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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-phenylthio-1-pentanol 91967-97-4 C11H16OS
    4-phenylthio-1-pentanol
    —— propan-2-yl triphenylstannylsulfanylformate 310465-00-0 C22H22O2SSn
    propan-2-yl triphenylstannylsulfanylformate
    —— bis-(8-ethoxycarbonyl-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d]-bis[1,3]dithiol-4-yl)mono(8-carboxyl-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d]-bis[1,3]dithiol-4-yl)methyl radical 1429310-47-3 C44H47O6S12
    bis-(8-ethoxycarbonyl-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d]-bis[1,3]dithiol-4-yl)mono(8-carboxyl-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d]-bis[1,3]dithiol-4-yl)methyl radical
    —— N,N-Diethyl-S-pentafluorophenyl-thiohydroxylamine 35366-53-1 C10H10F5NS
    N,N-Diethyl-S-pentafluorophenyl-thiohydroxylamine
    —— bis-(4,6-bis-phenylsulfanyl-[1,3,5]triazin-2-yl)-amine 33190-93-1 C30H21N7S4
    bis-(4,6-bis-phenylsulfanyl-[1,3,5]triazin-2-yl)-amine
    —— 2-(O,O-Diethyl-phosphorothiolyl)-4,6-bis(butyl-xantyl)-s-triazin 10158-85-7 C17H28N3O5PS5
    2-(O,O-Diethyl-phosphorothiolyl)-4,6-bis(butyl-xantyl)-s-triazin
    —— nitro-[1,3]thiazinan-2-ylidene-acetic acid 2-phenylsulfanyl-ethyl ester 60517-61-5 C14H16N2O4S2
    nitro-[1,3]thiazinan-2-ylidene-acetic acid 2-phenylsulfanyl-ethyl ester
    —— thiophosphoric acid <i>S</i>-(5-allylsulfanyl-2-oxo-[1,3,4]thiadiazol-3-ylmethyl) ester <i>O</i>,<i>O</i>'-dimethyl ester 92526-83-5 C8H13N2O4PS3
    thiophosphoric acid <i>S</i>-(5-allylsulfanyl-2-oxo-[1,3,4]thiadiazol-3-ylmethyl) ester <i>O</i>,<i>O</i>'-dimethyl ester
    —— 2,3,6,7-Tetrachloro-9,10-dithia-1,4,5,8-tetraaza-anthracene 51627-37-3 C8Cl4N4S2
    2,3,6,7-Tetrachloro-9,10-dithia-1,4,5,8-tetraaza-anthracene
    —— 56593-00-1 C14H24S
    —— methyl pyruvate diphenyl dithioacetal 105961-89-5 C16H16O2S2
    methyl pyruvate diphenyl dithioacetal
    —— 75642-17-0 C4H12N*C9H18N3S6Zn
    —— 3-Hydroxy-4-(2-methyl-[1,3]dithian-2-yl)-butyric acid methyl ester 459156-73-1 C10H18O3S2
    3-Hydroxy-4-(2-methyl-[1,3]dithian-2-yl)-butyric acid methyl ester
    —— 62672-87-1 C11H22S2
    —— 129110-62-9 C12H17FS
    —— (2R,3R,4S,5R)-5-((E)-2-Methyl-3-phenylsulfanyl-allyl)-2-[(2S,3S)-3-((1R,2S)-1-methyl-2-triethylsilanyloxy-propyl)-oxiranylmethyl]-3,4-bis-triethylsilanyloxy-tetrahydro-pyran 117467-94-4 C40H74O5SSi3
    (2R,3R,4S,5R)-5-((E)-2-Methyl-3-phenylsulfanyl-allyl)-2-[(2S,3S)-3-((1R,2S)-1-methyl-2-triethylsilanyloxy-propyl)-oxiranylmethyl]-3,4-bis-triethylsilanyloxy-tetrahydro-pyran
    —— 2-[(Z)-5-(3-[1,3]Dioxolan-2-yl-1-phenylsulfanyl-propyl)-4-methoxy-hexadec-4-enyloxy]-tetrahydro-pyran 95091-25-1 C34H56O5S
    2-[(Z)-5-(3-[1,3]Dioxolan-2-yl-1-phenylsulfanyl-propyl)-4-methoxy-hexadec-4-enyloxy]-tetrahydro-pyran
    —— [2-(4-Chloro-2-methoxy-phenylsulfanyl)-4-methoxy-phenyl]-acetonitrile 79332-69-7 C16H14ClNO2S
    [2-(4-Chloro-2-methoxy-phenylsulfanyl)-4-methoxy-phenyl]-acetonitrile
    —— <(Phenylthio)methylene>adamantane 33521-89-0 C17H20S
    <(Phenylthio)methylene>adamantane
    —— 1309372-04-0 C34H54N6O10SSi
    —— 4,4-(trimethylenedithio)-(E,E)-6,8-decadienal 139230-36-7 C13H20OS2
    4,4-(trimethylenedithio)-(E,E)-6,8-decadienal
    —— pentafluorophenyl(2,3,5,6-tetrafluoro-4-pyridyl)sulfane 56354-54-2 C11F9NS
    pentafluorophenyl(2,3,5,6-tetrafluoro-4-pyridyl)sulfane
    —— 4-(4-(2-chloroacetamido)phenylthio)-N-methylpicolinamide 1291103-29-1 C15H14ClN3O2S
    4-(4-(2-chloroacetamido)phenylthio)-N-methylpicolinamide
    —— N-(3-(6-amino-8-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)propyl)pivalamide 1402546-12-6 C20H23IN6O3S
    N-(3-(6-amino-8-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)propyl)pivalamide
    —— 1255910-36-1 C21H14F7NS2
    —— O-(6-methylenecyclodecyl)-S-methyl dithiocarbonate 133367-13-2 C13H22OS2
    O-(6-methylenecyclodecyl)-S-methyl dithiocarbonate
    —— 1-(cyclohex-1-enyl)-3-methanesulfonyl-3-azahex-5-yn-1-one 1005481-66-2 C12H17NO3S
    1-(cyclohex-1-enyl)-3-methanesulfonyl-3-azahex-5-yn-1-one
    —— 2-(NN'-dimethylhydrazino)ethanethiol 66175-27-7 C4H12N2S
    2-(NN'-dimethylhydrazino)ethanethiol
    —— 8-Methyl-2,3-dihydro-6H-[1,4]dithiino[2,3-d]pyridazin-5-one 33589-76-3 C7H8N2OS2
    8-Methyl-2,3-dihydro-6H-[1,4]dithiino[2,3-d]pyridazin-5-one
    —— (+/-)-2-Phenylsulfanyl-1-(2-pyridinyl)ethanol 375367-57-0 C13H13NOS
    (+/-)-2-Phenylsulfanyl-1-(2-pyridinyl)ethanol
    —— 2-((3-(4-(2,6-di-tert-butylpyrimidin-4-yl)-1,4-diazepan-1-yl)-2-methylpropyl)thio)pyrimidin-4-ol 193607-69-1 C25H40N6OS
    2-((3-(4-(2,6-di-tert-butylpyrimidin-4-yl)-1,4-diazepan-1-yl)-2-methylpropyl)thio)pyrimidin-4-ol
    —— N-(1,3-benzothiazol-2-yl)-2-(4-chlorophenyl)sulfanylpyridine-3-carboxamide 97936-26-0 C19H12ClN3OS2
    N-(1,3-benzothiazol-2-yl)-2-(4-chlorophenyl)sulfanylpyridine-3-carboxamide
    —— Allyl-(1-dimethylcarbamoyl-1-methyl-ethyl)-dithiocarbamic acid allyl ester 61796-14-3 C13H22N2OS2
    Allyl-(1-dimethylcarbamoyl-1-methyl-ethyl)-dithiocarbamic acid allyl ester
    —— methyl 2-ethenyl-2,4-dimethyl-4-pentenedithioate 107094-84-8 C10H16S2
    methyl 2-ethenyl-2,4-dimethyl-4-pentenedithioate
    —— 6-{6-[1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrazol-4-yl]-[1,2,4]triazolo[4,3-b]pyridazin-3-ylsulfanyl}-quinoline 1022151-64-9 C23H25N7OSSi
    6-{6-[1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrazol-4-yl]-[1,2,4]triazolo[4,3-b]pyridazin-3-ylsulfanyl}-quinoline
    —— 2-(4-bromophenyl)-2-(phenylthio)penta-3,4-dien-1-ol 941270-74-2 C17H15BrOS
    2-(4-bromophenyl)-2-(phenylthio)penta-3,4-dien-1-ol
    —— 2,2-dimethyl-2,3-dihydro-benzothiazole; silver (I)-compound 108724-45-4 Ag*C9H10NS
    2,2-dimethyl-2,3-dihydro-benzothiazole; silver (I)-compound
    —— 3-(3-chlorophenylsulfanyl)-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid amide 853685-39-9 C14H10ClN3OS
    3-(3-chlorophenylsulfanyl)-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid amide
    —— tris-dimethylthiocarbamoylsulfanyl-[1,3,5]triazine 33096-56-9 C12H18N6S6
    tris-dimethylthiocarbamoylsulfanyl-[1,3,5]triazine
    —— 2,4-Bis-methylmercapto-8-phenylmercapto-chinazolin 37575-89-6 C16H14N2S3
    2,4-Bis-methylmercapto-8-phenylmercapto-chinazolin
    —— 4-[(E)-Phenylimino]-3-p-tolylsulfanyl-cyclohexa-2,5-dienone 104053-97-6 C19H15NOS
    4-[(E)-Phenylimino]-3-p-tolylsulfanyl-cyclohexa-2,5-dienone
    —— 3-Methylmercapto-5-ethoxalylmethyl-1,2,4-thiadiazol 90007-63-9 C8H10N2O3S2
    3-Methylmercapto-5-ethoxalylmethyl-1,2,4-thiadiazol
    —— 2-benzyl-4-benzylsulfanyl-5-hydroxy-2<i>H</i>-pyridazin-3-one 25818-65-9 C18H16N2O2S
    2-benzyl-4-benzylsulfanyl-5-hydroxy-2<i>H</i>-pyridazin-3-one
    —— 3-((4-chlorophenyl)thio)-2-(thiophen-2-yl)imidazo[1,2-a]pyridine 1609583-51-8 C17H11ClN2S2
    3-((4-chlorophenyl)thio)-2-(thiophen-2-yl)imidazo[1,2-a]pyridine
    —— 2-[3-(phenylthio)-1-propynyl]-1-cyclohexanol 130158-50-8 C15H18OS
    2-[3-(phenylthio)-1-propynyl]-1-cyclohexanol
    —— 143300-91-8 C33H15F15N3RhS3
    —— 4-nitrotetrafluorophenyl-pentafluorophenylsulfane 18504-15-9 C12F9NO2S
    4-nitrotetrafluorophenyl-pentafluorophenylsulfane
    —— 131660-04-3 C11H8CdN2S
    —— (β-Hydroxy-ethyl)-(3-ethylmercapto-phenyl)-sulfid 22017-39-6 C10H14OS2
    (β-Hydroxy-ethyl)-(3-ethylmercapto-phenyl)-sulfid
    —— Di-(p-bromphenyl)trithiocarbonat 96464-40-3 C13H8Br2S3
    Di-(p-bromphenyl)trithiocarbonat