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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(4-methylsulfanylphenyl)methyl]-3-[(2S)-1-(1,3,5-trimethylpyrazol-4-yl)propan-2-yl]urea —— C18H26N4OS
    1-[(4-methylsulfanylphenyl)methyl]-3-[(2S)-1-(1,3,5-trimethylpyrazol-4-yl)propan-2-yl]urea
    —— N-methyl-4-naphthalen-2-ylsulfanyl-3-nitrobenzenesulfonamide —— C17H14N2O4S2
    N-methyl-4-naphthalen-2-ylsulfanyl-3-nitrobenzenesulfonamide
    —— 4-Naphthalen-2-ylsulfanyl-3-nitrobenzenesulfonamide —— C16H12N2O4S2
    4-Naphthalen-2-ylsulfanyl-3-nitrobenzenesulfonamide
    —— 4-(2-Fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide —— C12H9FN2O4S2
    4-(2-Fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 4-[4-(2-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonylmorpholine —— C16H15FN2O5S2
    4-[4-(2-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonylmorpholine
    —— (1R)-1-(3-chlorophenyl)-2-[(4-cyclopropyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanol —— C14H16ClN3OS
    (1R)-1-(3-chlorophenyl)-2-[(4-cyclopropyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanol
    —— 4-(2-fluorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]-3-nitrobenzenesulfonamide —— C16H17FN2O5S2
    4-(2-fluorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]-3-nitrobenzenesulfonamide
    —— 4-(2-Fluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidine —— C14H11FN2S2
    4-(2-Fluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidine
    —— 2-[[4-(2-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonylamino]ethyl-dimethylazanium —— C16H19FN3O4S2+
    2-[[4-(2-Fluorophenyl)sulfanyl-3-nitrophenyl]sulfonylamino]ethyl-dimethylazanium
    —— N-[2-(dimethylamino)ethyl]-4-(2-fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide —— C16H18FN3O4S2
    N-[2-(dimethylamino)ethyl]-4-(2-fluorophenyl)sulfanyl-3-nitrobenzenesulfonamide
    —— 4-(2-fluorophenyl)sulfanyl-3-nitro-N-propan-2-ylbenzenesulfonamide —— C15H15FN2O4S2
    4-(2-fluorophenyl)sulfanyl-3-nitro-N-propan-2-ylbenzenesulfonamide
    —— 4-Chloro-2-phenyl-5-[3-(trifluoromethyl)phenyl]sulfanylpyridazin-3-one —— C17H10ClF3N2OS
    4-Chloro-2-phenyl-5-[3-(trifluoromethyl)phenyl]sulfanylpyridazin-3-one
    —— 4-(2-fluorophenyl)sulfanyl-N-methyl-3-nitrobenzenesulfonamide —— C13H11FN2O4S2
    4-(2-fluorophenyl)sulfanyl-N-methyl-3-nitrobenzenesulfonamide
    —— 1-(2-Fluorophenyl)sulfanyl-2,4-dinitrobenzene —— C12H7FN2O4S
    1-(2-Fluorophenyl)sulfanyl-2,4-dinitrobenzene
    —— 4-[[12-(2-Fluorophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine —— C20H20FN3OS2
    4-[[12-(2-Fluorophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholine
    —— 4-(2-Fluorophenyl)sulfanylthieno[2,3-d]pyrimidine —— C12H7FN2S2
    4-(2-Fluorophenyl)sulfanylthieno[2,3-d]pyrimidine
    —— 2-[(2-Fluorophenyl)sulfanyl]-5-nitrobenzonitrile —— C13H7FN2O2S
    2-[(2-Fluorophenyl)sulfanyl]-5-nitrobenzonitrile
    —— 4-[[12-(2-Fluorophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium —— C20H21FN3OS2+
    4-[[12-(2-Fluorophenyl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraen-10-yl]methyl]morpholin-4-ium
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2S)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(3S)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone —— C18H24N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(2R)-2-(morpholin-4-ylmethyl)pyrrolidin-1-yl]methanone
    —— 1-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-[(2S)-2-phenylsulfanylpropyl]urea —— C16H21N5OS
    1-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-[(2S)-2-phenylsulfanylpropyl]urea
    —— 1-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-[(2R)-2-phenylsulfanylpropyl]urea —— C16H21N5OS
    1-(6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-3-ylmethyl)-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— N-ethyl-2-[4-(methylsulfamoyl)phenyl]sulfanyl-N-[[(3R)-oxolan-3-yl]methyl]benzamide —— C21H26N2O4S2
    N-ethyl-2-[4-(methylsulfamoyl)phenyl]sulfanyl-N-[[(3R)-oxolan-3-yl]methyl]benzamide
    —— (2R)-2-(1H-imidazol-2-ylsulfanyl)-N-(2,2,2-trifluoroethyl)propanamide —— C8H10F3N3OS
    (2R)-2-(1H-imidazol-2-ylsulfanyl)-N-(2,2,2-trifluoroethyl)propanamide
    —— 3-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine —— C14H23N3O2S
    3-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine
    —— 3-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine —— C14H23N3O2S
    3-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine
    —— N-ethyl-2-[4-(methylsulfamoyl)phenyl]sulfanyl-N-[[(3S)-oxolan-3-yl]methyl]benzamide —— C21H26N2O4S2
    N-ethyl-2-[4-(methylsulfamoyl)phenyl]sulfanyl-N-[[(3S)-oxolan-3-yl]methyl]benzamide
    —— (2R)-2-(1H-imidazol-2-ylsulfanyl)-1-pyrrolidin-1-ylpropan-1-one —— C10H15N3OS
    (2R)-2-(1H-imidazol-2-ylsulfanyl)-1-pyrrolidin-1-ylpropan-1-one
    —— (2S)-2-(1H-imidazol-2-ylsulfanyl)-N-(2,2,2-trifluoroethyl)propanamide —— C8H10F3N3OS
    (2S)-2-(1H-imidazol-2-ylsulfanyl)-N-(2,2,2-trifluoroethyl)propanamide
    —— (2S)-2-(1H-imidazol-2-ylsulfanyl)-1-pyrrolidin-1-ylpropan-1-one —— C10H15N3OS
    (2S)-2-(1H-imidazol-2-ylsulfanyl)-1-pyrrolidin-1-ylpropan-1-one
    —— 3-ethyl-5-[(1S)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C9H12N4OS
    3-ethyl-5-[(1S)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— 3-ethyl-5-[(1R)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C9H12N4OS
    3-ethyl-5-[(1R)-1-(1H-imidazol-2-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— N-(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)-3-phenyl-2,1-benzoxazole-5-carboxamide —— C18H14N4O2S2
    N-(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)-3-phenyl-2,1-benzoxazole-5-carboxamide
    —— 3-methyl-5-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine —— C12H16N4S
    3-methyl-5-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— 3-methyl-5-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine —— C12H16N4S
    3-methyl-5-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— 4-Amino-6-methyl-3-(3-methylsulfanylpropylsulfanyl)-1,2,4-triazin-5-one —— C8H14N4OS2
    4-Amino-6-methyl-3-(3-methylsulfanylpropylsulfanyl)-1,2,4-triazin-5-one
    —— (2R)-N-[(3-fluorophenyl)methyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide —— C16H21FN4O2S
    (2R)-N-[(3-fluorophenyl)methyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide
    —— 5-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-1H-1,2,4-triazole —— C11H13N3S
    5-[(1R)-1-(3-methylphenyl)ethyl]sulfanyl-1H-1,2,4-triazole
    —— 5-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-1H-1,2,4-triazole —— C11H13N3S
    5-[(1S)-1-(3-methylphenyl)ethyl]sulfanyl-1H-1,2,4-triazole
    —— (2S)-N-[(3-fluorophenyl)methyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide —— C16H21FN4O2S
    (2S)-N-[(3-fluorophenyl)methyl]-2-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-methylpropanamide
    —— (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H21FN4OS
    (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H21FN4OS
    (2R)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone —— C16H20N4OS2
    2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone
    —— 2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone —— C16H20N4OS2
    2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C17H19NO3S2
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C16H14ClF2NOS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— (2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanenitrile —— C12H13NO2S
    (2R)-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)propanenitrile
    —— N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(2-fluorophenyl)sulfanylacetamide —— C16H22FNO3S2
    N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(2-fluorophenyl)sulfanylacetamide