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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-Chlorophenyl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C14H7ClN4OS2
    2-(2-Chlorophenyl)-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— 2-(2-Methylfuran-3-yl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C16H14N4O2S2
    2-(2-Methylfuran-3-yl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-(2-methylfuran-3-yl)-5-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C18H16N4O2S2
    2-(2-methylfuran-3-yl)-5-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-[[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile —— C15H7BrN4O3S
    2-[[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile
    —— 2-(2-Fluorophenyl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole —— C18H13FN4OS2
    2-(2-Fluorophenyl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-pyridin-3-yl-1,3,4-oxadiazole —— C15H11N5OS2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-pyridin-3-yl-1,3,4-oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(2-fluorophenyl)-1,3,4-oxadiazole —— C16H11FN4OS2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(2-fluorophenyl)-1,3,4-oxadiazole
    —— 2-Pyridin-3-yl-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C16H13N5OS2
    2-Pyridin-3-yl-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile —— C15H7FN4O3S
    2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-5-nitrobenzonitrile
    —— 2-(4-methoxyphenyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C20H18N4O2S2
    2-(4-methoxyphenyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-[5-(4-Methylphenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-pyridin-3-yl-1,3,4-oxadiazole —— C20H13N5OS2
    2-[5-(4-Methylphenyl)thieno[2,3-d]pyrimidin-4-yl]sulfanyl-5-pyridin-3-yl-1,3,4-oxadiazole
    —— 2-Pyridin-3-yl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole —— C13H7N5OS2
    2-Pyridin-3-yl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-oxadiazole
    —— N-butyl-5-(2-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-amine —— C12H14N4O2S2
    N-butyl-5-(2-nitrophenyl)sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-(6-Phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-pyridin-3-yl-1,3,4-oxadiazole —— C19H11N5OS2
    2-(6-Phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-pyridin-3-yl-1,3,4-oxadiazole
    —— 2-(4-Methoxyphenyl)-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole —— C18H14N4O2S2
    2-(4-Methoxyphenyl)-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(2-chlorophenyl)-1,3,4-oxadiazole —— C14H7Cl2N3O3S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(2-chlorophenyl)-1,3,4-oxadiazole
    —— 2-(4-methoxyphenyl)-5-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C20H18N4O2S2
    2-(4-methoxyphenyl)-5-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C14H7ClFN3O3S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(furan-2-yl)-1,3,4-oxadiazole —— C12H6ClN3O4S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(furan-2-yl)-1,3,4-oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C16H11FN4OS2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— 2-(2-Fluorophenyl)-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole —— C17H11FN4OS2
    2-(2-Fluorophenyl)-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-(furan-2-yl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C17H14N4O2S2
    2-(furan-2-yl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-(2-chlorophenyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C19H15ClN4OS2
    2-(2-chlorophenyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-Cyclopropyl-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C14H14N4OS2
    2-Cyclopropyl-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-(4-fluorophenyl)-5-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C19H15FN4OS2
    2-(4-fluorophenyl)-5-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-(2-Chlorophenyl)-5-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)-1,3,4-oxadiazole —— C18H13ClN4OS2
    2-(2-Chlorophenyl)-5-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole —— C13H8ClN3O4S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(2-methylfuran-3-yl)-1,3,4-oxadiazole
    —— 2-(4-fluorophenyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole —— C19H15FN4OS2
    2-(4-fluorophenyl)-5-[[(7S)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3,4-oxadiazole
    —— 2-(2-Chlorophenyl)-5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C16H11ClN4OS2
    2-(2-Chlorophenyl)-5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-Pyridin-3-yl-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole —— C16H11N5OS2
    2-Pyridin-3-yl-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-(Furan-2-yl)-5-(2-nitrophenyl)sulfanyl-1,3,4-oxadiazole —— C12H7N3O4S
    2-(Furan-2-yl)-5-(2-nitrophenyl)sulfanyl-1,3,4-oxadiazole
    —— 2-Cyclopropyl-5-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-1,3,4-oxadiazole —— C12H11N3O5S2
    2-Cyclopropyl-5-(4-methylsulfonyl-2-nitrophenyl)sulfanyl-1,3,4-oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(furan-2-yl)-1,3,4-oxadiazole —— C14H10N4O2S2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(furan-2-yl)-1,3,4-oxadiazole
    —— 2-(4-Fluorophenyl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole —— C18H13FN4OS2
    2-(4-Fluorophenyl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole
    —— 2-(4-Methoxyphenyl)-5-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)-1,3,4-oxadiazole —— C19H16N4O2S2
    2-(4-Methoxyphenyl)-5-(5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-ylsulfanyl)-1,3,4-oxadiazole
    —— 2-(2,4-Dinitro-phenylsulfanyl)-5-(4-fluoro-phenyl)-[1,3,4]oxadiazole 124946-16-3 C14H7FN4O5S
    2-(2,4-Dinitro-phenylsulfanyl)-5-(4-fluoro-phenyl)-[1,3,4]oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(4-methoxyphenyl)-1,3,4-oxadiazole —— C17H14N4O2S2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-(4-methoxyphenyl)-1,3,4-oxadiazole
    —— 2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-phenyl-1,3,4-oxadiazole —— C16H12N4OS2
    2-(5,6-Dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-5-phenyl-1,3,4-oxadiazole
    —— 2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(4-chlorophenyl)-1,3,4-oxadiazole —— C14H7Cl2N3O3S
    2-(2-Chloro-4-nitrophenyl)sulfanyl-5-(4-chlorophenyl)-1,3,4-oxadiazole
    —— 11-Prop-2-enyl-10-thieno[2,3-d]pyrimidin-4-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one —— C18H14N4OS3
    11-Prop-2-enyl-10-thieno[2,3-d]pyrimidin-4-ylsulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one
    —— 2-Phenyl-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole —— C17H12N4OS2
    2-Phenyl-5-(7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-ylsulfanyl)-1,3,4-oxadiazole
    —— 5,6-Dimethyl-2-(2-nitrophenyl)sulfanyl-3-prop-2-enylthieno[2,3-d]pyrimidin-4-one —— C17H15N3O3S2
    5,6-Dimethyl-2-(2-nitrophenyl)sulfanyl-3-prop-2-enylthieno[2,3-d]pyrimidin-4-one
    —— 10-(2-Nitrophenyl)sulfanyl-11-prop-2-enyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one —— C18H15N3O3S2
    10-(2-Nitrophenyl)sulfanyl-11-prop-2-enyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9-trien-12-one
    —— 2-(1,3-Benzodioxol-5-yl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole —— C19H14N4O3S2
    2-(1,3-Benzodioxol-5-yl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole
    —— 2-(4-Chlorophenyl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole —— C18H13ClN4OS2
    2-(4-Chlorophenyl)-5-[(10-methyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-12-yl)sulfanyl]-1,3,4-oxadiazole
    —— 2-Phenyl-5-(6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C20H12N4OS2
    2-Phenyl-5-(6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-(4-Chlorophenyl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C17H13ClN4OS2
    2-(4-Chlorophenyl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— N-benzyl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-thiadiazol-2-amine —— C15H11N5S3
    N-benzyl-5-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-(3,4-Dimethoxyphenyl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C19H18N4O3S2
    2-(3,4-Dimethoxyphenyl)-5-(2,5,6-trimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole
    —— 2-(1,3-Benzodioxol-5-yl)-5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole —— C17H12N4O3S2
    2-(1,3-Benzodioxol-5-yl)-5-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-oxadiazole