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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(1,3-Benzodioxol-5-yl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C18H14N4O3S2
    2-(1,3-Benzodioxol-5-yl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-(3,4-Dimethoxyphenyl)-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole —— C19H16N4O3S2
    2-(3,4-Dimethoxyphenyl)-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-[5-(4-Fluorophenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-phenyl-1,3,4-oxadiazole —— C20H11FN4OS2
    2-[5-(4-Fluorophenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-phenyl-1,3,4-oxadiazole
    —— 2-(3,4-Dimethoxyphenyl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C16H12N4O3S2
    2-(3,4-Dimethoxyphenyl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— 2-Phenyl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C14H8N4OS2
    2-Phenyl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile —— C16H11N5O2S2
    2-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile
    —— 3-Prop-2-enyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one —— C19H16N4OS3
    3-Prop-2-enyl-2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one
    —— 2-(1,3-Benzodioxol-5-yl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C15H8N4O3S2
    2-(1,3-Benzodioxol-5-yl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(3,4-Dimethoxyphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile —— C17H12N4O5S
    2-[[5-(3,4-Dimethoxyphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile
    —— 2-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-5-phenyl-1,3,4-oxadiazole —— C19H16N4OS2
    2-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-5-phenyl-1,3,4-oxadiazole
    —— 10-Methyl-12-(4-methylpyrimidin-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C15H14N4S2
    10-Methyl-12-(4-methylpyrimidin-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 4-Methyl-2-(2-nitrophenyl)sulfanylpyrimidine —— C11H9N3O2S
    4-Methyl-2-(2-nitrophenyl)sulfanylpyrimidine
    —— 2,5,6-Trimethyl-4-(4-methylpyrimidin-2-yl)sulfanylthieno[2,3-d]pyrimidine —— C14H14N4S2
    2,5,6-Trimethyl-4-(4-methylpyrimidin-2-yl)sulfanylthieno[2,3-d]pyrimidine
    —— 12-Pyrimidin-2-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C13H10N4S2
    12-Pyrimidin-2-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 5-Nitro-2-pyrimidin-2-ylsulfanylbenzonitrile —— C11H6N4O2S
    5-Nitro-2-pyrimidin-2-ylsulfanylbenzonitrile
    —— 4-methyl-2-[4-[(3S)-3-methylpiperidin-1-yl]sulfonyl-2-nitrophenyl]sulfanylpyrimidine —— C17H20N4O4S2
    4-methyl-2-[4-[(3S)-3-methylpiperidin-1-yl]sulfonyl-2-nitrophenyl]sulfanylpyrimidine
    —— 10-Methyl-12-pyrimidin-2-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C14H12N4S2
    10-Methyl-12-pyrimidin-2-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 2-(4-Methylsulfonyl-2-nitrophenyl)sulfanylpyrimidine —— C11H9N3O4S2
    2-(4-Methylsulfonyl-2-nitrophenyl)sulfanylpyrimidine
    —— N-benzyl-5-(2-chloro-4-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-amine —— C15H11ClN4O2S2
    N-benzyl-5-(2-chloro-4-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-(5,6-Dimethyl-4-oxo-3-prop-2-enylthieno[2,3-d]pyrimidin-2-yl)sulfanyl-5-nitrobenzonitrile —— C18H14N4O3S2
    2-(5,6-Dimethyl-4-oxo-3-prop-2-enylthieno[2,3-d]pyrimidin-2-yl)sulfanyl-5-nitrobenzonitrile
    —— N,N-diethyl-3-nitro-4-pyrimidin-2-ylsulfanylbenzenesulfonamide —— C14H16N4O4S2
    N,N-diethyl-3-nitro-4-pyrimidin-2-ylsulfanylbenzenesulfonamide
    —— 4-[[12-(4-Methylpyrimidin-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium —— C19H22N5OS2+
    4-[[12-(4-Methylpyrimidin-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium
    —— 10-[(4-Methylpiperidin-1-ium-1-yl)methyl]-12-pyrimidin-2-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C20H24N5S2+
    10-[(4-Methylpiperidin-1-ium-1-yl)methyl]-12-pyrimidin-2-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 4-[[5,6-Dimethyl-4-(4-methylpyrimidin-2-yl)sulfanylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C18H22N5OS2+
    4-[[5,6-Dimethyl-4-(4-methylpyrimidin-2-yl)sulfanylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-4-methylpyrimidine —— C11H8ClN3O2S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-4-methylpyrimidine
    —— (7R)-7-methyl-4-pyrimidin-2-ylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C15H14N4S2
    (7R)-7-methyl-4-pyrimidin-2-ylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— 5-(4-Fluorophenyl)-4-pyrimidin-2-ylsulfanylthieno[2,3-d]pyrimidine —— C16H9FN4S2
    5-(4-Fluorophenyl)-4-pyrimidin-2-ylsulfanylthieno[2,3-d]pyrimidine
    —— [4-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl-diethylazanium —— C19H26N5S2+
    [4-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl-diethylazanium
    —— 4-[[12-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine —— C20H23N5OS2
    4-[[12-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine
    —— 5,6-Dimethyl-4-(4-methylpyrimidin-2-yl)sulfanylthieno[2,3-d]pyrimidine —— C13H12N4S2
    5,6-Dimethyl-4-(4-methylpyrimidin-2-yl)sulfanylthieno[2,3-d]pyrimidine
    —— 4,6-Dimethyl-2-(2-nitrophenyl)sulfanylpyrimidine —— C12H11N3O2S
    4,6-Dimethyl-2-(2-nitrophenyl)sulfanylpyrimidine
    —— 4-[[4-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C19H24N5OS2+
    4-[[4-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 4,6-Dimethyl-2-(2-nitro-4-pyrrolidin-1-ylsulfonylphenyl)sulfanylpyrimidine —— C16H18N4O4S2
    4,6-Dimethyl-2-(2-nitro-4-pyrrolidin-1-ylsulfonylphenyl)sulfanylpyrimidine
    —— N-[[4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]-N-ethylethanamine —— C19H25N5S2
    N-[[4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]-N-ethylethanamine
    —— 12-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C16H16N4S2
    12-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 2-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-5-nitrobenzonitrile —— C13H10N4O2S
    2-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-5-nitrobenzonitrile
    —— 4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide —— C16H20N4O4S2
    4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide
    —— 2-(2-methylphenyl)sulfanyl-N-[(1R)-1-phenylethyl]acetamide —— C17H19NOS
    2-(2-methylphenyl)sulfanyl-N-[(1R)-1-phenylethyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C18H16ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 1-[[2-(4-Bromophenyl)sulfanylacetyl]amino]-3-(3-methoxypropyl)-1-methylthiourea —— C14H20BrN3O2S2
    1-[[2-(4-Bromophenyl)sulfanylacetyl]amino]-3-(3-methoxypropyl)-1-methylthiourea
    —— (2R)-N-cycloheptyl-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C22H32N4O2S
    (2R)-N-cycloheptyl-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-cycloheptyl-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C22H32N4O2S
    (2S)-N-cycloheptyl-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-(3-methoxyphenyl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-thiadiazol-2-amine —— C15H11N5OS3
    N-(3-methoxyphenyl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-thiadiazol-2-amine
    —— 4-[[5,6-Dimethyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C16H20N5OS3+
    4-[[5,6-Dimethyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C15H17N3OS2
    (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— methyl (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C13H15N3O2S2
    methyl (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 4-[[5,6-Dimethyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidin-2-yl]methyl]morpholine —— C16H19N5OS3
    4-[[5,6-Dimethyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidin-2-yl]methyl]morpholine
    —— N-benzyl-5-[(3-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H17N3S2
    N-benzyl-5-[(3-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 1-[[2-(4-fluorophenyl)sulfanylacetyl]amino]-3-[(2S)-2-methylheptyl]thiourea —— C17H26FN3OS2
    1-[[2-(4-fluorophenyl)sulfanylacetyl]amino]-3-[(2S)-2-methylheptyl]thiourea
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylacetamide —— C19H19FN4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylacetamide