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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— isothioquinanthrene 50634-26-9 C18H10N2S2
    isothioquinanthrene
    —— 2,4,7,9-Tetraphenyl-1,6-dithia-3,8-diazaspiro<4.4>nonan 50650-57-2 C29H26N2S2
    2,4,7,9-Tetraphenyl-1,6-dithia-3,8-diazaspiro<4.4>nonan
    —— Trimethyl-(3-phenylsulfanyl-propyl)-stannane 35935-24-1 C12H20SSn
    Trimethyl-(3-phenylsulfanyl-propyl)-stannane
    —— 3-(4-Bromo-phenyl)-4-phenylsulfanylmethyl-isoxazole 76164-62-0 C16H12BrNOS
    3-(4-Bromo-phenyl)-4-phenylsulfanylmethyl-isoxazole
    —— 4-Methyl-3-phenyl-5-aethylmercapto-isooxazol 13626-90-9 C12H13NOS
    4-Methyl-3-phenyl-5-aethylmercapto-isooxazol
    —— O-(1-isopropoxy-2,2-dimethylvinyl) S-ethyl dithiocarbonate 123330-29-0 C10H18O2S2
    O-(1-isopropoxy-2,2-dimethylvinyl) S-ethyl dithiocarbonate
    —— 1-methylsulfinyl-1-(methylthio)cyclopropane 57260-89-6 C5H10OS2
    1-methylsulfinyl-1-(methylthio)cyclopropane
    —— 2-Methyl-2,3,5,6,7,8-hexahydro-1lambda~6~,4lambda~6~-benzodithiine-1,1,4,4-tetrone 55789-54-3 C9H14O4S2
    2-Methyl-2,3,5,6,7,8-hexahydro-1lambda~6~,4lambda~6~-benzodithiine-1,1,4,4-tetrone
    —— bis(nicotinoyl)-4,4'-thiodiphenolate 941571-87-5 C24H16N2O4S
    bis(nicotinoyl)-4,4'-thiodiphenolate
    —— O-(isopropoxycyclopentylidenemethyl) S-ethyl dithiocarbonate 123311-32-0 C12H20O2S2
    O-(isopropoxycyclopentylidenemethyl) S-ethyl dithiocarbonate
    —— 7,9-Dimethyl-1,4-dioxa-7,9-diazacycloundecane-8-thione 89863-07-0 C9H18N2O2S
    7,9-Dimethyl-1,4-dioxa-7,9-diazacycloundecane-8-thione
    —— 3-Methyl-4-phenyl-5-aethylmercapto-isooxazol 13626-91-0 C12H13NOS
    3-Methyl-4-phenyl-5-aethylmercapto-isooxazol
    —— O-(isopropoxycyclohexylidenemethyl) S-ethyl dithiocarbonate 123311-34-2 C13H22O2S2
    O-(isopropoxycyclohexylidenemethyl) S-ethyl dithiocarbonate
    —— 2-Ethyl-4a,5,6,7,8,8a-hexahydro-1,4-benzodithiine 55789-70-3 C10H16S2
    2-Ethyl-4a,5,6,7,8,8a-hexahydro-1,4-benzodithiine
    —— 5-(4-chloro-phenylsulfanyl)-2-nitro-pyridine 77012-86-3 C11H7ClN2O2S
    5-(4-chloro-phenylsulfanyl)-2-nitro-pyridine
    —— S,S'-<2,2'-dithiobis(nitropyridyl)>bis(N,N-dimethylcarbamothioate) 81606-01-1 C16H16N6O6S4
    S,S'-<2,2'-dithiobis(nitropyridyl)>bis(N,N-dimethylcarbamothioate)
    —— 4-PHENYLTHIOCYCLOHEXYLAMINE 321597-32-4 C12H17NS
    4-PHENYLTHIOCYCLOHEXYLAMINE
    —— 2-Methyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine 55789-64-5 C9H14S2
    2-Methyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine
    —— 2-ethyl-2,3-dihydro-5-methyl-1,4-dithiin 1,1,4,4-tetroxide 58951-11-4 C7H12O4S2
    2-ethyl-2,3-dihydro-5-methyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 1,3-Di-(p-tolylthio)-azulen 61035-79-8 C24H20S2
    1,3-Di-(p-tolylthio)-azulen
    —— 2,3-dihydro-2,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide 58951-07-8 C6H10O4S2
    2,3-dihydro-2,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 2-ethyl-5,6-dihydro-3-methyl-1,4-dithiin 1,1,4,4-tetroxide 55789-52-1 C7H12O4S2
    2-ethyl-5,6-dihydro-3-methyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 2,3-dihydro-2,3,5,6-tetramethyl-1,4-dithiin 1,1,4,4-tetroxide 55789-57-6 C8H14O4S2
    2,3-dihydro-2,3,5,6-tetramethyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 2,6-Diethyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone 58951-18-1 C8H14O4S2
    2,6-Diethyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone
    —— 2-ethyl-4a,5,6,7,8,8a-hexahydro-1,4-benzodithiin 1,1,4,4-tetroxide 55789-61-2 C10H16O4S2
    2-ethyl-4a,5,6,7,8,8a-hexahydro-1,4-benzodithiin 1,1,4,4-tetroxide
    —— 2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine 55789-68-9 C10H16S2
    2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine
    —— 5-Ethyl-2,6-dimethyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone 58951-29-4 C8H14O4S2
    5-Ethyl-2,6-dimethyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone
    —— 5-[4-(2-methylbutan-2-yl)phenyl]sulfanyl-2-oxo-1H-pyridine-3-carbonitrile 1426959-51-4 C17H18N2OS
    5-[4-(2-methylbutan-2-yl)phenyl]sulfanyl-2-oxo-1H-pyridine-3-carbonitrile
    —— 5-(4-bromophenyl)sulfanyl-2-oxo-1H-pyridine-3-carbonitrile 1426959-52-5 C12H7BrN2OS
    5-(4-bromophenyl)sulfanyl-2-oxo-1H-pyridine-3-carbonitrile
    —— 2-ethyl-5,6-dihydro-6-methyl-1,4-dithiin 1,1,4,4-tetroxide 58951-16-9 C7H12O4S2
    2-ethyl-5,6-dihydro-6-methyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 5-(4-aminophenyl)sulfanyl-2-oxo-1H-pyridine-3-carbonitrile 1426959-53-6 C12H9N3OS
    5-(4-aminophenyl)sulfanyl-2-oxo-1H-pyridine-3-carbonitrile
    —— 5-(4-methylphenyl)sulfanyl-2-oxo-1H-pyridine-3-carbonitrile 1426959-49-0 C13H10N2OS
    5-(4-methylphenyl)sulfanyl-2-oxo-1H-pyridine-3-carbonitrile
    —— 2-oxo-5-phenylsulfanyl-1H-pyridine-3-carbonitrile 1426959-48-9 C12H8N2OS
    2-oxo-5-phenylsulfanyl-1H-pyridine-3-carbonitrile
    —— 2,6-diethyl-2,3-dihydro-1,4-dithiin 61947-26-0 C8H14S2
    2,6-diethyl-2,3-dihydro-1,4-dithiin
    —— 2-ethyl-2,3-dihydro-6-methyl-1,4-dithiin 61947-24-8 C7H12S2
    2-ethyl-2,3-dihydro-6-methyl-1,4-dithiin
    —— 1-Benzyl-2-oxo-5-(4-propan-2-ylphenyl)sulfanylpyridine-3-carbonitrile 1426959-55-8 C22H20N2OS
    1-Benzyl-2-oxo-5-(4-propan-2-ylphenyl)sulfanylpyridine-3-carbonitrile
    —— 2-ethyl-2,3-dihydro-5,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide 55789-56-5 C8H14O4S2
    2-ethyl-2,3-dihydro-5,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 2-oxo-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carbonitrile 1426959-50-3 C15H14N2OS
    2-oxo-5-(4-propan-2-ylphenyl)sulfanyl-1H-pyridine-3-carbonitrile
    —— 2,5-diethyl-2,3-dihydro-1,4-dithiin 61947-25-9 C8H14S2
    2,5-diethyl-2,3-dihydro-1,4-dithiin
    —— 2,3-dihydro-2,5,6-trimethyl-1,4-dithiin 1,1,4,4-tetroxide 55789-53-2 C7H12O4S2
    2,3-dihydro-2,5,6-trimethyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 2-Ethyl-6-methyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone 58951-10-3 C7H12O4S2
    2-Ethyl-6-methyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone
    —— methyl (3-ethylthio-1,2,4-triazol-5-yl)aminodithiocarbonate 131023-10-4 C6H10N4S3
    methyl (3-ethylthio-1,2,4-triazol-5-yl)aminodithiocarbonate
    —— 2,5-diethyl-2,3-dihydro-1,4-dithiin 1,1,4,4-tetroxide 58951-19-2 C8H14O4S2
    2,5-diethyl-2,3-dihydro-1,4-dithiin 1,1,4,4-tetroxide
    —— 2-ethyl-5,6-dihydro-5,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide 55789-58-7 C8H14O4S2
    2-ethyl-5,6-dihydro-5,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 2-ethyl-5,6-dihydro-3,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide 58951-28-3 C8H14O4S2
    2-ethyl-5,6-dihydro-3,6-dimethyl-1,4-dithiin 1,1,4,4-tetroxide
    —— 5-Ethyl-2-methyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone 58951-17-0 C7H12O4S2
    5-Ethyl-2-methyl-2,3-dihydro-1lambda~6~,4lambda~6~-dithiine-1,1,4,4-tetrone
    —— methyl <3-(2-methylethylthio)-1,2,4-triazol-5-yl>aminodithiocarbonate 131023-11-5 C7H12N4S3
    methyl <3-(2-methylethylthio)-1,2,4-triazol-5-yl>aminodithiocarbonate
    —— Dimethyl-sulphoxyliden-harnstoff 1520-15-6 C3H8N2O2S
    Dimethyl-sulphoxyliden-harnstoff
    —— 1-Methyl-5-phenylsulfanyl-1H-[1,2,3]triazole 194209-21-7 C9H9N3S
    1-Methyl-5-phenylsulfanyl-1H-[1,2,3]triazole
    —— 2,2-Dimethyl-propionic acid 1-ethoxythiocarbonylsulfanyl-3-methyl-4-oxo-pentyl ester 517867-32-2 C14H24O4S2
    2,2-Dimethyl-propionic acid 1-ethoxythiocarbonylsulfanyl-3-methyl-4-oxo-pentyl ester