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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— bis(4-(benzyloxy)phenyl)sulfane 98985-98-9 C26H22O2S
    bis(4-(benzyloxy)phenyl)sulfane
    —— 3-(1-Ethyl-1-methyl-pentyl)-6-methylsulfanyl-[1,2,4,5]tetrazine 159801-94-2 C11H20N4S
    3-(1-Ethyl-1-methyl-pentyl)-6-methylsulfanyl-[1,2,4,5]tetrazine
    —— (heptane-1-sulfinyl)-ethene 21961-09-1 C9H18OS
    (heptane-1-sulfinyl)-ethene
    —— 2-methylthio-6-[(1'-carboxyethyl)methan-1'-yl]-4(3H)-pyrimidinone 251347-70-3 C9H12N2O3S
    2-methylthio-6-[(1'-carboxyethyl)methan-1'-yl]-4(3H)-pyrimidinone
    —— 2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol 51543-47-6 C12H6Cl4O2S
    2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol
    —— Propenyldithioacetat 67230-78-8 C5H8S2
    Propenyldithioacetat
    —— dithiopropionic acid prop-2-ynyl ester 41830-44-8 C6H8S2
    dithiopropionic acid prop-2-ynyl ester
    —— tributyl-[3-(4-methylphenyl)sulfanylprop-1-enyl]stannane 155197-76-5 C22H38SSn
    tributyl-[3-(4-methylphenyl)sulfanylprop-1-enyl]stannane
    —— 2-methylthio-6-[(2'-hydroxy)ethan-1'-yl]-4(3H)-pyrimidinone 251347-72-5 C7H10N2O2S
    2-methylthio-6-[(2'-hydroxy)ethan-1'-yl]-4(3H)-pyrimidinone
    —— N-(2,5-Dimethyl-2H-pyrazol-3-yl)-2-{3-[1-hydroxy-meth-(Z)-ylidene]-2-oxo-2,3-dihydro-1H-indol-6-ylsulfanyl}-benzamide 919103-52-9 C21H18N4O3S
    N-(2,5-Dimethyl-2H-pyrazol-3-yl)-2-{3-[1-hydroxy-meth-(Z)-ylidene]-2-oxo-2,3-dihydro-1H-indol-6-ylsulfanyl}-benzamide
    —— 4-allylsulfanyl-3-methyl-4-methylsulfanyl-pent-1-ene 62418-91-1 C10H18S2
    4-allylsulfanyl-3-methyl-4-methylsulfanyl-pent-1-ene
    —— 4-but-2-enylsulfanyl-4-methylsulfanyl-pent-1-ene 62418-92-2 C10H18S2
    4-but-2-enylsulfanyl-4-methylsulfanyl-pent-1-ene
    —— 4-allylsulfanyl-3,3-dimethyl-4-methylsulfanyl-pent-1-ene 66312-52-5 C11H20S2
    4-allylsulfanyl-3,3-dimethyl-4-methylsulfanyl-pent-1-ene
    —— (2Z,4Z)-2,5-bis(tert-butylsulfanyl)hexa-2,4-diene-1,6-diol 186499-98-9 C14H26O2S2
    (2Z,4Z)-2,5-bis(tert-butylsulfanyl)hexa-2,4-diene-1,6-diol
    —— allyl 2-methylpropanedithioate 63881-54-9 C7H12S2
    allyl 2-methylpropanedithioate
    —— allylsulfanyl isopropyl thioketone oxide 162336-77-8 C7H12OS2
    allylsulfanyl isopropyl thioketone oxide
    —— 1-(5-amino-pyridin-2-yl)-2-[2-(dimethylamino)benzylthio]imidazole 117296-28-3 C17H19N5S
    1-(5-amino-pyridin-2-yl)-2-[2-(dimethylamino)benzylthio]imidazole
    —— ((S)-8-Azido-1,4-dithia-spiro[4.4]non-6-en-6-ylmethoxy)-tert-butyl-dimethyl-silane 154375-19-6 C14H25N3OS2Si
    ((S)-8-Azido-1,4-dithia-spiro[4.4]non-6-en-6-ylmethoxy)-tert-butyl-dimethyl-silane
    —— 4-isopropylthio-7-methyl-4-methylthio-5-(1-propen-2-yl)-1,7-octadiene —— C16H28S2
    4-isopropylthio-7-methyl-4-methylthio-5-(1-propen-2-yl)-1,7-octadiene
    —— 2,3-dibutylthiobutyraldehyde 108431-30-7 C12H24OS2
    2,3-dibutylthiobutyraldehyde
    —— 4-(4-methylsulfanylphenyl)-2H-1,2-oxazol-5-one 259543-69-6 C10H9NO2S
    4-(4-methylsulfanylphenyl)-2H-1,2-oxazol-5-one
    —— 2-n-Propyloxy-1,3-benzodithiolan 55315-54-3 C10H12OS2
    2-n-Propyloxy-1,3-benzodithiolan
    —— N-{[4-(4-methylthiophenyl)-5-oxo-2-hydroisoxazol-2-yl]methyl}acetamide 259542-29-5 C13H14N2O3S
    N-{[4-(4-methylthiophenyl)-5-oxo-2-hydroisoxazol-2-yl]methyl}acetamide
    —— {2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}(4-methylphenyl)methanol 607708-13-4 C20H17Cl2NOS
    {2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}(4-methylphenyl)methanol
    —— 9,14-diphenyl-6,7,8,9,14,15,16,17-octahydro-5,18-dithia-9,14-diphospha-dibenzo[<i>a</i>,<i>h</i>]cyclotetradecene 78339-70-5 C30H30P2S2
    9,14-diphenyl-6,7,8,9,14,15,16,17-octahydro-5,18-dithia-9,14-diphospha-dibenzo[<i>a</i>,<i>h</i>]cyclotetradecene
    —— isothiocyanic acid 1-cyclopentanecarbonyl ester 1154366-71-8 C7H9NOS
    isothiocyanic acid 1-cyclopentanecarbonyl ester
    —— dimethyl-dithiocarbamic acid 1-methylsulfanyl-hexyl ester 53799-81-8 C10H21NS3
    dimethyl-dithiocarbamic acid 1-methylsulfanyl-hexyl ester
    —— 2-(2-chlorophenyl)-2,3-dihydrobenzo[b]thiophene 1254175-16-0 C14H11ClS
    2-(2-chlorophenyl)-2,3-dihydrobenzo[b]thiophene
    —— 3-(Diphenyl-phosphinoyl)-3-(5-phenylsulfanyl-cyclopent-1-enyl)-butan-2-ol 64894-39-9 C27H29O2PS
    3-(Diphenyl-phosphinoyl)-3-(5-phenylsulfanyl-cyclopent-1-enyl)-butan-2-ol
    —— 4-amino-5-cyano-2,6-dimethylthio-pyrimidine 98277-53-3 C7H8N4S2
    4-amino-5-cyano-2,6-dimethylthio-pyrimidine
    —— 4-Hydroxy-5-phenylsulfanyl-4-(phenylsulfanylmethyl)pentan-2-one 1029128-81-1 C18H20O2S2
    4-Hydroxy-5-phenylsulfanyl-4-(phenylsulfanylmethyl)pentan-2-one
    —— 1,3-Bis(phenylsulfanyl)acetone oxime 187672-10-2 C15H15NOS2
    1,3-Bis(phenylsulfanyl)acetone oxime
    —— 2,2',<i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>'-hexamethyl-2,2'-thiocarbonyldiamino-bis-thiopropionamide 61796-35-8 C13H26N4S3
    2,2',<i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>'-hexamethyl-2,2'-thiocarbonyldiamino-bis-thiopropionamide
    —— 21,27,33,38-Tetratert-butyl-42,43-dihydroxy-3,17-dioxa-7,9,11,13-tetrathiaheptacyclo[17.15.7.125,29.136,40.02,31.08,12.018,23]tritetraconta-1,8(12),18,20,22,25(43),26,28,31,33,36,38,40(42)-tridecaene-10-thione 863915-94-0 C53H66O4S5
    21,27,33,38-Tetratert-butyl-42,43-dihydroxy-3,17-dioxa-7,9,11,13-tetrathiaheptacyclo[17.15.7.125,29.136,40.02,31.08,12.018,23]tritetraconta-1,8(12),18,20,22,25(43),26,28,31,33,36,38,40(42)-tridecaene-10-thione
    —— (Z)-4-(dimethylamino)-1,3-bis(phenylsulfanyl)but-3-en-2-one 115413-29-1 C18H19NOS2
    (Z)-4-(dimethylamino)-1,3-bis(phenylsulfanyl)but-3-en-2-one
    —— 1-Methylsulfanyl-3,5-bis[(4-propan-2-yloxyphenyl)sulfanyl]benzene 213135-26-3 C25H28O2S3
    1-Methylsulfanyl-3,5-bis[(4-propan-2-yloxyphenyl)sulfanyl]benzene
    —— 2-methyl-but-3-enedithioic acid methyl ester 69079-28-3 C6H10S2
    2-methyl-but-3-enedithioic acid methyl ester
    —— 1,3-Bis(phenylthio)-5,7-diazaadamantan-2-one 78693-62-6 C20H20N2OS2
    1,3-Bis(phenylthio)-5,7-diazaadamantan-2-one
    —— methyl 2-ethenyl-2-methyl-4-pentenedithioate 107094-83-7 C9H14S2
    methyl 2-ethenyl-2-methyl-4-pentenedithioate
    —— (E)-4-(3-phenylsulfanyl-1H-indol-2-yl)but-3-en-2-one 148404-04-0 C18H15NOS
    (E)-4-(3-phenylsulfanyl-1H-indol-2-yl)but-3-en-2-one
    —— methyl 4-methyl-2-(propen-2-yl)-4-pentenedithioate 107094-88-2 C10H16S2
    methyl 4-methyl-2-(propen-2-yl)-4-pentenedithioate
    —— prop-1-enyl propanedithioate 65901-84-0 C6H10S2
    prop-1-enyl propanedithioate
    —— O-(But-3-en-1-yl) S-methyl dithiocarbonate 89489-35-0 C6H10OS2
    O-(But-3-en-1-yl) S-methyl dithiocarbonate
    —— 2,5,5-trimethyl-4,4-bis-methylsulfanyl-hepta-1,6-diene 69079-36-3 C12H22S2
    2,5,5-trimethyl-4,4-bis-methylsulfanyl-hepta-1,6-diene
    —— (2-Hydroxy-phenylsulfanyl)-acetic acid ethyl ester 20277-05-8 C10H12O3S
    (2-Hydroxy-phenylsulfanyl)-acetic acid ethyl ester
    —— methyl 2-(propen-2-yl)-4-pentenedithioate 107094-87-1 C9H14S2
    methyl 2-(propen-2-yl)-4-pentenedithioate
    —— dithiopropionic acid allyl ester 41830-43-7 C6H10S2
    dithiopropionic acid allyl ester
    —— 2,5 dimethyl-3-<(1-isopropylthio-1-methylthio)-1-pentyl>-1,5-hexadiene —— C17H32S2
    2,5 dimethyl-3-<(1-isopropylthio-1-methylthio)-1-pentyl>-1,5-hexadiene
    —— 2,5 dimethyl-3-(isopropylthiomethylthio) methyl-1,5-hexadiene —— C13H24S2
    2,5 dimethyl-3-(isopropylthiomethylthio) methyl-1,5-hexadiene
    —— O-(1-isopropoxy-2,2-dimethylvinyl) S-methyl dithiocarbonate 123311-27-3 C9H16O2S2
    O-(1-isopropoxy-2,2-dimethylvinyl) S-methyl dithiocarbonate