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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— <i>sec</i>-butyl-(6-chloro-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-amine 39067-58-8 C9H13ClN4O2S
    <i>sec</i>-butyl-(6-chloro-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-amine
    —— (4-Chloro-phenyl)-dithiocarbamic acid 4-fluoro-phenyl ester 21167-97-5 C13H9ClFNS2
    (4-Chloro-phenyl)-dithiocarbamic acid 4-fluoro-phenyl ester
    —— 27824-06-2 C14H30Cl3N2OPS
    —— N-(1-(2-(3,4-dimethoxyphenylthio)phenyl)-2-propyl)formamide 128959-03-5 C18H21NO3S
    N-(1-(2-(3,4-dimethoxyphenylthio)phenyl)-2-propyl)formamide
    —— cis-1-tert-butyl-4-phenylsulfanyl-cyclohexane 59277-55-3 C16H24S
    cis-1-tert-butyl-4-phenylsulfanyl-cyclohexane
    —— 2-phenylthio-6-trifluoromethyl-1,3-benzoxazole 1300106-07-3 C14H8F3NOS
    2-phenylthio-6-trifluoromethyl-1,3-benzoxazole
    —— 2,7-dimethoxy-4,5-dithia-octane 130258-43-4 C8H18O2S2
    2,7-dimethoxy-4,5-dithia-octane
    —— methyl (NE)-N-[[2-(butanoylamino)-4-(4-chlorophenyl)sulfanylanilino]-(methoxycarbonylamino)methylidene]carbamate 73851-19-1 C21H23ClN4O5S
    methyl (NE)-N-[[2-(butanoylamino)-4-(4-chlorophenyl)sulfanylanilino]-(methoxycarbonylamino)methylidene]carbamate
    —— 3-methylsulfanyl-5-(2,4,5-trichloro-phenylsulfanyl)-[1,2,4]thiadiazole 21745-05-1 C9H5Cl3N2S3
    3-methylsulfanyl-5-(2,4,5-trichloro-phenylsulfanyl)-[1,2,4]thiadiazole
    —— 4-(2,4-dichloro-phenylsulfanyl)-6,7-dimethoxy-cinnoline 28006-21-5 C16H12Cl2N2O2S
    4-(2,4-dichloro-phenylsulfanyl)-6,7-dimethoxy-cinnoline
    —— 1582280-04-3 C13H15N3O2S
    —— 2-[[4-[(acetyloxy)methyl]-2-nitrophenyl]thio]-N,N-dimethylbenzamide 627487-91-6 C18H18N2O5S
    2-[[4-[(acetyloxy)methyl]-2-nitrophenyl]thio]-N,N-dimethylbenzamide
    —— 1,2,3,4,5-Pentachloro-6-[sulfinyl-(2,4,5-trichlorophenyl)sulfanylmethyl]sulfanylbenzene 1523313-55-4 C13H2Cl8OS3
    1,2,3,4,5-Pentachloro-6-[sulfinyl-(2,4,5-trichlorophenyl)sulfanylmethyl]sulfanylbenzene
    —— S-2-Pyrrolylisothiuronium-iodid 28021-22-9 C9H13N3OS*HI
    S-2-Pyrrolylisothiuronium-iodid
    —— methylthiovinyldichlorophosphine 59085-60-8 C3H5Cl2PS
    methylthiovinyldichlorophosphine
    —— 215855-31-5 C13H16OS
    —— dimethyl 2-(2-((4-chlorophenyl)thio)-2-(thiophen-2-yl)ethyl)malonate 1462945-77-2 C17H17ClO4S2
    dimethyl 2-(2-((4-chlorophenyl)thio)-2-(thiophen-2-yl)ethyl)malonate
    —— N‐(4‐methylphenyl)‐2‐(methylsulfanyl)aniline 1403489-53-1 C14H15NS
    N‐(4‐methylphenyl)‐2‐(methylsulfanyl)aniline
    —— 1-(Nitro-phenylsulfanyl-methyl)-3-phenyl-cyclobutanol 117543-12-1 C17H17NO3S
    1-(Nitro-phenylsulfanyl-methyl)-3-phenyl-cyclobutanol
    —— 2-(4-chlorophenylsulfanyl)cyclobutanone 74851-90-4 C10H9ClOS
    2-(4-chlorophenylsulfanyl)cyclobutanone
    —— <2-(1'-phenylthiopentyl)-1-cyclopentenyl> phenyl sulfoxid 56561-16-1 C22H26OS2
    <2-(1'-phenylthiopentyl)-1-cyclopentenyl> phenyl sulfoxid
    —— 1-benzyl-4-methyl-3-[4-(methylsulfanyl)phenyl]-4,5-dihydro-1H-pyrazole 1379686-78-8 C18H20N2S
    1-benzyl-4-methyl-3-[4-(methylsulfanyl)phenyl]-4,5-dihydro-1H-pyrazole
    —— 4-bromo-2-(phenylthio)phenylcyanamide 1260248-81-4 C13H9BrN2S
    4-bromo-2-(phenylthio)phenylcyanamide
    —— N,N-dimethyl-2-(4'-acetoxymethyl-2'-nitrophenylthio)-5-iodo-benzamide 1005412-93-0 C18H17IN2O5S
    N,N-dimethyl-2-(4'-acetoxymethyl-2'-nitrophenylthio)-5-iodo-benzamide
    —— methyl 4-(3-chlorosulfanyl)benzoate 400856-07-7 C14H11ClO2S
    methyl 4-(3-chlorosulfanyl)benzoate
    —— butylantimony diethyldithiocarbamate 30009-44-0 C14H29N2S4Sb
    butylantimony diethyldithiocarbamate
    —— tert-butyl {[5-[(3-chlorophenyl)thio]-4-(2-fluoropyridin-3-yl)-1,3-thiazol-2-yl]methyl}methylcarbamate 1138033-83-6 C21H21ClFN3O2S2
    tert-butyl {[5-[(3-chlorophenyl)thio]-4-(2-fluoropyridin-3-yl)-1,3-thiazol-2-yl]methyl}methylcarbamate
    —— N-cyclohexyl-2-(N-ethyl-2-((6-oxo-4-propyl-1,6-dihydropyrimidin-2-yl)thio)acetamido)-2-methylpropanamide 1379463-49-6 C21H34N4O3S
    N-cyclohexyl-2-(N-ethyl-2-((6-oxo-4-propyl-1,6-dihydropyrimidin-2-yl)thio)acetamido)-2-methylpropanamide
    —— 1,5-bis-(butane-1-sulfonyl)-3-methyl-3-nitro-pentane 873393-32-9 C14H29NO6S2
    1,5-bis-(butane-1-sulfonyl)-3-methyl-3-nitro-pentane
    —— 2-methoxy-5-(oxan-2-yloxy)-1-phenyl-2-[(E)-1-phenylsulfanylprop-1-en-2-yl]pentan-1-ol 95091-30-8 C26H34O4S
    2-methoxy-5-(oxan-2-yloxy)-1-phenyl-2-[(E)-1-phenylsulfanylprop-1-en-2-yl]pentan-1-ol
    —— dithioarsenochloridous acid bis-(2-chloro-ethyl) ester 90587-52-3 C4H8AsCl3S2
    dithioarsenochloridous acid bis-(2-chloro-ethyl) ester
    —— 3,5,8,11,14,17-hexathiatetracyclo[11.4.0.02,6.07,12]heptadeca-1(13),2(6),7(12)-triene-4-thione 133148-82-0 C11H8S7
    3,5,8,11,14,17-hexathiatetracyclo[11.4.0.02,6.07,12]heptadeca-1(13),2(6),7(12)-triene-4-thione
    —— S-3-dodecylphenyl dimethylcarbamothioate 29688-03-7 C21H35NOS
    S-3-dodecylphenyl dimethylcarbamothioate
    —— Methyl 2-chloro-2-(1-phenylthiocyclopropyl)acetate 110793-97-0 C12H13ClO2S
    Methyl 2-chloro-2-(1-phenylthiocyclopropyl)acetate
    —— N-(tert-butyldithio)acetamide 100682-57-3 C6H13NOS2
    N-(tert-butyldithio)acetamide
    —— Sulfur, (hypochlorito-kappaO)dimethyl- 468060-64-2 C2H6ClOS-
    Sulfur, (hypochlorito-kappaO)dimethyl-
    —— (Z)-1,1,1-trifluoro-4-(4-methylphenyl)sulfanyl-N-phenyldec-3-en-2-imine 1241668-61-0 C23H26F3NS
    (Z)-1,1,1-trifluoro-4-(4-methylphenyl)sulfanyl-N-phenyldec-3-en-2-imine
    —— N-(Dimethylamino)-α-(phenylthio)-succinimid 91567-16-7 C12H14N2O2S
    N-(Dimethylamino)-α-(phenylthio)-succinimid
    —— 3,6-dimethyl-5,7-dioxo-4,5,6,7-tetrahydro-[1,2,3]thiadiazolo[4,5-<i>d</i>]pyrimidinium betaine 60297-59-8 C6H6N4O2S
    3,6-dimethyl-5,7-dioxo-4,5,6,7-tetrahydro-[1,2,3]thiadiazolo[4,5-<i>d</i>]pyrimidinium betaine
    —— 3-(4-Chlor-2-brom-phenylmercapto)-4-amino-phenol 14757-72-3 C12H9BrClNOS
    3-(4-Chlor-2-brom-phenylmercapto)-4-amino-phenol
    —— (5-oxo-6-phenyl-4,5-dihydro-[1,2,4]triazin-3-ylmercapto)-acetic acid 118726-95-7 C11H9N3O3S
    (5-oxo-6-phenyl-4,5-dihydro-[1,2,4]triazin-3-ylmercapto)-acetic acid
    —— (E)-2-(2-(p-tolylthio)ethylidene)hydrazine-1-carboximidamide sulfate 105126-66-7 2C10H14N4S*H2O4S
    (E)-2-(2-(p-tolylthio)ethylidene)hydrazine-1-carboximidamide sulfate
    —— (S)-3-((S)-but-3-en-2-ylsulfonyl)but-1-ene 1314185-31-3 C8H14O2S
    (S)-3-((S)-but-3-en-2-ylsulfonyl)but-1-ene
    —— (E)-methylamino-1-phenyl-3-(4tolylyhio)propenethione 449814-52-2 C17H17NS2
    (E)-methylamino-1-phenyl-3-(4tolylyhio)propenethione
    —— 2-bromodecylthiouracil 152168-41-7 C14H23BrN2OS
    2-bromodecylthiouracil
    —— n-Heptyl-6,6-d2-thiovinylether 36711-99-6 C9H18S
    n-Heptyl-6,6-d2-thiovinylether
    —— 2-(2-morpholin-4-ylethylsulfanyl)-1H-pyrimidin-6-one 95264-00-9 C10H15N3O2S
    2-(2-morpholin-4-ylethylsulfanyl)-1H-pyrimidin-6-one
    —— Ethyl-tert-butyl-methyl-sulfonium 44637-65-2 C7H17S
    Ethyl-tert-butyl-methyl-sulfonium
    —— N-(2-butyl-2-cyclohexen-1-yl)-2-methyl-2-propanesulfonamide 1067231-32-6 C14H27NO2S
    N-(2-butyl-2-cyclohexen-1-yl)-2-methyl-2-propanesulfonamide
    —— bis(4-cyanatophenyl)thioether 101657-79-8 C14H8N2O2S
    bis(4-cyanatophenyl)thioether