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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-phenyl-1,3,4-oxadiazole —— C19H18N2O3S
    2-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-phenyl-1,3,4-oxadiazole
    —— 4-butyl-3-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C16H19N5O2S
    4-butyl-3-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— (1S)-1-[4-butyl-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C16H27N5OS
    (1S)-1-[4-butyl-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— (3S)-3-[5-(3-cyclopentylpropylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H25N3O2S2
    (3S)-3-[5-(3-cyclopentylpropylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 6-methyl-2-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanylpyrimidin-4-amine —— C15H15N5OS
    6-methyl-2-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanylpyrimidin-4-amine
    —— 2-(4-fluorophenyl)sulfanyl-N-[(S)-furan-2-yl(phenyl)methyl]acetamide —— C19H16FNO2S
    2-(4-fluorophenyl)sulfanyl-N-[(S)-furan-2-yl(phenyl)methyl]acetamide
    —— (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide —— C13H17N3OS4
    (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide
    —— 2-[(1S)-1-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C14H13N3OS2
    2-[(1S)-1-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— 4-butyl-3-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C16H19N5O2S
    4-butyl-3-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 2-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-phenyl-1,3,4-oxadiazole —— C19H18N2O3S
    2-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-5-phenyl-1,3,4-oxadiazole
    —— (2S)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide —— C16H18N4O2S2
    (2S)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide
    —— [2-Oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-(2-chloro-6-fluorophenyl)acetate —— C19H19ClFNO3S
    [2-Oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-(2-chloro-6-fluorophenyl)acetate
    —— 2-[(1S)-1-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C16H17N5OS
    2-[(1S)-1-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— N-[(R)-furan-2-yl(phenyl)methyl]-2-phenylsulfanylacetamide —— C19H17NO2S
    N-[(R)-furan-2-yl(phenyl)methyl]-2-phenylsulfanylacetamide
    —— (1R)-1-[4-butyl-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C16H27N5OS
    (1R)-1-[4-butyl-5-[(5-methyl-1,2-oxazol-3-yl)methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— 2-[(1R)-1-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C16H17N5OS
    2-[(1R)-1-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— ethyl (1S)-1-[2-[3-cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]-2-oxocyclopentane-1-carboxylate —— C18H19F3N2O3S
    ethyl (1S)-1-[2-[3-cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]-2-oxocyclopentane-1-carboxylate
    —— ethyl (1R)-1-[2-[3-cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]-2-oxocyclopentane-1-carboxylate —— C18H19F3N2O3S
    ethyl (1R)-1-[2-[3-cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]-2-oxocyclopentane-1-carboxylate
    —— N-[(S)-furan-2-yl(phenyl)methyl]-2-phenylsulfanylacetamide —— C19H17NO2S
    N-[(S)-furan-2-yl(phenyl)methyl]-2-phenylsulfanylacetamide
    —— 2-[(1R)-1-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C14H13N3OS2
    2-[(1R)-1-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— 2-[(1S)-1-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C18H19N5OS
    2-[(1S)-1-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— ethyl (1R)-2-oxo-1-[2-[[4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]cyclopentane-1-carboxylate —— C18H23N3O3S2
    ethyl (1R)-2-oxo-1-[2-[[4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]cyclopentane-1-carboxylate
    —— (3R)-3-[5-(3-cyclopentylpropylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H25N3O2S2
    (3R)-3-[5-(3-cyclopentylpropylsulfanyl)-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 1-(4-Benzylsulfonylpiperazin-1-yl)-2-pyrimidin-2-ylsulfanylethanone —— C17H20N4O3S2
    1-(4-Benzylsulfonylpiperazin-1-yl)-2-pyrimidin-2-ylsulfanylethanone
    —— 2-[(1R)-1-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole —— C18H19N5OS
    2-[(1R)-1-[(5-cyclopropyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-phenyl-1,3,4-oxadiazole
    —— ethyl (1S)-2-oxo-1-[2-[[4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]cyclopentane-1-carboxylate —— C18H23N3O3S2
    ethyl (1S)-2-oxo-1-[2-[[4-(2-thiophen-2-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]cyclopentane-1-carboxylate
    —— N-[(R)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C17H14FN3OS2
    N-[(R)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2R)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide —— C16H18N4O2S2
    (2R)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(2-thiophen-2-ylethyl)propanamide
    —— 3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(5S)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]propanamide —— C17H22N4OS
    3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(5S)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]propanamide
    —— N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-pyrimidin-2-ylsulfanylacetamide —— C19H23N3O3S
    N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C15H17N3OS
    N-[2-(2-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(1R)-1-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C12H13N3O2S
    N-[(1R)-1-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 2-(5-Bromothiophen-2-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole —— C11H7BrN4OS2
    2-(5-Bromothiophen-2-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-pyrimidin-2-ylsulfanylacetamide —— C13H19N3O4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-(2-methoxyethyl)-2-pyrimidin-2-ylsulfanylacetamide
    —— [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] 2-cyclopentylacetate —— C17H22BrNO3S
    [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] 2-cyclopentylacetate
    —— N-[3-(N-methylanilino)propyl]-2-pyrimidin-2-ylsulfanylacetamide —— C16H20N4OS
    N-[3-(N-methylanilino)propyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H14ClN3OS
    N-[2-(3-chlorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-[[(2S)-oxolan-2-yl]methyl]-2-pyrimidin-2-ylsulfanylacetamide —— C20H26N4O2S
    N-[[4-(dimethylamino)phenyl]methyl]-N-[[(2S)-oxolan-2-yl]methyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(2-fluorophenyl)methyl]-2-pyrimidin-2-ylsulfanylacetamide —— C13H12FN3OS
    N-[(2-fluorophenyl)methyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-2-pyrimidin-2-ylsulfanylethanone —— C17H17N3OS
    1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-2-pyrimidin-2-ylsulfanylethanone
    —— 3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(5R)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]propanamide —— C17H22N4OS
    3-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(5R)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]propanamide
    —— N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-N-cyclopropyl-2-pyrimidin-2-ylsulfanylacetamide —— C18H16ClN5O2S
    N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-N-cyclopropyl-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(R)-phenyl(thiophen-2-yl)methyl]-2-pyrimidin-2-ylsulfanylacetamide —— C17H15N3OS2
    N-[(R)-phenyl(thiophen-2-yl)methyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2R)-2-methylsulfonylbutane —— C5H12O2S
    (2R)-2-methylsulfonylbutane
    —— N-[(1S)-1-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C12H13N3O2S
    N-[(1S)-1-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 1-Methyl-2-[[3-[(1-methylimidazol-2-yl)sulfanylmethyl]phenyl]methylsulfanyl]imidazole —— C16H18N4S2
    1-Methyl-2-[[3-[(1-methylimidazol-2-yl)sulfanylmethyl]phenyl]methylsulfanyl]imidazole
    —— N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C17H29N3OS
    N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— 2-(1-methylimidazol-2-yl)sulfanyl-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide —— C17H17N3OS2
    2-(1-methylimidazol-2-yl)sulfanyl-N-[(S)-phenyl(thiophen-2-yl)methyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C15H20N4OS
    N-[[4-(dimethylamino)phenyl]methyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C17H16FN3OS2
    N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide