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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-O-acetyl-5-O-(tert-butyldiphenylsilyl)-2,3-dideoxy-2-phenylthio-D-erythro-pentofuranose 132436-48-7 C29H34O4SSi
    1-O-acetyl-5-O-(tert-butyldiphenylsilyl)-2,3-dideoxy-2-phenylthio-D-erythro-pentofuranose
    —— 2,2,4,5-tetramethyl-5,6-dihydro-2H-[1,3]thiazine 102308-79-2 C8H15NS
    2,2,4,5-tetramethyl-5,6-dihydro-2H-[1,3]thiazine
    —— (3R,5S)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-3-phenylsulfanyloxolan-2-ol 142495-48-5 C27H32O3SSi
    (3R,5S)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-3-phenylsulfanyloxolan-2-ol
    —— Ethyl<5-chlor-2(phenylthio)phenyl>acetat 67643-10-1 C16H15ClO2S
    Ethyl<5-chlor-2(phenylthio)phenyl>acetat
    —— tert-butyl (2-(pyridin-2-ylthio)ethyl)carbamate 906087-91-0 C12H18N2O2S
    tert-butyl (2-(pyridin-2-ylthio)ethyl)carbamate
    —— (3aR,4S,7Z,8aS)-3a,4,6,8a-tetrahydro-8-((1E)-2-((Z,3aR,4S,8aS)-3a,4,6,8a-tetrahydro-2,2-dimethyl-4-((phenylthio)methyl)-[1,3]dioxolo[4,5-c]oxepin-8-yl)vinyl)-2,2-dimethyl-4-((phenylthio)methyl)-[1,3]dioxolo[4,5-c]oxepine 1300579-68-3 C34H40O6S2
    (3aR,4S,7Z,8aS)-3a,4,6,8a-tetrahydro-8-((1E)-2-((Z,3aR,4S,8aS)-3a,4,6,8a-tetrahydro-2,2-dimethyl-4-((phenylthio)methyl)-[1,3]dioxolo[4,5-c]oxepin-8-yl)vinyl)-2,2-dimethyl-4-((phenylthio)methyl)-[1,3]dioxolo[4,5-c]oxepine
    —— ethyltrioxorhenium(VII) 131457-01-7 C2H5O3Re
    ethyltrioxorhenium(VII)
    —— allyl-propyl-thiocarbamic acid S-(methylsulfanyl-methyl ester) 92187-42-3 C9H17NOS2
    allyl-propyl-thiocarbamic acid S-(methylsulfanyl-methyl ester)
    —— 2-(1-pentynyl)thioanisole 90584-91-1 C12H14S
    2-(1-pentynyl)thioanisole
    —— Dicyan-hexasulfan 60583-09-7 C2N2S6
    Dicyan-hexasulfan
    —— 2-chlorotetrafluoroethylsulfenyl chloride 354-73-4 C2Cl2F4S
    2-chlorotetrafluoroethylsulfenyl chloride
    —— thiomethoxycarbonyl isocyanate 31912-69-3 C3H3NO2S
    thiomethoxycarbonyl isocyanate
    —— (Z,3aR,4S,8aS)-3a,4,6,8a-tetrahydro-2,2-dimethyl-4-((phenylthio)methyl)-8-vinyl-[1,3]dioxolo[4,5-c]oxepine 1300579-62-7 C18H22O3S
    (Z,3aR,4S,8aS)-3a,4,6,8a-tetrahydro-2,2-dimethyl-4-((phenylthio)methyl)-8-vinyl-[1,3]dioxolo[4,5-c]oxepine
    —— (Z)-1-nitro-1-(phenylthio)propene 67808-91-7 C9H9NO2S
    (Z)-1-nitro-1-(phenylthio)propene
    —— 3-((3,6-bis(2-(methylthio)ethyl)pyrazin-2-yl)thio)propan-1-ol 1283167-21-4 C13H22N2OS3
    3-((3,6-bis(2-(methylthio)ethyl)pyrazin-2-yl)thio)propan-1-ol
    —— (R)-1-(5-cyclopentyl-4-ethyl-1-methyl-4,5-dihydro-[1,2,4]triazolo[4,3-f]pteridin-7-yl)pyridin-4(1H)-imine 1371620-65-3 C20H24N8
    (R)-1-(5-cyclopentyl-4-ethyl-1-methyl-4,5-dihydro-[1,2,4]triazolo[4,3-f]pteridin-7-yl)pyridin-4(1H)-imine
    —— dipropyl-thiocarbamic acid S-(3t-chloro-allyl ester) 118871-37-7 C10H18ClNOS
    dipropyl-thiocarbamic acid S-(3t-chloro-allyl ester)
    —— Ethyl-(2-methyl-3-oxo-butyl)-phosphinothioic acid S-isopropyl ester 33454-70-5 C10H21O2PS
    Ethyl-(2-methyl-3-oxo-butyl)-phosphinothioic acid S-isopropyl ester
    —— Os(hydride)6(triisopropylphosphine)2 131296-74-7 C18H48OsP2
    Os(hydride)6(triisopropylphosphine)2
    —— 144899-23-0 C22H25NO2S2
    —— p-(methylthio)phenyl isopropyl selenide 87136-99-0 C10H14SSe
    p-(methylthio)phenyl isopropyl selenide
    —— N-Boc-N'-propionyl-S-methylisothiourea 1240515-33-6 C10H18N2O3S
    N-Boc-N'-propionyl-S-methylisothiourea
    —— Diaethylzinn-bis(aethansulfinat) 41309-91-5 C8H20O4S2Sn
    Diaethylzinn-bis(aethansulfinat)
    —— ethyl-N,N-bis(3-chloroallyl) thiolcarbamate 104287-03-8 C9H13Cl2NOS
    ethyl-N,N-bis(3-chloroallyl) thiolcarbamate
    —— hexakis(trifluoromethyl)-1,3,5-trithiane 1,1,3,3,5,5-hexaoxide 51947-99-0 C9F18O6S3
    hexakis(trifluoromethyl)-1,3,5-trithiane 1,1,3,3,5,5-hexaoxide
    —— 2-chlorophenyl dimethylcarbamodithioate 16906-71-1 C9H10ClNS2
    2-chlorophenyl dimethylcarbamodithioate
    —— 1416057-92-5 C18H11BrN2O3S2
    —— 4-((2S,3R,4S,5S)-3,4,5-Trihydroxy-tetrahydro-thiopyran-2-ylsulfanyl)-thiobenzamide 201546-84-1 C12H15NO3S3
    4-((2S,3R,4S,5S)-3,4,5-Trihydroxy-tetrahydro-thiopyran-2-ylsulfanyl)-thiobenzamide
    —— Ethylthiophosphinsaeure-isobutylester-chlorid 16543-47-8 C6H14ClPS
    Ethylthiophosphinsaeure-isobutylester-chlorid
    —— (3S,4S,5S)-3,4-isopropylidenedioxyhex-1-yn-5-ol-6-thiobenzene 1300579-53-6 C15H18O3S
    (3S,4S,5S)-3,4-isopropylidenedioxyhex-1-yn-5-ol-6-thiobenzene
    —— 2-(naphthalen-2-ylthio)pyridine 92498-42-5 C15H11NS
    2-(naphthalen-2-ylthio)pyridine
    —— iso-Butylammonium-N-iso-propyl-monothiocarbamat 77432-32-7 C4H9NOS*C4H11N
    iso-Butylammonium-N-iso-propyl-monothiocarbamat
    —— (3R,5S)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-3-phenylsulfanyloxolan-2-one 129778-50-3 C27H30O3SSi
    (3R,5S)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-3-phenylsulfanyloxolan-2-one
    —— ethyl-methallyl-thiocarbamic acid S-(methylsulfanyl-methyl ester) 92187-44-5 C9H17NOS2
    ethyl-methallyl-thiocarbamic acid S-(methylsulfanyl-methyl ester)
    —— Thiocarbonic acid O-(1,1-dimethyl-octadecyl) ester S-methyl ester 82884-56-8 C22H44O2S
    Thiocarbonic acid O-(1,1-dimethyl-octadecyl) ester S-methyl ester
    —— 1-((4R,5S)-4-Methyl-5-phenyl-2-thioxo-oxazolidin-3-yl)-3-phenylsulfanyl-butan-1-one 104499-20-9 C20H21NO2S2
    1-((4R,5S)-4-Methyl-5-phenyl-2-thioxo-oxazolidin-3-yl)-3-phenylsulfanyl-butan-1-one
    —— ethyl-butyl-thiocarbamic acid <i>S</i>-allyl ester 36784-35-7 C10H19NOS
    ethyl-butyl-thiocarbamic acid <i>S</i>-allyl ester
    —— Cl4Pd(Cys-Cys) 119272-59-2 C6H12Cl4N2O4PdS2
    Cl4Pd(Cys-Cys)
    —— β-<i>p</i>-tolylsulfanyl-isopropylamine; hydrochloride 104864-03-1 C10H15NS*ClH
    β-<i>p</i>-tolylsulfanyl-isopropylamine; hydrochloride
    —— [Pd(CH2SiPh2(CH2NC5H10)-κ2-C,N)(diethyldithiocarbamate)] 723280-99-7 C24H34N2PdS2Si
    [Pd(CH2SiPh2(CH2NC5H10)-κ2-C,N)(diethyldithiocarbamate)]
    —— O-ethyl S-(1-(methoxy(methyl)amino)-1-oxopropan-2-yl) carbonodithioate 1239316-66-5 C8H15NO3S2
    O-ethyl S-(1-(methoxy(methyl)amino)-1-oxopropan-2-yl) carbonodithioate
    —— Triethylammonium-N-cyclohexyl-thiolcarbamat 78614-05-8 C6H15N*C7H13NOS
    Triethylammonium-N-cyclohexyl-thiolcarbamat
    —— Thiophosphoric acid O-{3-[1-((3aR,4R,6R,6aR)-6-hydroxymethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl]-propyl} ester S-phenyl ester 198822-78-5 C21H27N2O9PS
    Thiophosphoric acid O-{3-[1-((3aR,4R,6R,6aR)-6-hydroxymethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl]-propyl} ester S-phenyl ester
    —— ethyl-butyl-thiocarbamic acid S-prop-2-ynyl ester 102653-01-0 C10H17NOS
    ethyl-butyl-thiocarbamic acid S-prop-2-ynyl ester
    —— 327989-09-3 C8H15NOS4
    —— ethyl-butyl-thiocarbamic acid S-cyanomethyl ester 114723-06-7 C9H16N2OS
    ethyl-butyl-thiocarbamic acid S-cyanomethyl ester
    —— ethyl-allyl-thiocarbamic acid S-allyl ester 99062-68-7 C9H15NOS
    ethyl-allyl-thiocarbamic acid S-allyl ester
    —— bromo(bis(N,N-dimethylthiocarbamoyl) sulfide)copper(I) 186099-23-0 C6H12BrCuN2S3
    bromo(bis(N,N-dimethylthiocarbamoyl) sulfide)copper(I)
    —— (1-Acetoxy-isobutyl)-phenyl-sulfid 55999-41-2 C12H16O2S
    (1-Acetoxy-isobutyl)-phenyl-sulfid
    —— 1,5-bis-methanesulfonyl-3,3-dimethyl-pentane-2,4-dione 19916-40-6 C9H16O6S2
    1,5-bis-methanesulfonyl-3,3-dimethyl-pentane-2,4-dione