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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(2-nitro-phenylsulfanyl)-1-pyridin-3-ylmethyl-1H-indol-6-ylamine 868672-72-4 C20H16N4O2S
    3-(2-nitro-phenylsulfanyl)-1-pyridin-3-ylmethyl-1H-indol-6-ylamine
    —— bis(2-mercapto-ethylamine)-cobalt(II) 66268-51-7 C4H12CoN2S2
    bis(2-mercapto-ethylamine)-cobalt(II)
    —— 2-(1-Triethylsilanyloxy-vinylsulfanyl)-pyridine 199989-15-6 C13H21NOSSi
    2-(1-Triethylsilanyloxy-vinylsulfanyl)-pyridine
    —— 6-phenylsulfanyl-2<i>H</i>-[1,2,4]triazine-3,5-dithione 32330-99-7 C9H7N3S3
    6-phenylsulfanyl-2<i>H</i>-[1,2,4]triazine-3,5-dithione
    —— 6-[2-isobutyl-3-(3-methyl-butyl)-5-nitro-3<i>H</i>-imidazol-4-ylsulfanyl]-7(9)<i>H</i>-purine 4604-86-8 C17H23N7O2S
    6-[2-isobutyl-3-(3-methyl-butyl)-5-nitro-3<i>H</i>-imidazol-4-ylsulfanyl]-7(9)<i>H</i>-purine
    —— 2-Amino-6-benzyl-4-methylsulfanyl-nicotinonitrile 28947-14-0 C14H13N3S
    2-Amino-6-benzyl-4-methylsulfanyl-nicotinonitrile
    —— [(R)-2-((1R,2S)-2-Methyl-cyclopropyl)-4,5-dihydro-thiazol-4-yl]-methanol 180866-39-1 C8H13NOS
    [(R)-2-((1R,2S)-2-Methyl-cyclopropyl)-4,5-dihydro-thiazol-4-yl]-methanol
    —— [(2,2'-thiobis(4,6-ditertbutylphenolate)AlCl(THF)] 1231659-35-0 C32H48AlClO3S
    [(2,2'-thiobis(4,6-ditertbutylphenolate)AlCl(THF)]
    —— 2-benzyl-2-(pyridin-2-ylthio)nonanedinitrile 1510799-57-1 C21H23N3S
    2-benzyl-2-(pyridin-2-ylthio)nonanedinitrile
    —— 7-hydroxy-2-methoxy-1,4,2-benzoxathiaphosphinin-3(2H)-one 2-oxide 1563093-01-5 C8H7O5PS
    7-hydroxy-2-methoxy-1,4,2-benzoxathiaphosphinin-3(2H)-one 2-oxide
    —— 2-((1H-indol-3-yl)thio)benzo[d]thiazole 27933-95-5 C15H10N2S2
    2-((1H-indol-3-yl)thio)benzo[d]thiazole
    —— 2-((4-amino-5-oxo-6-(2-(2-thienyl)vinyl)-4,5-dihydro-1,2,4-triazin-3-ylthio)methoxy)ethyl acetate 1313511-19-1 C14H16N4O4S2
    2-((4-amino-5-oxo-6-(2-(2-thienyl)vinyl)-4,5-dihydro-1,2,4-triazin-3-ylthio)methoxy)ethyl acetate
    —— 6-Ethyl-5-ethylsulfanyl-pyrimidine-2,4-diamine 74873-48-6 C8H14N4S
    6-Ethyl-5-ethylsulfanyl-pyrimidine-2,4-diamine
    —— 1-acetoxy-3-(5-chloro-2-methyl-6-phenylsulfanyl-benzoimidazol-1-yl)-propane 35967-35-2 C19H19ClN2O2S
    1-acetoxy-3-(5-chloro-2-methyl-6-phenylsulfanyl-benzoimidazol-1-yl)-propane
    —— 2-(3,4-bis-methylsulfanyl-benzyl)-3-morpholin-4-yl-acrylonitrile 71126-01-7 C16H20N2OS2
    2-(3,4-bis-methylsulfanyl-benzyl)-3-morpholin-4-yl-acrylonitrile
    —— (6-<i>sec</i>-butylsulfanyl-2-ethyl-5-nitro-pyrimidin-4-yl)-(1-ethyl-propyl)-amine 58289-55-7 C15H26N4O2S
    (6-<i>sec</i>-butylsulfanyl-2-ethyl-5-nitro-pyrimidin-4-yl)-(1-ethyl-propyl)-amine
    —— ethyl 2-(dimethyl(oxo)-λ<sup>6</sup>-sulfanylidene)acetate 19956-89-9 C6H12O3S
    ethyl 2-(dimethyl(oxo)-λ<sup>6</sup>-sulfanylidene)acetate
    —— 2,3-Dihydro[1,4]oxathiino[2,3-b]pyridin-7-ylmethanol 944407-70-9 C8H9NO2S
    2,3-Dihydro[1,4]oxathiino[2,3-b]pyridin-7-ylmethanol
    —— <i>sec</i>-butyl-thiophosphoramidic acid <i>O</i>-ethyl ester <i>S</i>-(3-methyl-6-oxo-6<i>H</i>-pyridazin-1-ylmethyl) ester 56075-85-5 C12H22N3O3PS
    <i>sec</i>-butyl-thiophosphoramidic acid <i>O</i>-ethyl ester <i>S</i>-(3-methyl-6-oxo-6<i>H</i>-pyridazin-1-ylmethyl) ester
    —— (1-ethyl-propyl)-(2-isopropyl-6-isopropylsulfanyl-5-nitro-pyrimidin-4-yl)-amine 58289-49-9 C15H26N4O2S
    (1-ethyl-propyl)-(2-isopropyl-6-isopropylsulfanyl-5-nitro-pyrimidin-4-yl)-amine
    —— 2-allylamino-4'-methyldiphenyl sulphide 98569-87-0 C16H17NS
    2-allylamino-4'-methyldiphenyl sulphide
    —— Methylen-N,N'-bis-(S-ethyl-thiocarbamat) 42155-28-2 C7H14N2O2S2
    Methylen-N,N'-bis-(S-ethyl-thiocarbamat)
    —— (+)(S)-(1-methyl-heptyl)-thiocyanate 73522-28-8 C9H17NS
    (+)(S)-(1-methyl-heptyl)-thiocyanate
    —— 2,3,5-trifluoro-1-(p-tolylthio)benzene 1055876-55-5 C13H9F3S
    2,3,5-trifluoro-1-(p-tolylthio)benzene
    —— Pd(II) dimethyldithiophosphate 29136-48-9 C4H12O4P2PdS4
    Pd(II) dimethyldithiophosphate
    —— S-(Pentafluorophenyl)propanethioate 137905-75-0 C9H5F5OS
    S-(Pentafluorophenyl)propanethioate
    —— methyl (NE)-N-[amino-[2-(butanoylamino)-4-phenylsulfanylanilino]methylidene]carbamate 65934-76-1 C19H22N4O3S
    methyl (NE)-N-[amino-[2-(butanoylamino)-4-phenylsulfanylanilino]methylidene]carbamate
    —— 5-bromo-3-[(4-nitrophenyl)thio]-1H-indole 336186-60-8 C14H9BrN2O2S
    5-bromo-3-[(4-nitrophenyl)thio]-1H-indole
    —— 2-Chlorpropyl-dithiochlorid 89167-70-4 C3H6Cl2S2
    2-Chlorpropyl-dithiochlorid
    —— 1-nitro-1-(p-tolylthio)cyclohexane 1402833-09-3 C13H17NO2S
    1-nitro-1-(p-tolylthio)cyclohexane
    —— 3-hydroxymethyl-5-isopropylsulfanyl-3<i>H</i>-[1,3,4]thiadiazol-2-one 91775-10-9 C6H10N2O2S2
    3-hydroxymethyl-5-isopropylsulfanyl-3<i>H</i>-[1,3,4]thiadiazol-2-one
    —— (η(5)-C5H5)Fe(C5H4CHN(CH2)2S2(CH2)2NCHC5H4)Fe(η(5)-C5H5) 220916-76-7 C26H28Fe2N2S2
    (η(5)-C5H5)Fe(C5H4CHN(CH2)2S2(CH2)2NCHC5H4)Fe(η(5)-C5H5)
    —— ethyl 3-phenylthio-4-pentenyl malonate 128886-20-4 C16H20O4S
    ethyl 3-phenylthio-4-pentenyl malonate
    —— 5,9-Dimethyl-1-phenylthio-spiro<3.5>non-1-en 63048-81-7 C17H22S
    5,9-Dimethyl-1-phenylthio-spiro<3.5>non-1-en
    —— ethyl 1-(2-p-chlorobenzylidenehydrazinyl)-4-cyano-5,6,7,8-tetrahydroisoquinoline-3-sulfanylacetate 1269792-87-1 C21H21ClN4O2S
    ethyl 1-(2-p-chlorobenzylidenehydrazinyl)-4-cyano-5,6,7,8-tetrahydroisoquinoline-3-sulfanylacetate
    —— ethyl 2-(1-cyclohexenyl)-2-phenylthioethyl malonate 128886-18-0 C19H24O4S
    ethyl 2-(1-cyclohexenyl)-2-phenylthioethyl malonate
    —— 4-(benzo[d]thiazol-2-ylthio)-5-(3-(methylsulfonyl)phenyl)thieno[2,3-d]pyrimidine 1370338-50-3 C20H13N3O2S4
    4-(benzo[d]thiazol-2-ylthio)-5-(3-(methylsulfonyl)phenyl)thieno[2,3-d]pyrimidine
    —— 3-(4-Chloromethyl-[1,2,3]thiadiazol-5-ylsulfanyl)-propionic acid ethyl ester 332125-87-8 C8H11ClN2O2S2
    3-(4-Chloromethyl-[1,2,3]thiadiazol-5-ylsulfanyl)-propionic acid ethyl ester
    —— <S-Aethyl-methylthiocarbamoyl>-diaethyl-aluminium 24004-56-6 C8H18AlNOS
    <S-Aethyl-methylthiocarbamoyl>-diaethyl-aluminium
    —— 5-methoxycarbonylmethylsulfanyl-2,4-dimethyl-pyrrole-3-carboxylic acid ethyl ester 33027-96-2 C12H17NO4S
    5-methoxycarbonylmethylsulfanyl-2,4-dimethyl-pyrrole-3-carboxylic acid ethyl ester
    —— 3-methoxy-2-methylsulfanyl-3,6-dihydro-2<i>H</i>-thiopyran-2-carbonitrile 35244-13-4 C8H11NOS2
    3-methoxy-2-methylsulfanyl-3,6-dihydro-2<i>H</i>-thiopyran-2-carbonitrile
    —— β-chloro-α-(p-chlorphenylthio)-ethylbenzene 21851-55-8 C14H12Cl2S
    β-chloro-α-(p-chlorphenylthio)-ethylbenzene
    —— <2-Hydroxy-aethylamino-methyl>-<4-chlor-phenyl>-sulfid 22959-37-1 C9H12ClNOS
    <2-Hydroxy-aethylamino-methyl>-<4-chlor-phenyl>-sulfid
    —— 2,4-Bis-propylmercapto-toluol 30393-63-6 C13H20S2
    2,4-Bis-propylmercapto-toluol
    —— 38859-82-4 C26H24S4Sn
    —— 6-chloro-2-phenyl-4-propylsulfanyl-2<i>H</i>-pyridazin-3-one 25381-03-7 C13H13ClN2OS
    6-chloro-2-phenyl-4-propylsulfanyl-2<i>H</i>-pyridazin-3-one
    —— 6-<i>p</i>-tolyloxy-2-<i>p</i>-tolylsulfanyl-pyrimidine-4,5-dione 5-phenylhydrazone 36137-30-1 C24H20N4O2S
    6-<i>p</i>-tolyloxy-2-<i>p</i>-tolylsulfanyl-pyrimidine-4,5-dione 5-phenylhydrazone
    —— Butyl-penten-(4)-yl-sulfon 25492-89-1 C9H18O2S
    Butyl-penten-(4)-yl-sulfon
    —— 2,3-dihydro-3-methylene-5H-thiazolo<2,3-b>-5-pyrimidinone 90997-81-2 C7H6N2OS
    2,3-dihydro-3-methylene-5H-thiazolo<2,3-b>-5-pyrimidinone
    —— cobalt(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate 1448848-07-4 C96H80CoN8O16S8
    cobalt(II) octakis[(3,4-dimethoxyphenyl)thio]phthalocyaninate