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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Dithiophosphoric acid S-allyl ester O-ethyl ester S'-methyl ester 27564-75-6 C6H13O2PS2
    Dithiophosphoric acid S-allyl ester O-ethyl ester S'-methyl ester
    —— 4-allyl-3-chloro-1-methyl-5-(phenylthio)-1H-pyrazole 1174231-76-5 C13H13ClN2S
    4-allyl-3-chloro-1-methyl-5-(phenylthio)-1H-pyrazole
    —— 2-(Diethylamino)-3-phenylsulfanylpropanenitrile 111248-42-1 C13H18N2S
    2-(Diethylamino)-3-phenylsulfanylpropanenitrile
    —— 2-Methyl-3-p-tolylmercapto-propionsaeure-butylester 30242-92-3 C15H22O2S
    2-Methyl-3-p-tolylmercapto-propionsaeure-butylester
    —— o-Tolyl-isopropylaminomethyl-sulfid 25508-62-7 C11H17NS
    o-Tolyl-isopropylaminomethyl-sulfid
    —— Tris-(p-sec.-nonyl-phenylthio)-phosphin 1952-80-3 C45H69PS3
    Tris-(p-sec.-nonyl-phenylthio)-phosphin
    —— <i>N</i>,<i>N</i>-diethyl-2-(4-methyl-6-oxo-5-propyl-1,6-dihydro-pyrimidin-2-ylsulfanyl)-acetamide 28994-69-6 C14H23N3O2S
    <i>N</i>,<i>N</i>-diethyl-2-(4-methyl-6-oxo-5-propyl-1,6-dihydro-pyrimidin-2-ylsulfanyl)-acetamide
    —— (2-Methyl-allylsulfanylmethylsulfanyl)-benzene 52163-48-1 C11H14S2
    (2-Methyl-allylsulfanylmethylsulfanyl)-benzene
    —— 1,3-Dimethyl-4-methylthiopyrazol-5-yl-methylcarbamat 26128-73-4 C8H13N3O2S
    1,3-Dimethyl-4-methylthiopyrazol-5-yl-methylcarbamat
    —— (2-Nitro-3-thienyl)-(2-amino-4-methylthio-phenyl)-sulfid 7028-14-0 C11H10N2O2S3
    (2-Nitro-3-thienyl)-(2-amino-4-methylthio-phenyl)-sulfid
    —— 2,4-dimethyl-5-methylsulfanyl-pyrrole-3-carboxylic acid ethyl ester 36151-66-3 C10H15NO2S
    2,4-dimethyl-5-methylsulfanyl-pyrrole-3-carboxylic acid ethyl ester
    —— 2-methylthio-5-methyl-6-[1-fluoro-1-(4-fluorophenyl)methyl]cytosine 1093390-13-6 C13H13F2N3S
    2-methylthio-5-methyl-6-[1-fluoro-1-(4-fluorophenyl)methyl]cytosine
    —— Acetic acid (1S,2S)-2-(1-phenylsulfanyl-allyl)-cyclohexyl ester 81634-91-5 C17H22O2S
    Acetic acid (1S,2S)-2-(1-phenylsulfanyl-allyl)-cyclohexyl ester
    —— 1108185-80-3 C19H28O3S
    —— (4-Chloro-phenyl)-dithiocarbamic acid phenyl ester 21167-90-8 C13H10ClNS2
    (4-Chloro-phenyl)-dithiocarbamic acid phenyl ester
    —— 1-[5-(3-chloro-phenyl)-[1,3,4]oxadiazol-2-ylsulfanyl]-2-thiocyanato-ethane 53961-40-3 C11H8ClN3OS2
    1-[5-(3-chloro-phenyl)-[1,3,4]oxadiazol-2-ylsulfanyl]-2-thiocyanato-ethane
    —— bis(5'-mesitylthio-3,4-ethylenedioxy-5,2'-bithien-2-yl) sulfide 1093634-23-1 C38H34O4S7
    bis(5'-mesitylthio-3,4-ethylenedioxy-5,2'-bithien-2-yl) sulfide
    —— 111994-28-6 C16H10CoN4S4
    —— 20639-46-7 C12H24N2O2S
    —— Dithiophosphorsaeure-O,O-diisopropyl-S-<2-(4-methylmercapto-phenylmercapto)-aethyl>-ester 92789-76-9 C15H25O2PS4
    Dithiophosphorsaeure-O,O-diisopropyl-S-<2-(4-methylmercapto-phenylmercapto)-aethyl>-ester
    —— Ethyl-phenyl-dithiocarbamic acid 4,6-dimethyl-pyrimidin-2-yl ester 32595-26-9 C15H17N3S2
    Ethyl-phenyl-dithiocarbamic acid 4,6-dimethyl-pyrimidin-2-yl ester
    —— (Z)-(2S,5R)-3-(2-acetoxyethylidene)-2-phenylthio-4-oxa-1-azabicyclo<3.2.0>heptan-7-one 82895-97-4 C15H15NO4S
    (Z)-(2S,5R)-3-(2-acetoxyethylidene)-2-phenylthio-4-oxa-1-azabicyclo<3.2.0>heptan-7-one
    —— Phenyl-phosphonothioic acid O-ethyl ester O-(2-isopropoxy-6-methyl-5-methylsulfanyl-pyrimidin-4-yl) ester 55995-87-4 C17H23N2O3PS2
    Phenyl-phosphonothioic acid O-ethyl ester O-(2-isopropoxy-6-methyl-5-methylsulfanyl-pyrimidin-4-yl) ester
    —— 5-bromo-2-dodecylsulfanyl-4-methyl-1H-pyrimidin-6-one 856766-59-1 C17H29BrN2OS
    5-bromo-2-dodecylsulfanyl-4-methyl-1H-pyrimidin-6-one
    —— tris(tert-butylsulfanyl)indigane 215182-56-2 C24H54In2S6
    tris(tert-butylsulfanyl)indigane
    —— 2-(4-methylphenylsulfanyl)cyclobutanone 84525-39-3 C11H12OS
    2-(4-methylphenylsulfanyl)cyclobutanone
    —— (S)-1,1,1,3,3,3-hexafluoropropan-2-yl 3-((4-chlorophenyl)thio)-3-phenylpropanoate 1443455-63-7 C18H13ClF6O2S
    (S)-1,1,1,3,3,3-hexafluoropropan-2-yl 3-((4-chlorophenyl)thio)-3-phenylpropanoate
    —— 4-Chloro-N<sup>1</sup>-(4-chloro-phenyl)-5-thiocyanato-benzene-1,2-diamine 23648-89-7 C13H9Cl2N3S
    4-Chloro-N<sup>1</sup>-(4-chloro-phenyl)-5-thiocyanato-benzene-1,2-diamine
    —— Bis-(carbamoylmethylmercapto)-chinon 38969-15-2 C24H24N4O4S2
    Bis-(carbamoylmethylmercapto)-chinon
    —— N-cyclohexyl-2-ethyl-2-(N-ethyl-2-((6-oxo-4-propyl-1,6-dihydropyrimidin-2-yl)thio)acetamido)butanamide 1379463-55-4 C23H38N4O3S
    N-cyclohexyl-2-ethyl-2-(N-ethyl-2-((6-oxo-4-propyl-1,6-dihydropyrimidin-2-yl)thio)acetamido)butanamide
    —— 2-[4-(4-chloro-5-styryl-[1,2,3]triazol-2-yl)-phenyl]-5-methoxy-6-phenylsulfanyl-2<i>H</i>-benzotriazole 41500-47-4 C29H21ClN6OS
    2-[4-(4-chloro-5-styryl-[1,2,3]triazol-2-yl)-phenyl]-5-methoxy-6-phenylsulfanyl-2<i>H</i>-benzotriazole
    —— 3,5-dichloro-2-(4-chlorophenylthio)benzyl alcohol 79332-33-5 C13H9Cl3OS
    3,5-dichloro-2-(4-chlorophenylthio)benzyl alcohol
    —— Chlorcarbonylthiocyanat 16829-40-6 C2ClNOS
    Chlorcarbonylthiocyanat
    —— 2-(2-methylphenyl)-5-(4-methylphenylthio)-1,3,4-oxadiazole 1414598-50-7 C16H14N2O2S
    2-(2-methylphenyl)-5-(4-methylphenylthio)-1,3,4-oxadiazole
    —— (1-Ethoxycarbonylamino-2-methyl-3-phenylsulfanyl-pentyl)-carbamic acid ethyl ester 24961-51-1 C18H28N2O4S
    (1-Ethoxycarbonylamino-2-methyl-3-phenylsulfanyl-pentyl)-carbamic acid ethyl ester
    —— α-Brom-β-phenylthio-cis-zimtsaeure-ethylester 33993-96-3 C17H15BrO2S
    α-Brom-β-phenylthio-cis-zimtsaeure-ethylester
    —— 1394293-57-2 C14H18N4O2S3
    —— 2-(N-benzyl-2-((6-oxo-4-propyl-1,6-dihydropyrimidin-2-yl)thio)acetamido)-N-cyclohexyl-2-ethylbutanamide 1379463-50-9 C28H40N4O3S
    2-(N-benzyl-2-((6-oxo-4-propyl-1,6-dihydropyrimidin-2-yl)thio)acetamido)-N-cyclohexyl-2-ethylbutanamide
    —— 9-(2-hydroxy-propyl)-7-methyl-2-methylsulfanyl-8,9-dihydro-7H-pyrimido[4,5-e][1,4]oxazepin-5-one 32640-37-2 C12H17N3O3S
    9-(2-hydroxy-propyl)-7-methyl-2-methylsulfanyl-8,9-dihydro-7H-pyrimido[4,5-e][1,4]oxazepin-5-one
    —— (3-(tert-butyl)-2-((2-(tert-butyl)phenyl)sulfonyl)phenyl)(p-tolyl)sulfane 1202638-04-7 C27H32O2S2
    (3-(tert-butyl)-2-((2-(tert-butyl)phenyl)sulfonyl)phenyl)(p-tolyl)sulfane
    —— propane-2,2-diylbis(p-tolylsulfane) 57354-83-3 C17H20S2
    propane-2,2-diylbis(p-tolylsulfane)
    —— (4-benzylsulfanyl-6-iodo-pyrimidin-5-yl)-methyl-amine 1092101-15-9 C12H12IN3S
    (4-benzylsulfanyl-6-iodo-pyrimidin-5-yl)-methyl-amine
    —— (methylthio)carbonyl methoxydichloromethyl disulphane 87463-12-5 C4H6Cl2O2S3
    (methylthio)carbonyl methoxydichloromethyl disulphane
    —— cis-1,2-bis-(p-tolylthio)ethylene 4526-53-8 C16H16S2
    cis-1,2-bis-(p-tolylthio)ethylene
    —— Tris-(p-sec.-heptyl-phenylthio)-phosphin 2316-01-0 C39H57PS3
    Tris-(p-sec.-heptyl-phenylthio)-phosphin
    —— 2-(6-chloro-3-oxo-2-phenyl-2,3-dihydro-pyridazin-4-ylsulfanyl)-<i>N</i>-hydroxy-acetamide 25381-88-8 C12H10ClN3O3S
    2-(6-chloro-3-oxo-2-phenyl-2,3-dihydro-pyridazin-4-ylsulfanyl)-<i>N</i>-hydroxy-acetamide
    —— 12694-01-8 C18H16N2O2S2
    —— 5-acetonylthio-2-thioxo-1,3-dithiol-4-carbonsaueremethylester 127252-36-2 C8H8O3S4
    5-acetonylthio-2-thioxo-1,3-dithiol-4-carbonsaueremethylester
    —— (3aR,4R,7aS)-3,4-dimethyl-6-(phenylthio)tetrahydro-4H-pyrano[3,4-d]oxazol-2(3H)-one 1260085-10-6 C14H17NO3S
    (3aR,4R,7aS)-3,4-dimethyl-6-(phenylthio)tetrahydro-4H-pyrano[3,4-d]oxazol-2(3H)-one
    —— N-(4-((8-(pyridin-3-yl)-9H-purin-6-yl)thio)phenyl)acetamide 1170069-31-4 C18H14N6OS
    N-(4-((8-(pyridin-3-yl)-9H-purin-6-yl)thio)phenyl)acetamide