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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— hexafluoro-2,3-butanedithione 55162-21-5 C4F6S2
    hexafluoro-2,3-butanedithione
    —— (2-chloroethyl)(2-((2-chloroethyl)thio)ethyl)(2-hydroxyethyl)sulfonium chloride 170424-99-4 C8H17Cl2OS2*Cl
    (2-chloroethyl)(2-((2-chloroethyl)thio)ethyl)(2-hydroxyethyl)sulfonium chloride
    —— 2-(4,5-bis(dodecylthio)-1,3-dithiol-2-ylidene)-5,6,8,9,16,17,19,20-octahydrobenzo[e][1,3]dithiolo[4,5-n][1,4,7,10]tetraoxa[13,16]dithiacyclooctadecine-12,13-dicarbonitrile 850533-68-5 C46H68N2O4S8
    2-(4,5-bis(dodecylthio)-1,3-dithiol-2-ylidene)-5,6,8,9,16,17,19,20-octahydrobenzo[e][1,3]dithiolo[4,5-n][1,4,7,10]tetraoxa[13,16]dithiacyclooctadecine-12,13-dicarbonitrile
    —— 2-(1-(4-((4-(1-(2-carbamothioylhydrazono)ethyl)phenyl)thio)phenyl)ethylidene)hydrazine-1-carboxamide 745076-16-8 C18H20N6OS2
    2-(1-(4-((4-(1-(2-carbamothioylhydrazono)ethyl)phenyl)thio)phenyl)ethylidene)hydrazine-1-carboxamide
    —— N-[2-(pyridin-2-ylsulfanyl)-ethyl]-thioacetimidic acid methyl ester 786686-84-8 C10H14N2S2
    N-[2-(pyridin-2-ylsulfanyl)-ethyl]-thioacetimidic acid methyl ester
    —— 1-(((2-cyanoethyl)thio)(methylthio)methylene)piperidin-1-ium trifluoromethanesulfonate 1514912-52-7 CF3O3S*C10H17N2S2
    1-(((2-cyanoethyl)thio)(methylthio)methylene)piperidin-1-ium trifluoromethanesulfonate
    —— tris(dimethyl(oxo)-l6-sulfaneyl)trihydroxyruthenium(VIII) 72916-74-6 C6H24O6RuS3
    tris(dimethyl(oxo)-l6-sulfaneyl)trihydroxyruthenium(VIII)
    —— Tetrathiomalonsaeure-diethylester 23664-10-0 C7H12S4
    Tetrathiomalonsaeure-diethylester
    —— catena((μ2-1,4-diaminobutane-N,N`)dicyanomercury(II)) 1211996-71-2 C6H12HgN4
    catena((μ2-1,4-diaminobutane-N,N`)dicyanomercury(II))
    —— 1-Methyl-7-methylsulfanyl-3-nitro-1H-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one 116061-64-4 C6H6N6O3S
    1-Methyl-7-methylsulfanyl-3-nitro-1H-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one
    —— 1-Ethylamino-7-ethylimino-4-phenylmercapto-cyclohepta-1.3.5-trien 97405-49-7 C17H20N2S
    1-Ethylamino-7-ethylimino-4-phenylmercapto-cyclohepta-1.3.5-trien
    —— <i>S</i>,<i>S</i>'-diethyl-<i>S</i>,<i>S</i>'-bis-(2-hydroxy-ethyl)-<i>S</i>,<i>S</i>'-(3-thia-pentane-1,5-diyl)-bis-sulfonium; dichloride 106502-83-4 C12H28O2S3*2Cl
    <i>S</i>,<i>S</i>'-diethyl-<i>S</i>,<i>S</i>'-bis-(2-hydroxy-ethyl)-<i>S</i>,<i>S</i>'-(3-thia-pentane-1,5-diyl)-bis-sulfonium; dichloride
    —— (2-chloro-ethyl)-(1,1,2,2-tetrachloro-ethyl)-sulfide 856165-15-6 C4H5Cl5S
    (2-chloro-ethyl)-(1,1,2,2-tetrachloro-ethyl)-sulfide
    —— 6-methoxy-2-(methylthio)-3-phenylpyrimidin-4(3H)-one 339593-38-3 C12H12N2O2S
    6-methoxy-2-(methylthio)-3-phenylpyrimidin-4(3H)-one
    —— tris-(2-chloro-ethyl)-sulfonium , iodide 119301-01-8 C6H12Cl3S*I
    tris-(2-chloro-ethyl)-sulfonium , iodide
    —— cis-diaquo-cis-bis(dimethyl sulfoxide)-trans-dichloro-ruthenium(II) 870527-23-4 C4H16Cl2O4RuS2
    cis-diaquo-cis-bis(dimethyl sulfoxide)-trans-dichloro-ruthenium(II)
    —— N-(3-(methylthio)phenyl)cyanamide 458567-42-5 C8H8N2S
    N-(3-(methylthio)phenyl)cyanamide
    —— ethyl(2-(ethylthio)ethyl)(2-hydroxyethyl)sulfonium chloride 107327-28-6 C8H19OS2*Cl
    ethyl(2-(ethylthio)ethyl)(2-hydroxyethyl)sulfonium chloride
    —— (1,2-dichloro-ethyl)-(1,1,2,2-tetrachloro-ethyl)-sulfide 856060-77-0 C4H4Cl6S
    (1,2-dichloro-ethyl)-(1,1,2,2-tetrachloro-ethyl)-sulfide
    —— praseodymium(III) (cysteinate)3 81818-17-9 C9H18N3O6PrS3
    praseodymium(III) (cysteinate)3
    —— bis-(2-fluoro-ethyl)-sulfide 373-25-1 C4H8F2S
    bis-(2-fluoro-ethyl)-sulfide
    —— 1-[2-Methyl-2-methylsulfanyl-1-(3-propan-2-ylpyrazol-1-yl)propyl]-3-propan-2-ylpyrazole 936476-24-3 C17H28N4S
    1-[2-Methyl-2-methylsulfanyl-1-(3-propan-2-ylpyrazol-1-yl)propyl]-3-propan-2-ylpyrazole
    —— (2-chloro-ethyl)-pentachloroethyl sulfide 861563-29-3 C4H4Cl6S
    (2-chloro-ethyl)-pentachloroethyl sulfide
    —— cis-Mo(18)O2(S2CNEt2)2 63912-66-3 C10H20MoN2O2S4
    cis-Mo(18)O2(S2CNEt2)2
    —— bis-[2-(2-methylsulfanyl-ethylsulfanyl)-ethyl]-sulfane 54595-69-6 C10H22S5
    bis-[2-(2-methylsulfanyl-ethylsulfanyl)-ethyl]-sulfane
    —— 1,11-bis-methanesulfinyl-undecane-2,10-dione 2813-26-5 C13H24O4S2
    1,11-bis-methanesulfinyl-undecane-2,10-dione
    —— 2-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]pyridine 1-oxide 943227-54-1 C12H10F5N3O2S
    2-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]pyridine 1-oxide
    —— (2-chloro-ethyl)-(2-chloro-vinyl)-sulfide 873408-12-9 C4H6Cl2S
    (2-chloro-ethyl)-(2-chloro-vinyl)-sulfide
    —— tris(benzene-1,2-dithiolate)molybdenum(VI) 10507-76-3 C18H12MoS6
    tris(benzene-1,2-dithiolate)molybdenum(VI)
    —— 4-[[1,3-Bis(3-chlorophenyl)-4-[(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)imino]-1,3-diazetidin-2-ylidene]amino]-6-methyl-3-methylsulfanyl-1,2,4-triazin-5-one 111981-40-9 C24H20Cl2N10O2S2
    4-[[1,3-Bis(3-chlorophenyl)-4-[(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)imino]-1,3-diazetidin-2-ylidene]amino]-6-methyl-3-methylsulfanyl-1,2,4-triazin-5-one
    —— (2-chloro-ethyl)-(1,2-dichloro-ethyl)-sulfide 40709-89-5 C4H7Cl3S
    (2-chloro-ethyl)-(1,2-dichloro-ethyl)-sulfide
    —— 2-(4,5-bis(dodecylthio)-1,3-dithiol-2-ylidene)-12,13-dibromo-5,6,8,9,16,17,19,20-octahydrobenzo[e][1,3]dithiolo[4,5-n][1,4,7,10]tetraoxa[13,16]dithiacyclooctadecine 850533-67-4 C44H68Br2O4S8
    2-(4,5-bis(dodecylthio)-1,3-dithiol-2-ylidene)-12,13-dibromo-5,6,8,9,16,17,19,20-octahydrobenzo[e][1,3]dithiolo[4,5-n][1,4,7,10]tetraoxa[13,16]dithiacyclooctadecine
    —— 2,3-dihydro-5-bischloroethylaminomethyl-6-chloroimidazo<2,1-b>thiazole 120123-66-2 C10H14Cl3N3S
    2,3-dihydro-5-bischloroethylaminomethyl-6-chloroimidazo<2,1-b>thiazole
    —— di(tert-butylsulfenyl)mercury 3374-16-1 C8H18HgS2
    di(tert-butylsulfenyl)mercury
    —— 2-(4-(2-amino-4-cyclopropylthiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol 869854-13-7 C15H15F3N2OS2
    2-(4-(2-amino-4-cyclopropylthiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol
    —— cis-Mo(18)O2(S2CN(n-Pr)2)2 63912-67-4 C14H28MoN2O2S4
    cis-Mo(18)O2(S2CN(n-Pr)2)2
    —— sulfurous difluoride-18O 82040-67-3 F2OS
    sulfurous difluoride-18O
    —— 2-(1-(4-((4-(1-((4-methylthiazol-2(5H)-ylidene)hydrazono)ethyl)phenyl)thio)phenyl)ethylidene)hydrazine-1-carbothioamide 745076-33-9 C21H22N6S3
    2-(1-(4-((4-(1-((4-methylthiazol-2(5H)-ylidene)hydrazono)ethyl)phenyl)thio)phenyl)ethylidene)hydrazine-1-carbothioamide
    —— N-methyl-N-(3-(methylthio)phenyl)cyanamide 222734-73-8 C9H10N2S
    N-methyl-N-(3-(methylthio)phenyl)cyanamide
    —— (2-chloro-ethyl)-(1,1,2-trichloro-ethyl)-sulfide 195213-78-6 C4H6Cl4S
    (2-chloro-ethyl)-(1,1,2-trichloro-ethyl)-sulfide
    —— 4-(7-(methylthio)-3-nitro-4-oxo-[1,2,4]triazolo[5,1-c][1,2,4]triazin-1(4H)-yl)butyl acetate 1235564-23-4 C11H14N6O5S
    4-(7-(methylthio)-3-nitro-4-oxo-[1,2,4]triazolo[5,1-c][1,2,4]triazin-1(4H)-yl)butyl acetate
    —— 2-(1-(4-((4-(1-((4-oxothiazolidin-2-ylidene)hydrazono)ethyl)phenyl)thio)phenyl)ethylidene)hydrazine-1-carbothioamide 745076-30-6 C20H20N6OS3
    2-(1-(4-((4-(1-((4-oxothiazolidin-2-ylidene)hydrazono)ethyl)phenyl)thio)phenyl)ethylidene)hydrazine-1-carbothioamide
    —— (Z)-4-((1-(4-chlorophenyl)-6-((4-chlorophenyl)amino)-4-phenyl-1,3,5-triazin-2(1H)-ylidene)amino)-6-methyl-3-(methylthio)-1,2,4-triazin-5(4H)-one 118543-23-0 C26H20Cl2N8OS
    (Z)-4-((1-(4-chlorophenyl)-6-((4-chlorophenyl)amino)-4-phenyl-1,3,5-triazin-2(1H)-ylidene)amino)-6-methyl-3-(methylthio)-1,2,4-triazin-5(4H)-one
    —— 7-methyl-2,3-dihydro-3-dimethylaminomethylenethiopyrano[2,3-b]pyridin-4(4H)-one 640265-22-1 C12H14N2OS
    7-methyl-2,3-dihydro-3-dimethylaminomethylenethiopyrano[2,3-b]pyridin-4(4H)-one
    —— (2-methylthiopyrimidin-5-yl)cerium(III) chloride 127041-87-6 C5H5CeCl2N2S
    (2-methylthiopyrimidin-5-yl)cerium(III) chloride
    —— 2-[1,1-dichloro-2,2-difluoro-2-(tetrahydropyran-4-yl)ethyl-sulphanyl]pyridine 929705-71-5 C12H13Cl2F2NOS
    2-[1,1-dichloro-2,2-difluoro-2-(tetrahydropyran-4-yl)ethyl-sulphanyl]pyridine
    —— tris-(2-chloro-ethyl)-sulfonium , bromide 116636-60-3 Br*C6H12Cl3S
    tris-(2-chloro-ethyl)-sulfonium , bromide
    —— bis(2,4-dimethylphenylthioethyl)amine 1442637-91-3 C20H27NS2
    bis(2,4-dimethylphenylthioethyl)amine
    —— 2-amino-4-(4-chlorophenyl)-5-[(4-chlorophenyl)sulfanyl]-6-methyl-4H-pyran-3-carbonitrile —— C19H14Cl2N2OS
    2-amino-4-(4-chlorophenyl)-5-[(4-chlorophenyl)sulfanyl]-6-methyl-4H-pyran-3-carbonitrile
    —— 1,4,5,8-tetrathia-10-cyclododecyne —— C8H12S4
    1,4,5,8-tetrathia-10-cyclododecyne