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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-nitro-4-phenylsulfanyl-aniline 33358-38-2 C12H10N2O2S
    3-nitro-4-phenylsulfanyl-aniline
    —— 4-chloro-6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidine 56032-34-9 C7H8ClN3O3S
    4-chloro-6-ethoxy-2-methylsulfanyl-5-nitro-pyrimidine
    —— (-)-2-Phenylsulfanyl-(1R)-(2-pyridynyl)ethyl (1'S,4'R)-camphanoate 375367-65-0 C23H25NO4S
    (-)-2-Phenylsulfanyl-(1R)-(2-pyridynyl)ethyl (1'S,4'R)-camphanoate
    —— 4-(6-chloro-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1-oxide 56032-66-7 C9H11ClN4O3S2
    4-(6-chloro-2-methylsulfanyl-5-nitro-pyrimidin-4-yl)-thiomorpholine 1-oxide
    —— (+)-2-Phenylsulfanyl-(1S)-(2-pyridynyl)ethyl (1'S,4'R)-camphanoate 375367-66-1 C23H25NO4S
    (+)-2-Phenylsulfanyl-(1S)-(2-pyridynyl)ethyl (1'S,4'R)-camphanoate
    —— 8-methyl-3,4-dihydro-2H,6H-pyrimido<2,1-b><1.3>thiazin-6-one 22874-49-3 C8H10N2OS
    8-methyl-3,4-dihydro-2H,6H-pyrimido<2,1-b><1.3>thiazin-6-one
    —— 2-[[4-[(4-Aminophenyl)methyl]-5-butyl-1,2,4-triazol-3-yl]sulfanyl]ethanol 134402-60-1 C15H22N4OS
    2-[[4-[(4-Aminophenyl)methyl]-5-butyl-1,2,4-triazol-3-yl]sulfanyl]ethanol
    —— 4-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]butanol 135967-29-2 C20H32O3S
    4-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]butanol
    —— (1RS,2SR,5SR,8RS)-8-methoxy-6,6-dimethyl-2-phenylthio-1-(2-propenyl)bicyclo<3.2.1>octan-3-one 128004-79-5 C20H26O2S
    (1RS,2SR,5SR,8RS)-8-methoxy-6,6-dimethyl-2-phenylthio-1-(2-propenyl)bicyclo<3.2.1>octan-3-one
    —— <i>S</i>-undecyl-isothiourea 75275-48-8 C12H26N2S
    <i>S</i>-undecyl-isothiourea
    —— 3-Isopropyl-2-nitro-2-p-tolylsulfanyl-oxirane 168135-88-4 C12H15NO3S
    3-Isopropyl-2-nitro-2-p-tolylsulfanyl-oxirane
    —— 3-(2-aminoethylthio)-4-methylhex-3-enenitrile 116547-81-0 C9H16N2S
    3-(2-aminoethylthio)-4-methylhex-3-enenitrile
    —— 3-(2-Pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-30-3 C16H19NS2
    3-(2-Pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— Methyl 2-(4-methoxy-3,3-dimethyl-1-cyclohexenyl)dithioacetate 111916-86-0 C12H20OS2
    Methyl 2-(4-methoxy-3,3-dimethyl-1-cyclohexenyl)dithioacetate
    —— 2,2,5,5-tetramethyl-3-cyclopentenethione 81396-39-6 C9H14S
    2,2,5,5-tetramethyl-3-cyclopentenethione
    —— (E)-1-phenylsulfanyl-1-tributylstannyl-1-hexene 137782-88-8 C24H42SSn
    (E)-1-phenylsulfanyl-1-tributylstannyl-1-hexene
    —— (Z,Z)-6-Ethyl-4,5,7-trithiadeca-2,8-diene 144304-14-3 C9H16S3
    (Z,Z)-6-Ethyl-4,5,7-trithiadeca-2,8-diene
    —— undecylsulfanyl cyanate 32446-42-7 C12H23NS
    undecylsulfanyl cyanate
    —— 2-Hydroxy-5-methylsulfanyl-dithiobenzoic acid methyl ester 116138-52-4 C9H10OS3
    2-Hydroxy-5-methylsulfanyl-dithiobenzoic acid methyl ester
    —— 1-((S)-2,3-Diazido-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one 208513-41-1 C9H12N8OS
    1-((S)-2,3-Diazido-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one
    —— Methyl 2,2-dimethyl-3-butynedithioate 79566-76-0 C7H10S2
    Methyl 2,2-dimethyl-3-butynedithioate
    —— 4-(1H-benzimidazol-2-ylsulfanyl)-5-tert-butylbenzene-1,2-diol 1436419-98-5 C17H18N2O2S
    4-(1H-benzimidazol-2-ylsulfanyl)-5-tert-butylbenzene-1,2-diol
    —— 2-furyl-2-n-undecyl-1,3-dithiane 885480-75-1 C19H32OS2
    2-furyl-2-n-undecyl-1,3-dithiane
    —— 4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfide 68974-04-9 C48H74O2SSn2
    4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfide
    —— 1-Chloro-4-(1-chloro-1-methyl-ethylsulfanyl)-benzene 144265-58-7 C9H10Cl2S
    1-Chloro-4-(1-chloro-1-methyl-ethylsulfanyl)-benzene
    —— 6-Phenylsulfanyl-hexan-2-one 172419-22-6 C12H16OS
    6-Phenylsulfanyl-hexan-2-one
    —— (3R)-3-t-butyldimethylsilyloxy-1-(phenylthio)-1-butene 120787-38-4 C16H26OSSi
    (3R)-3-t-butyldimethylsilyloxy-1-(phenylthio)-1-butene
    —— 1,6-Dibutylmercaptohexan 13344-04-2 C14H30S2
    1,6-Dibutylmercaptohexan
    —— O-ethyl S-1-methoxyhexane-3-yl carbonothioate 1241905-19-0 C10H20O3S
    O-ethyl S-1-methoxyhexane-3-yl carbonothioate
    —— Benzene, 1-methyl-4-[[2-phenyl-1-(phenylthio)ethenyl]thio]-, (E)- 104411-47-4 C21H18S2
    Benzene, 1-methyl-4-[[2-phenyl-1-(phenylthio)ethenyl]thio]-, (E)-
    —— 11-(2-hexyl-[1,3]dithian-2-yl)-1-(tert-butyldimethylsiloxy)undec-4-yne 386742-86-5 C27H52OS2Si
    11-(2-hexyl-[1,3]dithian-2-yl)-1-(tert-butyldimethylsiloxy)undec-4-yne
    —— 2-(1-pyrrolidinyl)-3-phenylthiopropionitrile 111248-41-0 C13H16N2S
    2-(1-pyrrolidinyl)-3-phenylthiopropionitrile
    —— (6-isopropylsulfanylpyridin-2-yl)methanol 1609289-20-4 C9H13NOS
    (6-isopropylsulfanylpyridin-2-yl)methanol
    —— 1,11-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]undecane 390800-00-7 C25H30N6S4
    1,11-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]undecane
    —— 3-hydroxy-2'-nitrodiphenyl sulphide 76039-59-3 C12H9NO3S
    3-hydroxy-2'-nitrodiphenyl sulphide
    —— Tetraethyl sulfanediyldibenzene-4,1-diyl bis(phosphate) 19875-86-6 C20H28O8P2S
    Tetraethyl sulfanediyldibenzene-4,1-diyl bis(phosphate)
    —— 2,5,2',5'-tetra(dimethylaminemethylene)bis(4-hydroxyphenyl)sulfide 912474-60-3 C24H38N4O2S
    2,5,2',5'-tetra(dimethylaminemethylene)bis(4-hydroxyphenyl)sulfide
    —— Tert-butyl [4-[4-[(2-methylpropan-2-yl)oxycarbonyloxy]phenyl]sulfanylphenyl] carbonate 138888-97-8 C22H26O6S
    Tert-butyl [4-[4-[(2-methylpropan-2-yl)oxycarbonyloxy]phenyl]sulfanylphenyl] carbonate
    —— 4,4'-thiodiphenyl dipropiolate 117583-42-3 C18H10O4S
    4,4'-thiodiphenyl dipropiolate
    —— 1,1,3,3-tetramethyl-2-(thiocarbonyl)cyclohexane S-oxide 63702-87-4 C11H18OS
    1,1,3,3-tetramethyl-2-(thiocarbonyl)cyclohexane S-oxide
    —— 2-hydroxy-3-[4-({4-[2-hydroxy-3-(prop-2-enoyloxy)propoxy]phenyl}sulfanyl)phenoxy]propyl prop-2-enoate 1238889-15-0 C24H26O8S
    2-hydroxy-3-[4-({4-[2-hydroxy-3-(prop-2-enoyloxy)propoxy]phenyl}sulfanyl)phenoxy]propyl prop-2-enoate
    —— 2,2'-dimethylaminemethylenebis(4-hydroxyphenyl)sulfide 912474-40-9 C18H24N2O2S
    2,2'-dimethylaminemethylenebis(4-hydroxyphenyl)sulfide
    —— thiobis(4,1-phenylene) diacetate 63449-96-7 C16H14O4S
    thiobis(4,1-phenylene) diacetate
    —— 2,3,5,6,8,10-Hexathiaundecane 423765-80-4 C5H12S6
    2,3,5,6,8,10-Hexathiaundecane
    —— 2,6,2',6'-tetrabromo-4,4'-sulfanediyl-di-phenol 40654-51-1 C12H6Br4O2S
    2,6,2',6'-tetrabromo-4,4'-sulfanediyl-di-phenol
    —— 4,4'-bis-(Tributylstannoxy)-diphenylsulfide 68963-84-8 C36H62O2SSn2
    4,4'-bis-(Tributylstannoxy)-diphenylsulfide
    —— 8-Isothiocyanatooctan-1-ol 1037167-37-5 C9H17NOS
    8-Isothiocyanatooctan-1-ol
    —— 4,4'-thiodiphenol diallyl ether 99873-56-0 C18H18O2S
    4,4'-thiodiphenol diallyl ether
    —— (3Z,7Z,9Z)-7,10-Bis-(2-trimethylsilanyl-ethylsulfanyl)-trideca-1,3,7,9-tetraene-5,11-diyne 218444-55-4 C23H36S2Si2
    (3Z,7Z,9Z)-7,10-Bis-(2-trimethylsilanyl-ethylsulfanyl)-trideca-1,3,7,9-tetraene-5,11-diyne
    —— tetrakis(2,6-di-t-butyl-4-methylphenyl) 4,4'-thiobisphenyl diphosphite 104082-83-9 C72H100O6P2S
    tetrakis(2,6-di-t-butyl-4-methylphenyl) 4,4'-thiobisphenyl diphosphite