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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1.2.5.6-Tetradesoxy-3.4-O-isopropyliden-1.2.5.6-bis-thiocarbonyldithio-L-idit 26302-15-8 C11H14O2S6
    1.2.5.6-Tetradesoxy-3.4-O-isopropyliden-1.2.5.6-bis-thiocarbonyldithio-L-idit
    —— (4-chloro-6-phenylsulfanyl-[1,3,5]triazin-2-yl)-octyl-amine 38375-20-1 C17H23ClN4S
    (4-chloro-6-phenylsulfanyl-[1,3,5]triazin-2-yl)-octyl-amine
    —— 4-(phenylmercapto)benzoyl chloride 50684-62-3 C13H9ClOS
    4-(phenylmercapto)benzoyl chloride
    —— 3,3-diethoxy-2-(methyldithio)propan-1-ol acetate 329776-06-9 C10H20O4S2
    3,3-diethoxy-2-(methyldithio)propan-1-ol acetate
    —— <4-Chlorphenyl>-<bis-(2-hydroxyaethyl)-aminomethyl>-sulfid 22959-51-9 C11H16ClNO2S
    <4-Chlorphenyl>-<bis-(2-hydroxyaethyl)-aminomethyl>-sulfid
    —— 4-Chlor-1-<2-pentylmercapto-aethylmercapto>-benzol 29960-06-3 C13H19ClS2
    4-Chlor-1-<2-pentylmercapto-aethylmercapto>-benzol
    —— 4-Phenylthio-cycloheptanon-semicarbazon 34395-15-8 C14H19N3OS
    4-Phenylthio-cycloheptanon-semicarbazon
    —— sulfur chloride perfluoroisopropylideneamide 38005-18-4 C3ClF6NS
    sulfur chloride perfluoroisopropylideneamide
    —— ethyl 5-methyl-6-(2-naphthylsulfanyl)-1,3,4,5-tetrahydro-2H-pyrido[4,3-b]indole-2-carboxylate 868161-15-3 C25H24N2O2S
    ethyl 5-methyl-6-(2-naphthylsulfanyl)-1,3,4,5-tetrahydro-2H-pyrido[4,3-b]indole-2-carboxylate
    —— N-[7-benzyl-5-((4-methoxyphenyl)sulfanyl)-4-methyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl]-2,2-dimethylpropanamide 1424430-91-0 C26H28N4O2S
    N-[7-benzyl-5-((4-methoxyphenyl)sulfanyl)-4-methyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl]-2,2-dimethylpropanamide
    —— 5-(3-Chloro-phenylsulfanyl)-3-methoxy-6-nitro-benzofuran 286377-39-7 C15H10ClNO4S
    5-(3-Chloro-phenylsulfanyl)-3-methoxy-6-nitro-benzofuran
    —— 2,2'-(3,3'-sulfonylbis(prop-1-yne-3,1-diyl))bis(1-(methoxymethyl)cyclohex-1-ene) 1393727-43-9 C22H30O4S
    2,2'-(3,3'-sulfonylbis(prop-1-yne-3,1-diyl))bis(1-(methoxymethyl)cyclohex-1-ene)
    —— 4-<<2'-(dimethylamino)ethyl>thio>phenyllithium 131407-89-1 C10H14LiNS
    4-<<2'-(dimethylamino)ethyl>thio>phenyllithium
    —— 6-<2-(ethoxycarbonyl)ethylthiol>-1,3-dimethyluracil 139455-61-1 C11H16N2O4S
    6-<2-(ethoxycarbonyl)ethylthiol>-1,3-dimethyluracil
    —— 2-bromo-3-(4-chlorophenylthio)-1-methyl-1H-indole 1417051-69-4 C15H11BrClNS
    2-bromo-3-(4-chlorophenylthio)-1-methyl-1H-indole
    —— 2-bromo-5-methoxy-3-(4-methoxyphenylthio)-1H-indole 1385029-12-8 C16H14BrNO2S
    2-bromo-5-methoxy-3-(4-methoxyphenylthio)-1H-indole
    —— 4-methylphenyl 3,5-O-(tetraisopropyldisiloxane-1,3-diyl)-1-thio-α-L-arabinofuranoside 1451369-72-4 C24H42O5SSi2
    4-methylphenyl 3,5-O-(tetraisopropyldisiloxane-1,3-diyl)-1-thio-α-L-arabinofuranoside
    —— ethyl 1-ethyl-6-fluoro-1,2-dihydro-4-hydroxy-7-(p-tolylthio)-1,8-naphthyridine-3-carboxylate 114171-72-1 C20H21FN2O3S
    ethyl 1-ethyl-6-fluoro-1,2-dihydro-4-hydroxy-7-(p-tolylthio)-1,8-naphthyridine-3-carboxylate
    —— 81504-39-4 C17H23Cl3CuN2O2S
    —— (2Z, 4E, 6R)-2-methoxy-6-methyl-7-[3-amino-5-hydroxyphenyl]-thiohepta-2,4-dienoic acid S-(2-acetylaminoethyl) ester 1137914-22-7 C19H26N2O4S
    (2Z, 4E, 6R)-2-methoxy-6-methyl-7-[3-amino-5-hydroxyphenyl]-thiohepta-2,4-dienoic acid S-(2-acetylaminoethyl) ester
    —— (E)-2-amino-2,4,5,6-tetradeoxy-6-(undecylsulfonyl)-D-erythro-hex-4-enitol 1193091-92-7 C17H35NO4S
    (E)-2-amino-2,4,5,6-tetradeoxy-6-(undecylsulfonyl)-D-erythro-hex-4-enitol
    —— 2-(3-chloro-phenyl)-5-methoxycarbonylsulfanyl-[1,3,4]oxadiazole 53961-41-4 C10H7ClN2O3S
    2-(3-chloro-phenyl)-5-methoxycarbonylsulfanyl-[1,3,4]oxadiazole
    —— 11,11'-disulfanediyldiundecanoyl chloride 851778-52-4 C22H40Cl2O2S2
    11,11'-disulfanediyldiundecanoyl chloride
    —— 1092582-68-7 C24H34O5S
    —— bis-(2-phenyl-1,2,3-triazol-4-yl) sulphide 77896-77-6 C16H12N6S
    bis-(2-phenyl-1,2,3-triazol-4-yl) sulphide
    —— 4-n-Butylthiopyrrole 120884-78-8 C8H13NS
    4-n-Butylthiopyrrole
    —— 1120282-92-9 C9H13N3OS
    —— (4-Phenylsulfanylphenyl)methyl methanesulfonate 898535-26-7 C14H14O3S2
    (4-Phenylsulfanylphenyl)methyl methanesulfonate
    —— (4-chlorophenyl)(cyclohex-2-enyl)sulfane 1403961-62-5 C12H13ClS
    (4-chlorophenyl)(cyclohex-2-enyl)sulfane
    —— (8-chloro-3-methylsulfanyl-5,6-dihydro-pyrimido[4,5-<i>e</i>][1,2,4]triazin-6-yl)-dimethyl-amine 38713-98-3 C8H11ClN6S
    (8-chloro-3-methylsulfanyl-5,6-dihydro-pyrimido[4,5-<i>e</i>][1,2,4]triazin-6-yl)-dimethyl-amine
    —— copper(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate 1448848-09-6 C96H80CuN8O16S8
    copper(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate
    —— 5-(2,4-dinitro-phenylsulfanyl)-2,4-dimethyl-pyrrole-3-carboxylic acid ethyl ester 36151-67-4 C15H15N3O6S
    5-(2,4-dinitro-phenylsulfanyl)-2,4-dimethyl-pyrrole-3-carboxylic acid ethyl ester
    —— 28940-28-5 C38H26N6O4S3
    —— 4-chloro-2-phenyl-5-thiocyanato-2<i>H</i>-pyridazin-3-one 25381-79-7 C11H6ClN3OS
    4-chloro-2-phenyl-5-thiocyanato-2<i>H</i>-pyridazin-3-one
    —— 5-allylsulfanyl-4-chloro-2-phenyl-2<i>H</i>-pyridazin-3-one 25381-22-0 C13H11ClN2OS
    5-allylsulfanyl-4-chloro-2-phenyl-2<i>H</i>-pyridazin-3-one
    —— 4-allylsulfanyl-6-chloro-2-phenyl-2<i>H</i>-pyridazin-3-one 25381-05-9 C13H11ClN2OS
    4-allylsulfanyl-6-chloro-2-phenyl-2<i>H</i>-pyridazin-3-one
    —— (2-Amino-5-chlor-phenyl)-(4-brom-2-nitro-phenyl)-sulfid 24034-02-4 C12H8BrClN2O2S
    (2-Amino-5-chlor-phenyl)-(4-brom-2-nitro-phenyl)-sulfid
    —— (3-Chloro-phenylsulfanyl)-(dimethoxy-thiophosphorylsulfanyl)-acetic acid ethyl ester 27884-62-4 C12H16ClO4PS3
    (3-Chloro-phenylsulfanyl)-(dimethoxy-thiophosphorylsulfanyl)-acetic acid ethyl ester
    —— (Dimethoxy-thiophosphorylsulfanyl)-phenylsulfanyl-acetic acid propyl ester 28058-61-9 C13H19O4PS3
    (Dimethoxy-thiophosphorylsulfanyl)-phenylsulfanyl-acetic acid propyl ester
    —— (1R,4R,6R)-1-methyl-7-(phenylthio)-4-(prop-1-en-2-yl)bicyclo[4.1.0]heptan-2-one-3,3-d2 85152-67-6 C17H20OS
    (1R,4R,6R)-1-methyl-7-(phenylthio)-4-(prop-1-en-2-yl)bicyclo[4.1.0]heptan-2-one-3,3-d2
    —— (E)-2-ethyl-1-methoxy-3-phenylthio-1-propene 119046-74-1 C12H16OS
    (E)-2-ethyl-1-methoxy-3-phenylthio-1-propene
    —— 3-methylsulfanyl-5-(2,4,5-trichloro-benzylsulfanyl)-[1,2,4]thiadiazole 21745-11-9 C10H7Cl3N2S3
    3-methylsulfanyl-5-(2,4,5-trichloro-benzylsulfanyl)-[1,2,4]thiadiazole
    —— Diethyl N-butyl-N-(1-chloro-2-phenylthioisobutyl)amidophosphate 134241-61-5 C18H31ClNO3PS
    Diethyl N-butyl-N-(1-chloro-2-phenylthioisobutyl)amidophosphate
    —— nonafluoro-tert-butylsulfenyl chloride 32308-83-1 C4ClF9S
    nonafluoro-tert-butylsulfenyl chloride
    —— 2-phenyl-5,8-bis-phenylsulfanyl-pyrimido[4,5-<i>d</i>]pyridazine 38277-17-7 C24H16N4S2
    2-phenyl-5,8-bis-phenylsulfanyl-pyrimido[4,5-<i>d</i>]pyridazine
    —— 6-chloro-5-ethylsulfanyl-2-phenyl-2<i>H</i>-pyridazin-3-one 25381-16-2 C12H11ClN2OS
    6-chloro-5-ethylsulfanyl-2-phenyl-2<i>H</i>-pyridazin-3-one
    —— 2,2'-Bis-(pyridyl-3-thio)-diethylamin 21910-76-9 C14H17N3S2
    2,2'-Bis-(pyridyl-3-thio)-diethylamin
    —— 86816-44-6 C18H18S2
    —— 3-Phenylthio-1,4-oxathian 37938-96-8 C10H12OS2
    3-Phenylthio-1,4-oxathian
    —— Diuracilylsulfid 37737-46-5 C8H6N4O4S
    Diuracilylsulfid