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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-{[(2,2-dimethyl-1,3-dioxolan-4-yl)methyl]thio}pyrimidin-4(1H)-one 1160617-55-9 C10H14N2O3S
    2-{[(2,2-dimethyl-1,3-dioxolan-4-yl)methyl]thio}pyrimidin-4(1H)-one
    —— 2-<3-Chlor-pyridyl-(2)-mercapto>-acetaldehyd-diethylacetal 5897-99-4 C11H16ClNO2S
    2-<3-Chlor-pyridyl-(2)-mercapto>-acetaldehyd-diethylacetal
    —— benzyl(2,3,5,6-tetrafluoro-4-((perfluorophenyl)thio)phenyl)sulfane 33288-17-4 C19H7F9S2
    benzyl(2,3,5,6-tetrafluoro-4-((perfluorophenyl)thio)phenyl)sulfane
    —— N,N-dimethyl 2-chloropropenethioamide 101538-29-8 C5H8ClNS
    N,N-dimethyl 2-chloropropenethioamide
    —— 4-methoxy-2-(methylsulfanyl)-6-[(2-oxoethyl)amino]pyrimidine-5-carbonitrile 1476056-54-8 C9H10N4O2S
    4-methoxy-2-(methylsulfanyl)-6-[(2-oxoethyl)amino]pyrimidine-5-carbonitrile
    —— [2-(2,4-Dimethyl-10-thia-1,3,9-triaza-anthracen-9-yl)-ethyl]-diethyl-amine 6981-89-1 C18H24N4S
    [2-(2,4-Dimethyl-10-thia-1,3,9-triaza-anthracen-9-yl)-ethyl]-diethyl-amine
    —— [2-(2-Methylsulfanylcarbonylamino-ethylsulfanyl)-ethyl]-thiocarbamic acid S-methyl ester 92381-53-8 C8H16N2O2S3
    [2-(2-Methylsulfanylcarbonylamino-ethylsulfanyl)-ethyl]-thiocarbamic acid S-methyl ester
    —— (1R,3S,5R,6R)-O-1,8-dimethyl-3-ethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-yl S-methyl dithiocarbonate 109431-04-1 C13H20O3S2
    (1R,3S,5R,6R)-O-1,8-dimethyl-3-ethyl-2,9-dioxabicyclo<3.3.1>non-7-en-6-yl S-methyl dithiocarbonate
    —— [2-(4-Chloro-phenylsulfanyl)-2-ethyl-butyryl]-urea 21310-58-7 C13H17ClN2O2S
    [2-(4-Chloro-phenylsulfanyl)-2-ethyl-butyryl]-urea
    —— dimethyl 2-(2-((4-chlorophenyl)thio)-2-(5-methylfuran-2-yl)ethyl)malonate 1462945-78-3 C18H19ClO5S
    dimethyl 2-(2-((4-chlorophenyl)thio)-2-(5-methylfuran-2-yl)ethyl)malonate
    —— Dibutyl-dithiocarbamic acid 4,6-dimethyl-pyrimidin-2-yl ester 32595-23-6 C15H25N3S2
    Dibutyl-dithiocarbamic acid 4,6-dimethyl-pyrimidin-2-yl ester
    —— 5-ethyl-2-(2-[2]thienylmercapto-ethyl)-pyridine 100373-67-9 C13H15NS2
    5-ethyl-2-(2-[2]thienylmercapto-ethyl)-pyridine
    —— 5,8-Bis-phenylmercapto-pyrazino<2,3-d>pyridazin 13480-50-7 C18H12N4S2
    5,8-Bis-phenylmercapto-pyrazino<2,3-d>pyridazin
    —— 3-methyl-1-phenylthio-2-octene-4-one 110362-86-2 C15H20OS
    3-methyl-1-phenylthio-2-octene-4-one
    —— 2,13-diethoxy-benzo[a][1,4]benzothiazino[3,2-c]phenothiazine 56536-76-6 C26H20N2O2S2
    2,13-diethoxy-benzo[a][1,4]benzothiazino[3,2-c]phenothiazine
    —— 5-(Phenylsulfanyl-trimethylsilanyl-methyl)-undecan-6-one 86029-79-0 C21H36OSSi
    5-(Phenylsulfanyl-trimethylsilanyl-methyl)-undecan-6-one
    —— 6-methoxy-2-phenyl-4<i>H</i>,7<i>H</i>-[1,3]dithiino[5,4-<i>d</i>]pyrimidin-8-one 15497-19-5 C13H12N2O2S2
    6-methoxy-2-phenyl-4<i>H</i>,7<i>H</i>-[1,3]dithiino[5,4-<i>d</i>]pyrimidin-8-one
    —— 5-(3-chlorophenylthio)-2(1H)-pyrimidinone 121487-03-4 C10H7ClN2OS
    5-(3-chlorophenylthio)-2(1H)-pyrimidinone
    —— 7-acetoxy-6-(4'-methoxyphenylthio)-Δ6-1-octalone 65173-98-0 C19H22O4S
    7-acetoxy-6-(4'-methoxyphenylthio)-Δ6-1-octalone
    —— 1-[2-({3-[2-(benzyloxy)-3-chlorophenyl][1,2,4]triazolo[4,3-a]pyridin-6-yl}thio)phenyl]methanamine 1344738-19-7 C26H21ClN4OS
    1-[2-({3-[2-(benzyloxy)-3-chlorophenyl][1,2,4]triazolo[4,3-a]pyridin-6-yl}thio)phenyl]methanamine
    —— methyl 2-((1S,2S,3S,4R)-4-(6-chloro-5-nitro-2-(propylthio)-pyrimidin-4-ylamino)-2,3-dihydroxycyclopentyloxy)acetate 1402150-06-4 C15H21ClN4O7S
    methyl 2-((1S,2S,3S,4R)-4-(6-chloro-5-nitro-2-(propylthio)-pyrimidin-4-ylamino)-2,3-dihydroxycyclopentyloxy)acetate
    —— 2,4-bis(i-propylthio)toluene 87544-09-0 C13H20S2
    2,4-bis(i-propylthio)toluene
    —— 4,6-Di(2-aminophenylthio)-5-nitro-2-phenyl-pyrimidin 37412-36-5 C22H17N5O2S2
    4,6-Di(2-aminophenylthio)-5-nitro-2-phenyl-pyrimidin
    —— (S)-4,4,4-trifluoro-1-(4-iodo-3,5-dimethyl-1H-pyrazol-1-yl)-3-(phenylthio)butan-1-one 1374034-28-2 C15H14F3IN2OS
    (S)-4,4,4-trifluoro-1-(4-iodo-3,5-dimethyl-1H-pyrazol-1-yl)-3-(phenylthio)butan-1-one
    —— 5-Chloro-2-(5-nitro-furan-2-ylsulfanyl)-1H-benzoimidazole 32570-71-1 C11H6ClN3O3S
    5-Chloro-2-(5-nitro-furan-2-ylsulfanyl)-1H-benzoimidazole
    —— 2-(3-pyridinyl)-5-(4-methylphenylthio)-1,3,4-oxadiazole 1414598-65-4 C14H11N3OS
    2-(3-pyridinyl)-5-(4-methylphenylthio)-1,3,4-oxadiazole
    —— 2-Chlor-1-isothiocyanato-propan 13163-26-3 C4H6ClNS
    2-Chlor-1-isothiocyanato-propan
    —— 1-butylsulfonyl-1-bromoethene 80623-48-9 C6H11BrO2S
    1-butylsulfonyl-1-bromoethene
    —— <i>N</i>-allyl-2-(4,5,6,7-tetrahydro-benzothiazol-2-ylsulfanyl)-acetamide 23888-40-6 C12H16N2OS2
    <i>N</i>-allyl-2-(4,5,6,7-tetrahydro-benzothiazol-2-ylsulfanyl)-acetamide
    —— Cyclohexylmethylxanthogenat 74169-12-3 C8H14OS2
    Cyclohexylmethylxanthogenat
    —— dimethyl 2,2'-((2-thioxo-1,3-dithiole-4,5-diyl)bis(sulfanediyl))dibenzoate 1449507-05-4 C19H14O4S5
    dimethyl 2,2'-((2-thioxo-1,3-dithiole-4,5-diyl)bis(sulfanediyl))dibenzoate
    —— 1-Benzyl-4-methylthio-triazol-(1,2,3) 36811-25-3 C10H11N3S
    1-Benzyl-4-methylthio-triazol-(1,2,3)
    —— (3R,4S)-4-Methyl-4-phenylsulfanyl-heptane-1,3,7-triol 131074-40-3 C14H22O3S
    (3R,4S)-4-Methyl-4-phenylsulfanyl-heptane-1,3,7-triol
    —— [1,3]Dithiolo[4,5-d]-1,3-dithiolethione, (1-propylbutylidene)- 144028-61-5 C11H14S5
    [1,3]Dithiolo[4,5-d]-1,3-dithiolethione, (1-propylbutylidene)-
    —— (Z)-(6S,7S,8R)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4,6,8-tetramethyl-9-phenylsulfanyl-non-3-en-5-one 116839-21-5 C25H42O2SSi
    (Z)-(6S,7S,8R)-7-(tert-Butyl-dimethyl-silanyloxy)-2,4,6,8-tetramethyl-9-phenylsulfanyl-non-3-en-5-one
    —— N-[4-(2-fluoro-4-nitrophenylthio)phenyl]acetamide 771477-10-2 C14H11FN2O3S
    N-[4-(2-fluoro-4-nitrophenylthio)phenyl]acetamide
    —— 1-(1,3-Dichloropropan-2-ylsulfanyl)octane 210481-65-5 C11H22Cl2S
    1-(1,3-Dichloropropan-2-ylsulfanyl)octane
    —— (4-Phenyl-[1,2,3]selenadiazol-5-ylsulfanyl)-acetic acid 200576-88-1 C10H8N2O2SSe
    (4-Phenyl-[1,2,3]selenadiazol-5-ylsulfanyl)-acetic acid
    —— (1S,2S,5R)-5-methyl-1-trifluoromethyl-2-[(4-methylphenyl)sulfenyl]-6,8-dioxabicyclo[3.2.1]octane 248957-70-2 C15H17F3O2S
    (1S,2S,5R)-5-methyl-1-trifluoromethyl-2-[(4-methylphenyl)sulfenyl]-6,8-dioxabicyclo[3.2.1]octane
    —— 193607-73-7 C2H2O4*C24H36N6OS
    —— 2-(4-chloro-phenylsulfanyl)-N-hydroxy-N-morpholin-4-ylmethyl-acetamide 41402-65-7 C13H17ClN2O3S
    2-(4-chloro-phenylsulfanyl)-N-hydroxy-N-morpholin-4-ylmethyl-acetamide
    —— 2-methoxycarbonylmethyl-[1,3]oxathiolane-2-carboxylic acid methyl ester 30125-27-0 C8H12O5S
    2-methoxycarbonylmethyl-[1,3]oxathiolane-2-carboxylic acid methyl ester
    —— Methyl-dithiophosphonsaeure-O-Methyl-S-<2-(4-methylmercapto-phenylmercapto)-aethyl>-ester 91250-50-9 C11H17OPS4
    Methyl-dithiophosphonsaeure-O-Methyl-S-<2-(4-methylmercapto-phenylmercapto)-aethyl>-ester
    —— N,N-Bis-(2-hydroxyethyl)-2-<(4-hydroxy-6-methyl-2-pyrimidinyl)-thio>-acetamid 21004-26-2 C11H17N3O4S
    N,N-Bis-(2-hydroxyethyl)-2-<(4-hydroxy-6-methyl-2-pyrimidinyl)-thio>-acetamid
    —— 3-methyl-5-(4-methyl-5-nitro-thiazol-2-ylsulfanyl)-[1,2,4]thiadiazole 21735-02-4 C7H6N4O2S3
    3-methyl-5-(4-methyl-5-nitro-thiazol-2-ylsulfanyl)-[1,2,4]thiadiazole
    —— Tris-(1-chlor-ethyliden-sulfin) 46848-33-3 C6H9Cl3O6S3
    Tris-(1-chlor-ethyliden-sulfin)
    —— 4-Isopentyl-4-methyl-1,7,3,5-dioxadithionane 20991-35-9 C11H22O2S2
    4-Isopentyl-4-methyl-1,7,3,5-dioxadithionane
    —— (4-Chloro-2-methyl-phenylsulfanyl)-(dimethoxy-thiophosphorylsulfanyl)-acetic acid ethyl ester 28053-94-3 C13H18ClO4PS3
    (4-Chloro-2-methyl-phenylsulfanyl)-(dimethoxy-thiophosphorylsulfanyl)-acetic acid ethyl ester
    —— (3S)-3-(1,3-benzodithiol-2-yl)-4-hydroxybutanenitrile 1333204-01-5 C11H11NOS2
    (3S)-3-(1,3-benzodithiol-2-yl)-4-hydroxybutanenitrile
    —— 2-phenyl-3-phenylthio-1-thiochroman 130779-69-0 C21H18S2
    2-phenyl-3-phenylthio-1-thiochroman