R)-2-methylsulfonyl-N-(2-phenylsulfanylphenyl)propanamide —— C16H17NO3S2
    (2R)-2-methylsulfonyl-N-(2-phenylsulfanylphenyl)propanamide
    —— 3-[(1R)-cyclohex-2-en-1-yl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine —— C13H20N4OS
    3-[(1R)-cyclohex-2-en-1-yl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine
    —— 2-(4-chlorophenyl)sulfanyl-N'-[1-(2,4-dimethylpyrrol-3-ylidene)ethyl]acetohydrazide —— C16H18ClN3OS
    2-(4-chlorophenyl)sulfanyl-N'-[1-(2,4-dimethylpyrrol-3-ylidene)ethyl]acetohydrazide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C13H18N6OS
    N-[[4-(dimethylamino)phenyl]methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 1-Methyl-5-[[3-[(1-methyltetrazol-5-yl)sulfanylmethyl]phenyl]methylsulfanyl]tetrazole —— C12H14N8S2
    1-Methyl-5-[[3-[(1-methyltetrazol-5-yl)sulfanylmethyl]phenyl]methylsulfanyl]tetrazole
    —— ethyl 5-[[2-[2-(4-chlorophenyl)sulfanylacetyl]hydrazinyl]methylidene]-2,4-dimethylpyrrole-3-carboxylate —— C18H20ClN3O3S
    ethyl 5-[[2-[2-(4-chlorophenyl)sulfanylacetyl]hydrazinyl]methylidene]-2,4-dimethylpyrrole-3-carboxylate
    —— 5-(Furan-2-yl)-3-[(1-methyltetrazol-5-yl)sulfanylmethyl]-1,2-oxazole —— C10H9N5O2S
    5-(Furan-2-yl)-3-[(1-methyltetrazol-5-yl)sulfanylmethyl]-1,2-oxazole
    —— 2-(1-methyltetrazol-5-yl)sulfanyl-1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethanone —— C15H17N5OS
    2-(1-methyltetrazol-5-yl)sulfanyl-1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethanone
    —— N-[(2-fluorophenyl)methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C11H12FN5OS
    N-[(2-fluorophenyl)methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]methylideneamino]acetamide —— C18H17ClN4OS2
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]methylideneamino]acetamide
    —— (2S)-2-methylsulfonyl-N-(2-phenylsulfanylphenyl)propanamide —— C16H17NO3S2
    (2S)-2-methylsulfonyl-N-(2-phenylsulfanylphenyl)propanamide
    —— (2R)-N-[5-chloro-2-(2,4-dimethylphenyl)sulfanylphenyl]-2-methylsulfonylpropanamide —— C18H20ClNO3S2
    (2R)-N-[5-chloro-2-(2,4-dimethylphenyl)sulfanylphenyl]-2-methylsulfonylpropanamide
    —— N-[(Z)-[(E)-3-(1-benzyltriazol-4-yl)prop-2-enylidene]amino]-2-(4-chlorophenyl)sulfanylacetamide —— C20H18ClN5OS
    N-[(Z)-[(E)-3-(1-benzyltriazol-4-yl)prop-2-enylidene]amino]-2-(4-chlorophenyl)sulfanylacetamide
    —— (2R)-N-(2-methylpropyl)-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C16H22N4OS
    (2R)-N-(2-methylpropyl)-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— 3-[(1S)-cyclohex-2-en-1-yl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine —— C13H20N4OS
    3-[(1S)-cyclohex-2-en-1-yl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine
    —— 3-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine —— C16H22N4OS
    3-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine
    —— (2S)-N-[5-chloro-2-(2,4-dimethylphenyl)sulfanylphenyl]-2-methylsulfonylpropanamide —— C18H20ClNO3S2
    (2S)-N-[5-chloro-2-(2,4-dimethylphenyl)sulfanylphenyl]-2-methylsulfonylpropanamide
    —— 2-(1-methyltetrazol-5-yl)sulfanyl-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide —— C15H15N5OS2
    2-(1-methyltetrazol-5-yl)sulfanyl-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide
    —— 3-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine —— C16H22N4OS
    3-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-5-(oxan-4-yl)-1,2,4-triazol-4-amine
    —— N-[2-(2-methylphenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C13H17N5OS
    N-[2-(2-methylphenyl)ethyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— 1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-(1-methyltetrazol-5-yl)sulfanylethanone —— C13H14N4O3S
    1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-(1-methyltetrazol-5-yl)sulfanylethanone
    —— 2-(5-Bromothiophen-2-yl)-5-[(1-methyltetrazol-5-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C9H7BrN6OS2
    2-(5-Bromothiophen-2-yl)-5-[(1-methyltetrazol-5-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— 3-(oxan-4-yl)-5-[(2S)-2-phenylpropyl]sulfanyl-1,2,4-triazol-4-amine —— C16H22N4OS
    3-(oxan-4-yl)-5-[(2S)-2-phenylpropyl]sulfanyl-1,2,4-triazol-4-amine
    —— (2R)-N-propyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C15H20N4OS
    (2R)-N-propyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— 3-(oxan-4-yl)-5-[(2R)-2-phenylpropyl]sulfanyl-1,2,4-triazol-4-amine —— C16H22N4OS
    3-(oxan-4-yl)-5-[(2R)-2-phenylpropyl]sulfanyl-1,2,4-triazol-4-amine
    —— (2R)-N-prop-2-enyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C15H18N4OS
    (2R)-N-prop-2-enyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— (2S)-N-propyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C15H20N4OS
    (2S)-N-propyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide