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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylacetamide —— C17H19N5OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylacetamide
    —— (2S)-N-cyclopropyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C15H18N4OS
    (2S)-N-cyclopropyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— (2S)-N-(2-methylpropyl)-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C16H22N4OS
    (2S)-N-(2-methylpropyl)-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— (2R)-N-cyclopropyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C15H18N4OS
    (2R)-N-cyclopropyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— (2S)-N-prop-2-enyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide —— C15H18N4OS
    (2S)-N-prop-2-enyl-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylpropanamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylacetamide —— C17H19N5OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylacetamide
    —— [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (1S,2R)-2-methylcyclopropane-1-carboxylate —— C15H18BrNO3S
    [2-[2-(4-bromophenyl)sulfanylethylamino]-2-oxoethyl] (1S,2R)-2-methylcyclopropane-1-carboxylate
    —— 2-[(1S)-cyclopent-2-en-1-yl]-N-ethyl-N-[(2S)-1-methylsulfonylpropan-2-yl]acetamide —— C13H23NO3S
    2-[(1S)-cyclopent-2-en-1-yl]-N-ethyl-N-[(2S)-1-methylsulfonylpropan-2-yl]acetamide
    —— 2-[(1R)-cyclopent-2-en-1-yl]-N-ethyl-N-[(2S)-1-methylsulfonylpropan-2-yl]acetamide —— C13H23NO3S
    2-[(1R)-cyclopent-2-en-1-yl]-N-ethyl-N-[(2S)-1-methylsulfonylpropan-2-yl]acetamide
    —— 2-[(1R)-cyclopent-2-en-1-yl]-N-ethyl-N-[(2R)-1-methylsulfonylpropan-2-yl]acetamide —— C13H23NO3S
    2-[(1R)-cyclopent-2-en-1-yl]-N-ethyl-N-[(2R)-1-methylsulfonylpropan-2-yl]acetamide
    —— N-[(2,4-dimethylphenyl)methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C20H24N4O2S
    N-[(2,4-dimethylphenyl)methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-phenylmethoxyacetamide —— C17H19NO2S
    2-(3,4-dimethylphenyl)sulfanyl-N-phenylmethoxyacetamide
    —— 3-(4-chlorophenyl)sulfanyl-N-phenylmethoxypropanamide —— C16H16ClNO2S
    3-(4-chlorophenyl)sulfanyl-N-phenylmethoxypropanamide
    —— 2-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-4-ium-1-yl]ethanone —— C22H27N6OS+
    2-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-4-ium-1-yl]ethanone
    —— 2-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone —— C22H26N6OS
    2-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-1-yl]ethanone
    —— 2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-4-ium-1-yl]ethanone —— C20H25N6O2S+
    2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-[4-(pyridin-4-ylmethyl)piperazin-4-ium-1-yl]ethanone
    —— 2-(4-Bromo-2-methylphenyl)sulfanyl-1-[4-(pyridin-4-ylmethyl)piperazin-4-ium-1-yl]ethanone —— C19H23BrN3OS+
    2-(4-Bromo-2-methylphenyl)sulfanyl-1-[4-(pyridin-4-ylmethyl)piperazin-4-ium-1-yl]ethanone
    —— (3R)-N-[2-(dimethylamino)pyridin-3-yl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide —— C17H19N3OS
    (3R)-N-[2-(dimethylamino)pyridin-3-yl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3S)-N-[2-(dimethylamino)pyridin-3-yl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide —— C17H19N3OS
    (3S)-N-[2-(dimethylamino)pyridin-3-yl]-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— N-[(1S)-1-(2,4-difluorophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C18H21F2N3OS
    N-[(1S)-1-(2,4-difluorophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(1R,2S)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2OS2
    N-[(1R,2S)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— (2R)-N-[(1R)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide —— C20H20ClN3O2S
    (2R)-N-[(1R)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide
    —— N-[(1S,2S)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2OS2
    N-[(1S,2S)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(1S,2R)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2OS2
    N-[(1S,2R)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— (2R)-N-[(1S)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide —— C20H20ClN3O2S
    (2R)-N-[(1S)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide
    —— (2S)-N-[(1S)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide —— C20H20ClN3O2S
    (2S)-N-[(1S)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide
    —— (2S)-N-[(1R)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide —— C20H20ClN3O2S
    (2S)-N-[(1R)-1-(3-benzyl-1,2,4-oxadiazol-5-yl)ethyl]-2-(2-chlorophenyl)sulfanylpropanamide
    —— N-[(1R,2R)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2OS2
    N-[(1R,2R)-2-ethylsulfanylcyclohexyl]-2-pyridin-4-ylsulfanylacetamide
    —— (2R)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide —— C22H25N3O2S
    (2R)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide
    —— (2S)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C22H25N3O2S
    (2S)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— (2S)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide —— C22H25N3O2S
    (2S)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-phenylpropyl]propanamide
    —— (2R)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C22H25N3O2S
    (2R)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C15H18FN3OS3
    (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— N-methyl-N-(4-methylcyclohexyl)-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H29N3O2S
    N-methyl-N-(4-methylcyclohexyl)-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-N-(4-methylcyclohexyl)-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H29N3O2S
    N-methyl-N-(4-methylcyclohexyl)-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 1-[4-[[(3S)-oxolan-3-yl]methyl]piperazin-1-yl]-2-phenylsulfanylethanone —— C17H24N2O2S
    1-[4-[[(3S)-oxolan-3-yl]methyl]piperazin-1-yl]-2-phenylsulfanylethanone
    —— 1-[4-[[(3R)-oxolan-3-yl]methyl]piperazin-1-yl]-2-phenylsulfanylethanone —— C17H24N2O2S
    1-[4-[[(3R)-oxolan-3-yl]methyl]piperazin-1-yl]-2-phenylsulfanylethanone
    —— 5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine —— C14H17N3O2S2
    5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— (2R)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-1-one —— C18H26N5OS2+
    (2R)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-1-one
    —— 2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S3
    2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H23N5OS2
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine —— C16H13N5O2S2
    5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-(3-methoxypropyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H20N4O2S2
    N-(3-methoxypropyl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-acetyl-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide —— C13H15N5O2S2
    N'-acetyl-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide
    —— N-(furan-2-ylmethyl)-N-methyl-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H18N4O2S2
    N-(furan-2-ylmethyl)-N-methyl-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-1-one —— C18H26N5OS2+
    (2S)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-1-one
    —— methyl (2S)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C13H15N3O2S2
    methyl (2S)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 1-(4-Acetylpiperazin-1-yl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C17H21N5O2S2
    1-(4-Acetylpiperazin-1-yl)-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N,N-diethyl-4-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C17H24N4OS2
    N,N-diethyl-4-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— 5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine —— C13H13N5OS2
    5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine