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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— trans-bis[3-(di-tert-butylphosphinothioyl)-1,1,1-trifluoro-2-(trifluoromethyl)-2-propanolato-κO,κS]tin(II) 908373-91-1 C24H40F12O2P2S2Sn
    trans-bis[3-(di-tert-butylphosphinothioyl)-1,1,1-trifluoro-2-(trifluoromethyl)-2-propanolato-κO,κS]tin(II)
    —— tert-Butyl-dimethyl-{2-[1-phenylsulfanyl-meth-(Z)-ylidene]-cyclohexyloxy}-silane 125536-59-6 C19H30OSSi
    tert-Butyl-dimethyl-{2-[1-phenylsulfanyl-meth-(Z)-ylidene]-cyclohexyloxy}-silane
    —— 1010704-19-4 C11H14O2S
    —— methyl 4,7,7-trimethyl-8-oxo-3-phenylthiobicyclo<3.3.0>oct-3-ene-1-carboxylate 106060-08-6 C19H22O3S
    methyl 4,7,7-trimethyl-8-oxo-3-phenylthiobicyclo<3.3.0>oct-3-ene-1-carboxylate
    —— 2,3-dibromo-1,1,4,4-tetrakis(4-fluorophenylthio)-1,3-butadiene 1257082-01-1 C28H16Br2F4S4
    2,3-dibromo-1,1,4,4-tetrakis(4-fluorophenylthio)-1,3-butadiene
    —— Ethylsulfanylmethylidyneoxidanium 75599-69-8 C3H5OS
    Ethylsulfanylmethylidyneoxidanium
    —— Cyclopenta-2,4-dien-1-yl(dimethyl)bismuthane 56521-07-4 C7H11Bi
    Cyclopenta-2,4-dien-1-yl(dimethyl)bismuthane
    —— (S)-(+)-2-fluoro-2-methyl-3-phenylthiopropionic acid 110790-22-2 C10H11FO2S
    (S)-(+)-2-fluoro-2-methyl-3-phenylthiopropionic acid
    —— 3-(1-acetyl-4,7-difluoro-6-(phenylthio)-2,3-dihydro-1H-pyrrolo[3,2-c]pyridin-3-yl)propanenitrile 1309372-24-4 C18H15F2N3OS
    3-(1-acetyl-4,7-difluoro-6-(phenylthio)-2,3-dihydro-1H-pyrrolo[3,2-c]pyridin-3-yl)propanenitrile
    —— 2-Amino-4-hydroxy-5-(2-amino-phenylmercapto)-pyrimidin 1141-84-0 C10H10N4OS
    2-Amino-4-hydroxy-5-(2-amino-phenylmercapto)-pyrimidin
    —— 1-(3-Bromopropyl)-2-(phenylsulfanyl)-1H-indole 169890-98-6 C17H16BrNS
    1-(3-Bromopropyl)-2-(phenylsulfanyl)-1H-indole
    —— O-(octadecyl)-S-methyl dithiocarbonate 62008-63-3 C20H40OS2
    O-(octadecyl)-S-methyl dithiocarbonate
    —— 2,3-dihydro-3-hydroxy-5H-thiazolo<3,2-a>pyrimidin-5-one 73351-67-4 C6H6N2O2S
    2,3-dihydro-3-hydroxy-5H-thiazolo<3,2-a>pyrimidin-5-one
    —— N-[2-(3-fluorophenyl)ethyl]-2-phenylsulfanylacetamide 832713-47-0 C16H16FNOS
    N-[2-(3-fluorophenyl)ethyl]-2-phenylsulfanylacetamide
    —— 6,7-Dimethyl-9H-10-thia-1,3,9-triaza-anthracene-2,4-diamine 4941-04-2 C12H13N5S
    6,7-Dimethyl-9H-10-thia-1,3,9-triaza-anthracene-2,4-diamine
    —— ethyl 3-[1,3-dimethyl-4-(ethylsulfanyl)-6,7-dihydro-1H-indole-2,5-diyl]acrylate 1092522-18-3 C22H29NO4S
    ethyl 3-[1,3-dimethyl-4-(ethylsulfanyl)-6,7-dihydro-1H-indole-2,5-diyl]acrylate
    —— 12-acetyl-1-chloro-12H-quinoxalino<2,3-b><1,4>benzothiazine 110744-35-9 C16H10ClN3OS
    12-acetyl-1-chloro-12H-quinoxalino<2,3-b><1,4>benzothiazine
    —— 2-[3-(3-Methylsulfanyl-quinolin-4-ylsulfanyl)-quinolin-4-yl]-2-phenyl-pent-4-enenitrile 109179-08-0 C30H23N3S2
    2-[3-(3-Methylsulfanyl-quinolin-4-ylsulfanyl)-quinolin-4-yl]-2-phenyl-pent-4-enenitrile
    —— 2-methyl-4-propylsulfanyl-pyridine-1-oxide 100860-95-5 C9H13NOS
    2-methyl-4-propylsulfanyl-pyridine-1-oxide
    —— 4-Hydroxy-4-phenylthiomethyl-2,5-cyclohexadienon 71316-87-5 C13H12O2S
    4-Hydroxy-4-phenylthiomethyl-2,5-cyclohexadienon
    —— 3-(5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-pyridine 28534-84-1 C9H9N3S2
    3-(5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-pyridine
    —— N<sup>4</sup>,S-Diacetyl-5-methylthio-2-furaldehyd-thiosemicarbazon 24306-88-5 C11H13N3O3S2
    N<sup>4</sup>,S-Diacetyl-5-methylthio-2-furaldehyd-thiosemicarbazon
    —— 1,1,1-trichloro-2,3,4,4,4-pentafluorobut-2-ene 138805-27-3 C4Cl3F5
    1,1,1-trichloro-2,3,4,4,4-pentafluorobut-2-ene
    —— Dithiocarbonic acid O-(2,2-dipropyl-cyclohex-3-enyl) ester S-methyl ester 27334-14-1 C14H24OS2
    Dithiocarbonic acid O-(2,2-dipropyl-cyclohex-3-enyl) ester S-methyl ester
    —— 4-(1-Trifluoromethanesulfonyl-ethanesulfonyl)-pent-1-en-3-ol 96247-10-8 C8H13F3O5S2
    4-(1-Trifluoromethanesulfonyl-ethanesulfonyl)-pent-1-en-3-ol
    —— 3-cyano-1-methylisothiourea sodium salt 67944-71-2 C3H4N3S*Na
    3-cyano-1-methylisothiourea sodium salt
    —— (S,Z)-4-(2-((R)-2-hydroxybutyl)-1,3-dithian-2-yl)pent-2-en-1-ol 1374424-61-9 C13H24O2S2
    (S,Z)-4-(2-((R)-2-hydroxybutyl)-1,3-dithian-2-yl)pent-2-en-1-ol
    —— (β-Hydroxy-ethyl)-(3-isopropylmercapto-phenyl)-sulfid 22017-41-0 C11H16OS2
    (β-Hydroxy-ethyl)-(3-isopropylmercapto-phenyl)-sulfid
    —— 2-Sulfinyl-1-benzothiophen-3-one 91891-70-2 C8H4O2S2
    2-Sulfinyl-1-benzothiophen-3-one
    —— (2E,3E)-1,1,1-trifluoro-3-(methoxymethyl)-N,4-diphenyl-4-(p-tolylthio)but-3-en-2-imine 1241668-44-9 C25H22F3NOS
    (2E,3E)-1,1,1-trifluoro-3-(methoxymethyl)-N,4-diphenyl-4-(p-tolylthio)but-3-en-2-imine
    —— 2-<2-<1,3-dimethyl-2-<(phenylthio)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane 98127-13-0 C19H26O2S
    2-<2-<1,3-dimethyl-2-<(phenylthio)methyl>-2-cyclohexen-1-yl>methyl>-1,3-dioxolane
    —— (1R,3R,4S)-4-isopropyl-3-(phenylsulfanyl)cyclohexyl acetate 881927-35-1 C17H24O2S
    (1R,3R,4S)-4-isopropyl-3-(phenylsulfanyl)cyclohexyl acetate
    —— 2-Diethoxyphosphorylessigsaeure-<6-<2β-(2-formyl-1,3-dithian-2-yl)-4α-<(2-methoxyethoxy)methoxy>-1α-cyclopentyl>-1-methyl-5-hexenyl>ester 90383-06-5 C27H47O9PS2
    2-Diethoxyphosphorylessigsaeure-<6-<2β-(2-formyl-1,3-dithian-2-yl)-4α-<(2-methoxyethoxy)methoxy>-1α-cyclopentyl>-1-methyl-5-hexenyl>ester
    —— (E)-2-Methyl-but-2-enedithioic acid methyl ester 75413-24-0 C6H10S2
    (E)-2-Methyl-but-2-enedithioic acid methyl ester
    —— methyl 5-deoxy-2,3-O-isopropylidene-5-(uracil-2-yl)thio-β-D-ribofuranoside 676557-67-8 C13H18N2O5S
    methyl 5-deoxy-2,3-O-isopropylidene-5-(uracil-2-yl)thio-β-D-ribofuranoside
    —— 5-dimethylcarbamoyloxy-1-methyl-3-methylsulfanyl-1<i>H</i>-[1,2,4]triazole 53065-34-2 C7H12N4O2S
    5-dimethylcarbamoyloxy-1-methyl-3-methylsulfanyl-1<i>H</i>-[1,2,4]triazole
    —— 3-(naphthalen-1-ylthio)-6-nitro-1H-indazole 1300735-05-0 C17H11N3O2S
    3-(naphthalen-1-ylthio)-6-nitro-1H-indazole
    —— N,N-dimethyl-2-(4'-bromomethyl-2'-nitrophenylthio)-5-iodo-benzamide 1005412-89-4 C16H14BrIN2O3S
    N,N-dimethyl-2-(4'-bromomethyl-2'-nitrophenylthio)-5-iodo-benzamide
    —— [3-(2-cyano-phenylsulfanyl)-1-pyridin-2-ylmethyl-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester 868673-39-6 C27H26N4O2S
    [3-(2-cyano-phenylsulfanyl)-1-pyridin-2-ylmethyl-1H-indol-6-yl]-methyl-carbamic acid tert-butyl ester
    —— 3-(2-aminoethylthio)-4-phenylfurazan 204335-75-1 C10H11N3OS
    3-(2-aminoethylthio)-4-phenylfurazan
    —— 2,4-Bis-(2-hydroxy-aethylmercapto)-toluol 30393-61-4 C11H16O2S2
    2,4-Bis-(2-hydroxy-aethylmercapto)-toluol
    —— 2,4-Dimethyl-9-(2-morpholin-4-yl-ethyl)-9H-10-thia-1,3,9-triaza-anthracene 6981-92-6 C18H22N4OS
    2,4-Dimethyl-9-(2-morpholin-4-yl-ethyl)-9H-10-thia-1,3,9-triaza-anthracene
    —— (But-3-yn-1-yl)(imino)methyl-lambda6-sulfanone 2309466-18-8 C5H9NOS
    (But-3-yn-1-yl)(imino)methyl-lambda6-sulfanone
    —— 2-(5-Nitropyridin-2-yl)sulfanyl-1H-pyrimidin-6-one 73768-48-6 C9H6N4O3S
    2-(5-Nitropyridin-2-yl)sulfanyl-1H-pyrimidin-6-one
    —— phenyl 3-(4-fluorophenylthio)-2-methyl-N-(4-methylphenyl)-2-propenimidothioate 1158835-12-1 C23H20FNS2
    phenyl 3-(4-fluorophenylthio)-2-methyl-N-(4-methylphenyl)-2-propenimidothioate
    —— [7-chloro-3-(4-chlorophenylamino)-8-methyl-1,1-dioxo-4H-1,5,2-benzo[f]dithiazepin-4-ylidene]acetic acid 1083063-89-1 C17H12Cl2N2O4S2
    [7-chloro-3-(4-chlorophenylamino)-8-methyl-1,1-dioxo-4H-1,5,2-benzo[f]dithiazepin-4-ylidene]acetic acid
    —— 3-Benzyloxy-5-methylsulfanyl-isothiazole-4-carbonitrile 4886-06-0 C12H10N2OS2
    3-Benzyloxy-5-methylsulfanyl-isothiazole-4-carbonitrile
    —— 2,5-dimethyl-4-pentachlorophenylsulfanyl-pyrrole 32884-69-8 C12H8Cl5NS
    2,5-dimethyl-4-pentachlorophenylsulfanyl-pyrrole
    —— 5-(2-isopropylsulfanylphenyl)-3-(5-phenyl-1,3,4-oxadiazol-2-yl)pyrazin-2-amine 1232411-53-8 C21H19N5OS
    5-(2-isopropylsulfanylphenyl)-3-(5-phenyl-1,3,4-oxadiazol-2-yl)pyrazin-2-amine
    —— 3-ethoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one 34658-14-5 C8H10N2O2S
    3-ethoxy-2,3-dihydro-thiazolo[3,2-a]pyrimidin-7-one