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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(1R)-1-[5-[2-(tert-butylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium —— C13H25N4O2S+
    [(1R)-1-[5-[2-(tert-butylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium
    —— ethyl N-[2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]carbamate —— C13H21N4O4S+
    ethyl N-[2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]carbamate
    —— (2S)-N-methyl-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C12H20N4O2S
    (2S)-N-methyl-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide —— C15H25N5O2S2
    (2R)-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-prop-2-enylpropanamide
    —— N-(2-methoxyethyl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C8H13N3O3S
    N-(2-methoxyethyl)-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-methyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C13H23N5O2S2
    (2S)-N-methyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C11H14N4O4S2
    (2S)-N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-methyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C7H11N3O2S
    (2S)-N-methyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-ethyl-2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C13H23N4O2S+
    (2S)-N-ethyl-2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H18N4O3S2
    N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C15H19N3O4S2
    1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— (2R)-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide —— C14H24N4O2S
    (2R)-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C10H15N3O4S2
    (2R)-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-tert-butyl-2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H25N4O2S+
    N-tert-butyl-2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S)-1-cyclopropylethyl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C10H15N3O2S
    N-[(1S)-1-cyclopropylethyl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(2S)-3-methylbutan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C10H17N3O2S
    N-[(2S)-3-methylbutan-2-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-methyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C13H23N5O2S2
    (2R)-N-methyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-ethyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C8H13N3O2S
    (2S)-N-ethyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C11H17N3O4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-cyclopropyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H25N5O2S2
    (2R)-N-cyclopropyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-cyclopropyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N5O2S2+
    N-cyclopropyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C9H13N3O4S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C10H15N3O4S2
    (2R)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-(2-cyanoethyl)-N-methyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C9H12N4O2S
    N-(2-cyanoethyl)-N-methyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C8H12N4OS
    (2S)-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-cyclopropyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H26N5O2S2+
    (2S)-N-cyclopropyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(2-methylpropyl)acetamide —— C9H15N3O2S
    2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(2-methylpropyl)acetamide
    —— (2R)-N-cyclopropyl-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C11H15N3O2S
    (2R)-N-cyclopropyl-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-(2-methylpropyl)-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H28N5O2S2+
    N-(2-methylpropyl)-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C10H15N3O3S
    2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C10H15N3O4S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-[(1R)-1-phenylethyl]piperazin-4-ium-1-yl]ethanone —— C18H26N5OS+
    2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-[(1R)-1-phenylethyl]piperazin-4-ium-1-yl]ethanone
    —— 1-[2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]pyrrolidin-2-one —— C10H14N4O2S
    1-[2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]pyrrolidin-2-one
    —— 2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C11H18N4O3S2
    2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— [(1S)-2-[[2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium —— C16H24N5OS+
    [(1S)-2-[[2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]amino]-1-phenylethyl]-dimethylazanium
    —— 2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-[(1S)-1-phenylethyl]piperazin-1-yl]ethanone —— C18H25N5OS
    2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[4-[(1S)-1-phenylethyl]piperazin-1-yl]ethanone
    —— 1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C12H20N4O2S
    1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C8H14N4OS
    (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide —— C11H18N4O3S2
    (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]propanamide
    —— 2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C11H18N4O3S2
    2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide
    —— N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H23N5OS
    N-[(2S)-2-(dimethylamino)-2-phenylethyl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-(2,5-Dichlorothiophen-3-yl)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C10H9Cl2N3OS2
    1-(2,5-Dichlorothiophen-3-yl)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 3-[2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C9H12N4O3S
    3-[2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide —— C13H22N4O3S2
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethylpropanamide
    —— N'-acetyl-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetohydrazide —— C9H12N4O3S
    N'-acetyl-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetohydrazide
    —— (3R)-1-[(2S)-1-methoxypropan-2-yl]-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide —— C21H24N2O3S
    (3R)-1-[(2S)-1-methoxypropan-2-yl]-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide
    —— (3S)-1-[(2R)-1-methoxypropan-2-yl]-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide —— C21H24N2O3S
    (3S)-1-[(2R)-1-methoxypropan-2-yl]-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide
    —— (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C11H18N4O3S2
    (2S)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-N-cyclopropyl-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C11H15N3O2S
    (2S)-N-cyclopropyl-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H18N4OS
    N-[(1R)-1-cyclopropylethyl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]acetamide