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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— trans-2,2-dimethyl-6-phenyl-5-phenylthio-1,3-dioxolane 119061-73-3 C18H20O2S
    trans-2,2-dimethyl-6-phenyl-5-phenylthio-1,3-dioxolane
    —— 2-isopropylthio,6-bromopyridine 98626-90-5 C8H10BrNS
    2-isopropylthio,6-bromopyridine
    —— 2-isopropylthio,5-chloropyridine 98626-99-4 C8H10ClNS
    2-isopropylthio,5-chloropyridine
    —— 2-Isopropylsulfanyl-2-methyl-butyraldehyde 89812-37-3 C8H16OS
    2-Isopropylsulfanyl-2-methyl-butyraldehyde
    —— 2,6-bis(isopropylthio)pyridine 98627-03-3 C11H17NS2
    2,6-bis(isopropylthio)pyridine
    —— 3-chloro-6-(isopropylthio)pyridazine 66089-81-4 C7H9ClN2S
    3-chloro-6-(isopropylthio)pyridazine
    —— 2-Chloro-3-propan-2-ylsulfanylpyridine 871099-86-4 C8H10ClNS
    2-Chloro-3-propan-2-ylsulfanylpyridine
    —— (RS)-1-(3-pyridylthio)propan-2-ol 464934-46-1 C8H11NOS
    (RS)-1-(3-pyridylthio)propan-2-ol
    —— α-Methyl-α-amino-thioisovaleriansaeureamid 16256-19-2 C6H14N2S
    α-Methyl-α-amino-thioisovaleriansaeureamid
    —— 1-(phenylthio)-5-isoquinolinol 144242-88-6 C15H11NOS
    1-(phenylthio)-5-isoquinolinol
    —— 2-Nitro-3-phenethyl-2-p-tolylsulfanyl-oxirane 168135-87-3 C17H17NO3S
    2-Nitro-3-phenethyl-2-p-tolylsulfanyl-oxirane
    —— 5,6-dihydrothieno<2,3-d>-1,3-dithiol-2-one 67188-89-0 C5H4OS3
    5,6-dihydrothieno<2,3-d>-1,3-dithiol-2-one
    —— 2,4-Bis-(2-pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-59-6 C28H33NS4
    2,4-Bis-(2-pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— N-(diisopropoxyphosphorothioyl)-N',N'-dimethylthiourea 1211031-03-6 C9H21N2O2PS2
    N-(diisopropoxyphosphorothioyl)-N',N'-dimethylthiourea
    —— (E)-tert-butyl 1-propenyl sulfone 69113-46-8 C7H14O2S
    (E)-tert-butyl 1-propenyl sulfone
    —— 2-cyano-N,N-dimethylethanethioamide 146561-43-5 C5H8N2S
    2-cyano-N,N-dimethylethanethioamide
    —— 3-Ethyl-2-methylthio-4-phenylthiophene 72814-46-1 C13H14S2
    3-Ethyl-2-methylthio-4-phenylthiophene
    —— (2R,3S,4R)-1-[2-[(2S,3S,6R)-3-[tert-butyl(dimethyl)silyl]oxy-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]heptan-2-yl]-1,3-dithian-2-yl]-3-methoxy-5-methylhexane-2,4-diol 642442-80-6 C45H86O6S4Si
    (2R,3S,4R)-1-[2-[(2S,3S,6R)-3-[tert-butyl(dimethyl)silyl]oxy-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]heptan-2-yl]-1,3-dithian-2-yl]-3-methoxy-5-methylhexane-2,4-diol
    —— 2-Methylthio-4-phenyl-3-propylthiophene 125150-84-7 C14H16S2
    2-Methylthio-4-phenyl-3-propylthiophene
    —— 2-benzylthio-3-methyl-4,5-diphenylthiophene 89003-21-4 C24H20S2
    2-benzylthio-3-methyl-4,5-diphenylthiophene
    —— tert-butyl-[(2S,3S,6R)-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]-2-(1,3-dithian-2-yl)heptan-3-yl]oxy-dimethylsilane 642442-77-1 C37H70O3S4Si
    tert-butyl-[(2S,3S,6R)-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]-2-(1,3-dithian-2-yl)heptan-3-yl]oxy-dimethylsilane
    —— 3-methyl-6-methylsulfanyl-3<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one 99584-35-7 C8H8N4OS
    3-methyl-6-methylsulfanyl-3<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one
    —— <3R,4R,5R,8S,9S,12R,12<2S,3S,6R,8S,8(3S),9R>>-5,9-bis(tert-butyldimethylsilyl)oxy-12-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5,5>undecan-2-yl>-4-methoxy-2,8-dimethyl-7-(1,3-dithian-2-yl)-3-tridecanol 170708-58-4 C51H100O6S4Si2
    <3R,4R,5R,8S,9S,12R,12<2S,3S,6R,8S,8(3S),9R>>-5,9-bis(tert-butyldimethylsilyl)oxy-12-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5,5>undecan-2-yl>-4-methoxy-2,8-dimethyl-7-(1,3-dithian-2-yl)-3-tridecanol
    —— 4,5,6,7-tetrakis(methylthio)-1,3-benzodithiole-2-thione 133148-79-5 C11H12S7
    4,5,6,7-tetrakis(methylthio)-1,3-benzodithiole-2-thione
    —— (4R,5S,6S)-<<5-(Methoxymethoxy)-4,6-dimethyl-8-(phenylthio)-1-octyl>oxy>(1,1-dimethylethyl)diphenylsilane 165961-51-3 C34H48O3SSi
    (4R,5S,6S)-<<5-(Methoxymethoxy)-4,6-dimethyl-8-(phenylthio)-1-octyl>oxy>(1,1-dimethylethyl)diphenylsilane
    —— per(methylthio)dibenzotetrathiafulvalene 129137-82-2 C22H24S12
    per(methylthio)dibenzotetrathiafulvalene
    —— <2S,2<2R,3S,6R,8S,8(3S),9R>>-2-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5.5>undecane-2-yl>-1-propanal 160238-59-5 C23H40O3S2
    <2S,2<2R,3S,6R,8S,8(3S),9R>>-2-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5.5>undecane-2-yl>-1-propanal
    —— 1-Vinyl-trans-2-butenylmethyl-dithiolcarbonat 40486-69-9 C8H12OS2
    1-Vinyl-trans-2-butenylmethyl-dithiolcarbonat
    —— 6-methylsulfanyl-2-thioxo-2,3-dihydro-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one 98550-20-0 C7H6N4OS2
    6-methylsulfanyl-2-thioxo-2,3-dihydro-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one
    —— 2-methyl-6-(methylthio)pyrimido[5,4-d]pyrimidin-4(3H)-one 99584-34-6 C8H8N4OS
    2-methyl-6-(methylthio)pyrimido[5,4-d]pyrimidin-4(3H)-one
    —— 6-methylsulfanyl-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidine-2,4-dione 98550-25-5 C7H6N4O2S
    6-methylsulfanyl-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidine-2,4-dione
    —— 1-chloro-3-phenyl-2-propynyl phenyl sulfide 153940-38-6 C15H11ClS
    1-chloro-3-phenyl-2-propynyl phenyl sulfide
    —— 5-(2-fluoro-phenyl)-3-methylsulfanyl-[1,2,4]triazine 71347-51-8 C10H8FN3S
    5-(2-fluoro-phenyl)-3-methylsulfanyl-[1,2,4]triazine
    —— 4-[1,3-Bis[(1-butylpyridin-1-ium-4-yl)sulfanyl]propan-2-ylsulfanyl]-1-butylpyridin-1-ium;triiodide 446242-10-0 C30H44I3N3S3
    4-[1,3-Bis[(1-butylpyridin-1-ium-4-yl)sulfanyl]propan-2-ylsulfanyl]-1-butylpyridin-1-ium;triiodide
    —— 2-phenylethynyl-1,3-benzdithiole 131549-16-1 C15H10S2
    2-phenylethynyl-1,3-benzdithiole
    —— 1,1,2-tris(methylthio)-2-(ethylthio)ethylene 87373-96-4 C7H14S4
    1,1,2-tris(methylthio)-2-(ethylthio)ethylene
    —— (E)-1-(methylthio)-2-(ethylthio)ethylene 87373-94-2 C5H10S2
    (E)-1-(methylthio)-2-(ethylthio)ethylene
    —— 3-heptanamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172470-01-8 C21H28N2O2S
    3-heptanamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 3-formamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-98-6 C15H16N2O2S
    3-formamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— Carbamic acid, (4-((3,5-dimethylphenyl)thio)-1,2-dihydro-5-methyl-2-oxo-3-pyridinyl)-, ethyl ester 172469-69-1 C17H20N2O3S
    Carbamic acid, (4-((3,5-dimethylphenyl)thio)-1,2-dihydro-5-methyl-2-oxo-3-pyridinyl)-, ethyl ester
    —— 2-(4-chlorophenylthio)-3-phenylpropanal 1383467-76-2 C15H13ClOS
    2-(4-chlorophenylthio)-3-phenylpropanal
    —— 3-acetamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-99-7 C16H18N2O2S
    3-acetamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 3-amino-5-ethyl-4-(3', 5'-dimethylphenyl) thio-pyridin-2(1H)-one 172469-93-1 C15H18N2OS
    3-amino-5-ethyl-4-(3', 5'-dimethylphenyl) thio-pyridin-2(1H)-one
    —— 2-(4-bromophenylthio)-3-phenylpropanal 1383467-75-1 C15H13BrOS
    2-(4-bromophenylthio)-3-phenylpropanal
    —— 5-methyl-3-phenylacetamido-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172470-02-9 C22H22N2O2S
    5-methyl-3-phenylacetamido-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 5-ethyl-3-nitro-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-77-1 C15H16N2O3S
    5-ethyl-3-nitro-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 6-[(4-methylphenyl)sulfanyl]-2,4-diaminopyrimidine 606964-84-5 C11H12N4S
    6-[(4-methylphenyl)sulfanyl]-2,4-diaminopyrimidine
    —— 6-(phenylsulfanyl)pyrimidine-2,4-diamine 73119-72-9 C10H10N4S
    6-(phenylsulfanyl)pyrimidine-2,4-diamine
    —— 6-(benzylsulfanyl)-2,4-diaminopyrimidine 99864-74-1 C11H12N4S
    6-(benzylsulfanyl)-2,4-diaminopyrimidine
    —— 3-phenyl-2-phenylthio-propionaldehyde 55064-98-7 C15H14OS
    3-phenyl-2-phenylthio-propionaldehyde