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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1S)-1-[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-bis(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-prop-2-yn-1-ol 381246-86-2 C36H70O5S2Si2
    (1S)-1-[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-bis(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-prop-2-yn-1-ol
    —— dichloro-s-triazinyl-2,3,5,6-tetrafluoropyridylsulphane 24316-29-8 C8Cl2F4N4S
    dichloro-s-triazinyl-2,3,5,6-tetrafluoropyridylsulphane
    —— ethyl phenyl trithiocarbonate 77102-69-3 C9H10S3
    ethyl phenyl trithiocarbonate
    —— hexakis((diaminomethylene)-l4-sulfaneyl)osmium(IX) 12300-37-7 C6H24N12OsS6
    hexakis((diaminomethylene)-l4-sulfaneyl)osmium(IX)
    —— [MeHg(3-SC6H4NH2)] 342607-55-0 C7H9HgNS
    [MeHg(3-SC6H4NH2)]
    —— N-(methyl)carbamate du trichloro-2,4,5 thiophenol 96408-94-5 C8H6Cl3NOS
    N-(methyl)carbamate du trichloro-2,4,5 thiophenol
    —— (R)-3,5-dimethyl-4-hydroxy-5-((E)-4-hydroxy-2-methylbut-1-enyl)-5H-thiophen-2-one 873801-63-9 C11H16O3S
    (R)-3,5-dimethyl-4-hydroxy-5-((E)-4-hydroxy-2-methylbut-1-enyl)-5H-thiophen-2-one
    —— 151192-84-6 C4H10S*Cl
    —— tetra-<i>S</i>-methyl-<i>S</i>,<i>S</i>'-azanediyl-bis-sulfonium monobetaine; chloride 2229-50-7 C4H12NS2*Cl
    tetra-<i>S</i>-methyl-<i>S</i>,<i>S</i>'-azanediyl-bis-sulfonium monobetaine; chloride
    —— Allyl-2-hydrooctafluoroisobutyl sulfide 73479-31-9 C7H6F8S
    Allyl-2-hydrooctafluoroisobutyl sulfide
    —— N,N-dimethylthiocarbamoyl trifluoroborate 1622923-32-3 C3H6BF3NS*K
    N,N-dimethylthiocarbamoyl trifluoroborate
    —— 1,1,3-tris-ethylsulfanyl-propane 19157-17-6 C9H20S3
    1,1,3-tris-ethylsulfanyl-propane
    —— 4-Hexyl-benzolsulfonylcyanid 24225-07-8 C7H13NO2S
    4-Hexyl-benzolsulfonylcyanid
    —— <i>S</i>-butyl-<i>N</i>-cyano-isothiourea 15647-06-0 C6H11N3S
    <i>S</i>-butyl-<i>N</i>-cyano-isothiourea
    —— methyl thio fluoroformate 2694-34-0 C2H3FOS
    methyl thio fluoroformate
    —— 9-[(4,4,5,5,5-pentafluoropentyl)thio]nonyl magnesium bromide 875573-62-9 C14H24BrF5MgS
    9-[(4,4,5,5,5-pentafluoropentyl)thio]nonyl magnesium bromide
    —— Cyclooctylrhodanid 5263-56-9 C9H15NS
    Cyclooctylrhodanid
    —— 2,4,6-tris(4-hydroxy-3,5-di-tert-butylphenylthio)-symm-triazine 105648-50-8 C45H63N3O3S3
    2,4,6-tris(4-hydroxy-3,5-di-tert-butylphenylthio)-symm-triazine
    —— (2S,3R,4S,5R,6S)-2-{2-[(2R,3S,4R)-2,4-bis(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl]-[1,3]dithian-2-yl}-6-methoxy-4-methyl-5-triethylsilanyloxy-oct-7-yn-3-ol 381246-88-4 C40H82O5S2Si3
    (2S,3R,4S,5R,6S)-2-{2-[(2R,3S,4R)-2,4-bis(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl]-[1,3]dithian-2-yl}-6-methoxy-4-methyl-5-triethylsilanyloxy-oct-7-yn-3-ol
    —— [(PhN(P(OC10H6(μ-S)C10H6O)-κP)2)PtI2] 1001201-68-8 C46H29I2NO4P2PtS2
    [(PhN(P(OC10H6(μ-S)C10H6O)-κP)2)PtI2]
    —— bis-iodomethyl sulfide 98025-72-0 C2H4I2S
    bis-iodomethyl sulfide
    —— 9-<4-acetoxy-3-(acetoxymethyl)butyl>-2-amino-6-<(4-chlorophenyl)sulfanyl>-9H-purine 225111-66-0 C20H22ClN5O4S
    9-<4-acetoxy-3-(acetoxymethyl)butyl>-2-amino-6-<(4-chlorophenyl)sulfanyl>-9H-purine
    —— 2,4-Bis-methylmercapto-3-methyl-phenylcyanat 1203-78-7 C10H11NOS2
    2,4-Bis-methylmercapto-3-methyl-phenylcyanat
    —— 1,3-di-tert-butyl-2-thioisocyanato-1,3-diaza-2-silacyclopent-4-ene 1352140-04-5 C11H21N3SSi
    1,3-di-tert-butyl-2-thioisocyanato-1,3-diaza-2-silacyclopent-4-ene
    —— dec-1-yn-1-yl(ethyl)sulfane 1562257-91-3 C12H22S
    dec-1-yn-1-yl(ethyl)sulfane
    —— (E)-N-methyl-2-((3-(2-(pyridin-2-yl)vinyl)-1-(tetrahydro-2H-pyran-2-yl)-1H-indazol-6-yl)thio)benzamide 885126-35-2 C27H26N4O2S
    (E)-N-methyl-2-((3-(2-(pyridin-2-yl)vinyl)-1-(tetrahydro-2H-pyran-2-yl)-1H-indazol-6-yl)thio)benzamide
    —— N-(2-(1-methyl-2-piperidynyl)ethyl)-2-(2-fluorophenylthio)-5-(methylthio)aniline 129846-85-1 C21H27FN2S2
    N-(2-(1-methyl-2-piperidynyl)ethyl)-2-(2-fluorophenylthio)-5-(methylthio)aniline
    —— sulfur dioxide-bis(tricyclohexylphosphane)-nickel(0) 94888-51-4 C36H66NiO2P2S
    sulfur dioxide-bis(tricyclohexylphosphane)-nickel(0)
    —— (2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-2-(pyrimidin-2-ylthio)tetrahydro-2H-pyran-3-yl methyl carbonate 78443-17-1 C14H21N3O4S
    (2S,3R,4S,6R)-4-(dimethylamino)-6-methyl-2-(pyrimidin-2-ylthio)tetrahydro-2H-pyran-3-yl methyl carbonate
    —— 1,1,2,2-tetrafluoro-1-pentafluoroethyloxy-4-thiocyanatobutane 1353321-82-0 C7H4F9NOS
    1,1,2,2-tetrafluoro-1-pentafluoroethyloxy-4-thiocyanatobutane
    —— chloromethyl phenylsulfanylformate 133217-39-7 C8H7ClO2S
    chloromethyl phenylsulfanylformate
    —— [((5Z,8Z,11Z,14Z,17Z)-Icosa-5,8,11,14,17-pentaenyl)sulfanyl]-benzene 690223-81-5 C26H36S
    [((5Z,8Z,11Z,14Z,17Z)-Icosa-5,8,11,14,17-pentaenyl)sulfanyl]-benzene
    —— N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanethiosulfenyl) carbamoyl fluoride 65839-35-2 C9H16FNO2S2
    N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanethiosulfenyl) carbamoyl fluoride
    —— 4-[N,N-bis(2-hydroxyethyl)amino]benzenethiocyanate 99841-22-2 C11H14N2O2S
    4-[N,N-bis(2-hydroxyethyl)amino]benzenethiocyanate
    —— (NZ)-N-(1-amino-2,2,2-trifluoroethylidene)sulfamoyl fluoride 27970-42-9 C2H2F4N2O2S
    (NZ)-N-(1-amino-2,2,2-trifluoroethylidene)sulfamoyl fluoride
    —— <i>N</i>-acetyl-<i>N</i>-allyl-thiourea 860750-33-0 C6H10N2OS
    <i>N</i>-acetyl-<i>N</i>-allyl-thiourea
    —— bis(dimethyltetrathiooxalate)nickel 71081-61-3 C8H12NiS8
    bis(dimethyltetrathiooxalate)nickel
    —— bis-(dimethylthiocarbamoylsulfanyl-methyl)-ether 13575-66-1 C8H16N2OS4
    bis-(dimethylthiocarbamoylsulfanyl-methyl)-ether
    —— 142457-46-3 C14H14N2NiS2
    —— 4,5,4',5'-Tetramethoxy-2,2'-bis-iodmethyl-diphenylsulfid 94066-91-8 C18H20I2O4S
    4,5,4',5'-Tetramethoxy-2,2'-bis-iodmethyl-diphenylsulfid
    —— N,N'-bis[2-(methylthio)phenyl]-1,2-diaminoethane 144919-18-6 C16H20N2S2
    N,N'-bis[2-(methylthio)phenyl]-1,2-diaminoethane
    —— octakis(3,4-dimethylphenylthio)naphthalene 181043-31-2 C74H72S8
    octakis(3,4-dimethylphenylthio)naphthalene
    —— S-ethyl-N-hydroxyacetimidate 20639-32-1 C4H9NOS
    S-ethyl-N-hydroxyacetimidate
    —— 3-(phenylthio)tetrahydrofuran 64823-94-5 C10H12OS
    3-(phenylthio)tetrahydrofuran
    —— 1-chloro-1-(phenylthio)-1-octene 83818-62-6 C14H19ClS
    1-chloro-1-(phenylthio)-1-octene
    —— 2-(phenylthio)benzyl thiocyanate 1274916-78-7 C14H11NS2
    2-(phenylthio)benzyl thiocyanate
    —— dithiooxalodiimidic acid diethyl ester 13534-35-5 C6H12N2S2
    dithiooxalodiimidic acid diethyl ester
    —— zinc(II) thiocyanate 557-42-6 2CNS*Zn
    zinc(II) thiocyanate
    —— 1,2-bis(1H-tetrazol-5-ylthio)ethane 112298-94-9 C4H6N8S2
    1,2-bis(1H-tetrazol-5-ylthio)ethane
    —— 2-methyl-4-(1,2,2,2-tetrafluoro-1-trifluoromethylethyl)-6-thiocyanatophenylamine 1126745-45-6 C11H7F7N2S
    2-methyl-4-(1,2,2,2-tetrafluoro-1-trifluoromethylethyl)-6-thiocyanatophenylamine