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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R,3S,4R)-1-(2-Ethyl-[1,3]dithian-2-yl)-3,5-dimethyl-hexane-2,4-diol 174420-22-5 C14H28O2S2
    (2R,3S,4R)-1-(2-Ethyl-[1,3]dithian-2-yl)-3,5-dimethyl-hexane-2,4-diol
    —— methyl N-[N'-[2-(butanoylamino)-4-(4-fluorophenyl)sulfanylphenyl]carbamimidoyl]carbamate 65934-81-8 C19H21FN4O3S
    methyl N-[N'-[2-(butanoylamino)-4-(4-fluorophenyl)sulfanylphenyl]carbamimidoyl]carbamate
    —— (4-Chloro-phenylsulfanyl)-(ethoxy-ethyl-phosphinothioylsulfanyl)-acetic acid ethyl ester 60322-01-2 C14H20ClO3PS3
    (4-Chloro-phenylsulfanyl)-(ethoxy-ethyl-phosphinothioylsulfanyl)-acetic acid ethyl ester
    —— 5-methyl-1-methylsulfinylhex-5-en-2-one 108264-36-4 C8H14O2S
    5-methyl-1-methylsulfinylhex-5-en-2-one
    —— [n-Bu(C3H3N2)CH2CH2SPh]Cl 1155239-04-5 C15H21N2S*Cl
    [n-Bu(C3H3N2)CH2CH2SPh]Cl
    —— Methyldi(ethylthio)bismutan 60458-08-4 C5H13BiS2
    Methyldi(ethylthio)bismutan
    —— methyl N-[N'-[2-[(2-ethoxyacetyl)amino]-4-phenylsulfanylphenyl]-N-methoxycarbonylcarbamimidoyl]carbamate 58306-31-3 C21H24N4O6S
    methyl N-[N'-[2-[(2-ethoxyacetyl)amino]-4-phenylsulfanylphenyl]-N-methoxycarbonylcarbamimidoyl]carbamate
    —— Allyl-<2,5-diaethyl-phenyl>-sulfid 21546-57-6 C13H18S
    Allyl-<2,5-diaethyl-phenyl>-sulfid
    —— 5-(5-amino-6-cyclopentylamino-pyrimidin-4-ylsulfanyl)-pentanoic acid 27131-79-9 C14H22N4O2S
    5-(5-amino-6-cyclopentylamino-pyrimidin-4-ylsulfanyl)-pentanoic acid
    —— 2-heptyl-4-p-tolylmercapto-quinoline 116534-37-3 C23H27NS
    2-heptyl-4-p-tolylmercapto-quinoline
    —— 2-(4-Chlorophenyl)-5-(methylsulfinylmethylsulfanyl)-1,3,4-thiadiazole 154220-76-5 C10H9ClN2OS3
    2-(4-Chlorophenyl)-5-(methylsulfinylmethylsulfanyl)-1,3,4-thiadiazole
    —— 1-(2,2-Bis-phenylsulfanyl-cyclopropyl)-pentan-1-ol 86816-56-0 C20H24OS2
    1-(2,2-Bis-phenylsulfanyl-cyclopropyl)-pentan-1-ol
    —— Thiophosphoric acid O-[2-(3,5-dichloro-6-fluoro-pyridin-2-ylsulfanyl)-phenyl] ester O',O''-diethyl ester 64557-16-0 C15H15Cl2FNO3PS2
    Thiophosphoric acid O-[2-(3,5-dichloro-6-fluoro-pyridin-2-ylsulfanyl)-phenyl] ester O',O''-diethyl ester
    —— 3-dodecyl-8-phenylsulfanyl-3,4-dihydro-2<i>H</i>-benzo[4,5]imidazo[1,2-<i>a</i>][1,3,5]triazine-1-carboxylic acid methyl ester 56546-13-5 C29H40N4O2S
    3-dodecyl-8-phenylsulfanyl-3,4-dihydro-2<i>H</i>-benzo[4,5]imidazo[1,2-<i>a</i>][1,3,5]triazine-1-carboxylic acid methyl ester
    —— (2-Butyl-1-chloro-cyclopropylsulfanyl)-benzene 34678-55-2 C13H17ClS
    (2-Butyl-1-chloro-cyclopropylsulfanyl)-benzene
    —— Cyclohexyl-S-(6-hydroxy-4-methyl-2-pyrimidyl)-thioglycolat 21419-02-3 C13H18N2O3S
    Cyclohexyl-S-(6-hydroxy-4-methyl-2-pyrimidyl)-thioglycolat
    —— 4-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-5-ethylsulfanyl-[1,3]diselenole-2-selone 490037-35-9 C14H26OSSe3Si
    4-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-5-ethylsulfanyl-[1,3]diselenole-2-selone
    —— 6-fluoro-3-(p-tolylthio)-1H-indole 1622221-69-5 C15H12FNS
    6-fluoro-3-(p-tolylthio)-1H-indole
    —— 2-(2-amino-1,3,4-thiadiazol-5-yl)thio-7-methyl-5-oxo-5H-1,3,4-thiazolo<3,2-a>pyrimidine 157407-00-6 C8H6N6OS3
    2-(2-amino-1,3,4-thiadiazol-5-yl)thio-7-methyl-5-oxo-5H-1,3,4-thiazolo<3,2-a>pyrimidine
    —— bis-diisobutylthiocarbamoylmercapto-[1,3,4]thiadiazole 113011-82-8 C20H36N4S5
    bis-diisobutylthiocarbamoylmercapto-[1,3,4]thiadiazole
    —— [3-(4-chlorophenylsulfanyl)-2-methyl-7-trifluoromethylindolizin-1-yl]acetic acid ethyl ester 917761-00-3 C20H17ClF3NO2S
    [3-(4-chlorophenylsulfanyl)-2-methyl-7-trifluoromethylindolizin-1-yl]acetic acid ethyl ester
    —— 1,3-Difluoro-2,4,5,6-tetrakis-methylsulfanyl-benzene 36639-02-8 C10H12F2S4
    1,3-Difluoro-2,4,5,6-tetrakis-methylsulfanyl-benzene
    —— [4-(4-Chloro-phenylsulfanyl)-phenylsulfanyl]-acetic acid 2-[10-(2-{2-[4-(4-chloro-phenylsulfanyl)-phenylsulfanyl]-acetoxy}-1-methyl-ethylsulfanyl)-decylsulfanyl]-propyl ester 65250-88-6 C44H52Cl2O4S6
    [4-(4-Chloro-phenylsulfanyl)-phenylsulfanyl]-acetic acid 2-[10-(2-{2-[4-(4-chloro-phenylsulfanyl)-phenylsulfanyl]-acetoxy}-1-methyl-ethylsulfanyl)-decylsulfanyl]-propyl ester
    —— [5-fluoro-2-(6-methyl-1H-indol-3-ylsulfanyl)-benzyl]-methyl-amine 857499-00-4 C17H17FN2S
    [5-fluoro-2-(6-methyl-1H-indol-3-ylsulfanyl)-benzyl]-methyl-amine
    —— [(4R,6R)-6-(Acetoxy-p-tolylsulfanyl-methyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-acetic acid methyl ester 218168-27-5 C19H26O6S
    [(4R,6R)-6-(Acetoxy-p-tolylsulfanyl-methyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-acetic acid methyl ester
    —— (E)-(2S,3R,4S)-6-Phenylsulfanyl-hex-5-ene-1,2,3,4-tetraol 26706-21-8 C12H16O4S
    (E)-(2S,3R,4S)-6-Phenylsulfanyl-hex-5-ene-1,2,3,4-tetraol
    —— 25558-36-5 C19H20N2S3
    —— [Co(cyanodithioformato)2] 412294-82-7 C4CoN2S4
    [Co(cyanodithioformato)2]
    —— (4<i>H</i>-[1,2,4]triazol-3-ylsulfanyl)-acetic acid benzylidenehydrazide 24127-95-5 C11H11N5OS
    (4<i>H</i>-[1,2,4]triazol-3-ylsulfanyl)-acetic acid benzylidenehydrazide
    —— dimethyl 5,5'-[3,6-pyridazinediylbis(thio)]bis[2,2-dimethylpentanoate] 344574-32-9 C20H32N2O4S2
    dimethyl 5,5'-[3,6-pyridazinediylbis(thio)]bis[2,2-dimethylpentanoate]
    —— 1-(1,4-Dithia-spiro[4.5]dec-6-yl)-ethanone 117087-77-1 C10H16OS2
    1-(1,4-Dithia-spiro[4.5]dec-6-yl)-ethanone
    —— Malonic acid ethyl ester (1S,2R)-2-(3-phenylsulfanyl-prop-1-ynyl)-cyclohexyl ester 130158-55-3 C20H24O4S
    Malonic acid ethyl ester (1S,2R)-2-(3-phenylsulfanyl-prop-1-ynyl)-cyclohexyl ester
    —— N'-Methyl-N-isopropyl-N-(2-cyanethyl)-thioharnstoff 30381-02-3 C8H15N3S
    N'-Methyl-N-isopropyl-N-(2-cyanethyl)-thioharnstoff
    —— N-[4-(imidazo[1,2-a]pyrimidin-3-ylsulphanyl)phenyl]acetamide 1205121-73-8 C14H12N4OS
    N-[4-(imidazo[1,2-a]pyrimidin-3-ylsulphanyl)phenyl]acetamide
    —— 59274-09-8 C8H15Cl2PS2
    —— 3-(phenylthio) propyl (methyl) dichlorosilane 200283-60-9 C10H14Cl2SSi
    3-(phenylthio) propyl (methyl) dichlorosilane
    —— (2R,3S,4R)-5-(Phenylthio)-1,2-O-isopropylidenepentane-1,2,3,4-tetrol 81769-41-7 C14H20O4S
    (2R,3S,4R)-5-(Phenylthio)-1,2-O-isopropylidenepentane-1,2,3,4-tetrol
    —— 1,2-bis<bis(tert-butylthio)cyclopropenylio>cyclopentadienide 89821-02-3 C27H40S4
    1,2-bis<bis(tert-butylthio)cyclopropenylio>cyclopentadienide
    —— 5-(3-(methylsulfonyl)phenyl)-4-(pyridin-4-ylthio)thieno[2,3-d]pyrimidine 1370338-37-6 C18H13N3O2S3
    5-(3-(methylsulfonyl)phenyl)-4-(pyridin-4-ylthio)thieno[2,3-d]pyrimidine
    —— 1,4-Cyclohexendi(sulfonylisocyanat) 38189-92-3 C8H10N2O6S2
    1,4-Cyclohexendi(sulfonylisocyanat)
    —— 2-(2,6-Dihydroxy-4-methylphenyl)sulfanyl-5-methylbenzene-1,3-diol 5046-66-2 C14H14O4S
    2-(2,6-Dihydroxy-4-methylphenyl)sulfanyl-5-methylbenzene-1,3-diol
    —— 4-ethyl-2-ethylsulfanyl-3,5-dimethyl-1H-pyrrole 1128077-89-3 C10H17NS
    4-ethyl-2-ethylsulfanyl-3,5-dimethyl-1H-pyrrole
    —— 5-Ethylsulfanyl-6-methyl-pyrimidine-2,4-diamine 74890-51-0 C7H12N4S
    5-Ethylsulfanyl-6-methyl-pyrimidine-2,4-diamine
    —— 2-bromo-1-[5-(methylthio)thiophen-2-yl]ethanone 884488-29-3 C7H7BrOS2
    2-bromo-1-[5-(methylthio)thiophen-2-yl]ethanone
    —— (E)-3-tert-Butylsulfanyl-1-methoxy-non-1-ene 88909-35-7 C14H28OS
    (E)-3-tert-Butylsulfanyl-1-methoxy-non-1-ene
    —— S-(butoxycarbonyl) O-butyldithiocarbonate 103217-72-7 C10H18O3S2
    S-(butoxycarbonyl) O-butyldithiocarbonate
    —— 7(9)<i>H</i>,7'(9')<i>H</i>-6,6'-sulfanediyl-bis-purin-2-ylamine 90920-72-2 C10H8N10S
    7(9)<i>H</i>,7'(9')<i>H</i>-6,6'-sulfanediyl-bis-purin-2-ylamine
    —— 4-(4-(4-chlorobutanamido)phenylthio)-N-methylpicolinamide 1393482-53-5 C17H18ClN3O2S
    4-(4-(4-chlorobutanamido)phenylthio)-N-methylpicolinamide
    —— (4-Chloro-phenylsulfanyl)-(isopropoxy-methyl-phosphinothioylsulfanyl)-acetic acid ethyl ester 60178-15-6 C14H20ClO3PS3
    (4-Chloro-phenylsulfanyl)-(isopropoxy-methyl-phosphinothioylsulfanyl)-acetic acid ethyl ester
    —— (4R,5S,6R)-2,2-di-tert-butyl-4-((2-ethyl-1,3-dithian-2-yl)methyl)-6-isopropyl-5-methyl-1,3,2-dioxasilinane 174420-23-6 C22H44O2S2Si
    (4R,5S,6R)-2,2-di-tert-butyl-4-((2-ethyl-1,3-dithian-2-yl)methyl)-6-isopropyl-5-methyl-1,3,2-dioxasilinane