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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— <tert-Butylthio(thiocarbonyloxy)>essigsaeure 82979-46-2 C7H12O3S2
    <tert-Butylthio(thiocarbonyloxy)>essigsaeure
    —— 9-(2-Isopropoxy-ethyl)-8-(3-methoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-51-4 C17H21N5O2S
    9-(2-Isopropoxy-ethyl)-8-(3-methoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 4-Ethoxy-2-ethylmercapto-5-methyl-pyrimidin 99516-33-3 C9H14N2OS
    4-Ethoxy-2-ethylmercapto-5-methyl-pyrimidin
    —— 9-butyl-8-(3-methoxy-phenylsulfanyl)adenine 521308-36-1 C16H19N5OS
    9-butyl-8-(3-methoxy-phenylsulfanyl)adenine
    —— 9-Pent-4-ynyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-48-9 C19H21N5O3S
    9-Pent-4-ynyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 9-(2-Isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-54-7 C19H25N5O4S
    9-(2-Isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 8-(3,4,5-trimethoxy-phenylsulfanyl)adenine 827302-37-4 C14H15N5O3S
    8-(3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— 9-butyl-8-(2,5-dimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 521308-37-2 C17H21N5O2S
    9-butyl-8-(2,5-dimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 2-methylthio-3-phenylthiophene 72946-77-1 C11H10S2
    2-methylthio-3-phenylthiophene
    —— 8-(phenylthio)-9H-purin-6-amine 908117-27-1 C11H9N5S
    8-(phenylthio)-9H-purin-6-amine
    —— cis-3-(phenylthio)prop-2-en-1-ol —— C9H10OS
    cis-3-(phenylthio)prop-2-en-1-ol
    —— tert-butyl 3-(4-bromophenylthio)azetidine-1-carboxylate 1002355-69-2 C14H18BrNO2S
    tert-butyl 3-(4-bromophenylthio)azetidine-1-carboxylate
    —— (E)-3-chloro-1-phenylthioprop-1-ene 52072-01-2 C9H9ClS
    (E)-3-chloro-1-phenylthioprop-1-ene
    —— 4-Methyl-3-(phenylthio)-pentan-2-on 27872-69-1 C12H16OS
    4-Methyl-3-(phenylthio)-pentan-2-on
    —— S-Methyl-S-(n-propyl) dithiocarbonate 10596-54-0 C5H10OS2
    S-Methyl-S-(n-propyl) dithiocarbonate
    —— 4-methylthio-5-heptyl-1,3-oxathiolene 129206-06-0 C11H20OS2
    4-methylthio-5-heptyl-1,3-oxathiolene
    —— 3-methyl-4-methylsulfanyl-buta-1,2-diene 23451-61-8 C6H10S
    3-methyl-4-methylsulfanyl-buta-1,2-diene
    —— 2-<<(p-bromophenyl)thio>methyl>-5-methylpyridine 83782-45-0 C13H12BrNS
    2-<<(p-bromophenyl)thio>methyl>-5-methylpyridine
    —— 6-methylthio-2-phenyl-1,3-diazin-4-one 87905-18-8 C11H10N2OS
    6-methylthio-2-phenyl-1,3-diazin-4-one
    —— 4-amino-1,6-dihydro-1-methyl-2-methylthio-5-nitroso-6-oxo-pyrimidine 42026-60-8 C6H8N4O2S
    4-amino-1,6-dihydro-1-methyl-2-methylthio-5-nitroso-6-oxo-pyrimidine
    —— [(2,2-Dichloro-1-phenylethenyl)sulfanyl]benzene 88649-72-3 C14H10Cl2S
    [(2,2-Dichloro-1-phenylethenyl)sulfanyl]benzene
    —— (1,4-Diphenyl-4-phenylsulfanylbuta-1,2,3-trienyl)sulfanylbenzene 88649-77-8 C28H20S2
    (1,4-Diphenyl-4-phenylsulfanylbuta-1,2,3-trienyl)sulfanylbenzene
    —— 3-Methyl-1-methylsulfanylcyclohexene 70871-34-0 C8H14S
    3-Methyl-1-methylsulfanylcyclohexene
    —— 2-methoxy-3-phenylsulfanyl-toluene 107774-39-0 C14H14OS
    2-methoxy-3-phenylsulfanyl-toluene
    —— N-[(1S)-2,2-difluoro-1-phenyl-2-phenylsulfanylethyl]prop-2-en-1-amine 938463-88-8 C17H17F2NS
    N-[(1S)-2,2-difluoro-1-phenyl-2-phenylsulfanylethyl]prop-2-en-1-amine
    —— phenyl(phenylthiomethylene)cyclohexane 107014-86-8 C19H20S
    phenyl(phenylthiomethylene)cyclohexane
    —— 3-(4-bromo-phenylsulfanylmethyl)-pyridine 83782-70-1 C12H10BrNS
    3-(4-bromo-phenylsulfanylmethyl)-pyridine
    —— heptyl 3,3,3-trifluoropropyl sulfide 139758-52-4 C10H19F3S
    heptyl 3,3,3-trifluoropropyl sulfide
    —— 2-(2-pyridylmethylthio)-5-(pyridine-4-yl)-1,3,4-oxadiazole 197371-72-5 C13H10N4OS
    2-(2-pyridylmethylthio)-5-(pyridine-4-yl)-1,3,4-oxadiazole
    —— (6aR,8S,9R,9aS)-8-phenylsulfanyl-2,2,4,4-tetra(propan-2-yl)-6a,8,9,9a-tetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocin-9-ol 262421-85-2 C23H40O5SSi2
    (6aR,8S,9R,9aS)-8-phenylsulfanyl-2,2,4,4-tetra(propan-2-yl)-6a,8,9,9a-tetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocin-9-ol
    —— 4-(3,3,3-trifluoropropylthiomethyl)cyclohexanemethanol 1233934-87-6 C11H19F3OS
    4-(3,3,3-trifluoropropylthiomethyl)cyclohexanemethanol
    —— 2-<<(p-bromophenyl)thio>methyl>-3-methoxypyridine 83782-41-6 C13H12BrNOS
    2-<<(p-bromophenyl)thio>methyl>-3-methoxypyridine
    —— 2-(4-Bromo-phenylsulfanylmethyl)-pyridin-3-ol; hydrochloride 83782-36-9 C12H10BrNOS*ClH
    2-(4-Bromo-phenylsulfanylmethyl)-pyridin-3-ol; hydrochloride
    —— 2-(4-methoxyphenylthio)-4,5-dimethylthiazole 1335609-18-1 C12H13NOS2
    2-(4-methoxyphenylthio)-4,5-dimethylthiazole
    —— (+/-)-(2S<sup>*</sup>, 3R<sup>*</sup>, 4S<sup>*</sup>, 5S<sup>*</sup>)-tetrahydro-2-isobutyl-4,5-dimethyl-3-(phenylthio)furan 80091-17-4 C16H24OS
    (+/-)-(2S<sup>*</sup>, 3R<sup>*</sup>, 4S<sup>*</sup>, 5S<sup>*</sup>)-tetrahydro-2-isobutyl-4,5-dimethyl-3-(phenylthio)furan
    —— 2-[4-(4-Nitrophenyl)sulfanylphenyl]acetonitrile 126585-04-4 C14H10N2O2S
    2-[4-(4-Nitrophenyl)sulfanylphenyl]acetonitrile
    —— Dimethyl [2-chloro-1-(phenylsulfanyl)ethyl]phosphonate 88691-17-2 C10H14ClO3PS
    Dimethyl [2-chloro-1-(phenylsulfanyl)ethyl]phosphonate
    —— 2-[4-(4-Aminophenyl)sulfanylphenyl]acetic acid 126585-16-8 C14H13NO2S
    2-[4-(4-Aminophenyl)sulfanylphenyl]acetic acid
    —— (4-chloro-6-dimethylamino-2-methylsulfanylpyrimidin-5-yl)(4-chlorophenyl)methanol 1393456-95-5 C14H15Cl2N3OS
    (4-chloro-6-dimethylamino-2-methylsulfanylpyrimidin-5-yl)(4-chlorophenyl)methanol
    —— 2-[4-(4-Nitrophenyl)sulfanylphenyl]acetic acid 126585-06-6 C14H11NO4S
    2-[4-(4-Nitrophenyl)sulfanylphenyl]acetic acid
    —— 4-chloro-6-dimethylamino-2-methylsulfanylpyrimidine-5-carboxaldehyde 445040-58-4 C8H10ClN3OS
    4-chloro-6-dimethylamino-2-methylsulfanylpyrimidine-5-carboxaldehyde
    —— trithiocarbonic acid S,S-bis(2-hydroxyethyl) ester 77705-13-6 C5H10O2S3
    trithiocarbonic acid S,S-bis(2-hydroxyethyl) ester
    —— (E)-5,5′-bis[5-(butylsulfanyl)thiophen-2-yl]-3,3′-bi[thiophen-3(2H)-ylidene]-2,2′-dione 1438289-31-6 C24H24O2S6
    (E)-5,5′-bis[5-(butylsulfanyl)thiophen-2-yl]-3,3′-bi[thiophen-3(2H)-ylidene]-2,2′-dione
    —— <2-<(phenylthio)methyl>allyl>trimethylsilane 116279-69-7 C13H20SSi
    <2-<(phenylthio)methyl>allyl>trimethylsilane
    —— 7-Chloro-2,3-dihydro-5-oxo-5H-thiazolo[3,2-a]pyrimidine-6-carbaldehyde 150892-75-4 C7H5ClN2O2S
    7-Chloro-2,3-dihydro-5-oxo-5H-thiazolo[3,2-a]pyrimidine-6-carbaldehyde
    —— tert-butyl 2-((4-chlorophenyl)thio)acetate 36304-20-8 C12H15ClO2S
    tert-butyl 2-((4-chlorophenyl)thio)acetate
    —— 2-Ethyl-1-hydroxybutane-2-thiol 159982-42-0 C6H14OS
    2-Ethyl-1-hydroxybutane-2-thiol
    —— 2-acetamido-3-phenylthio-octane 74491-59-1 C16H25NOS
    2-acetamido-3-phenylthio-octane
    —— 3-acetamido-2-phenylthio-octane 74491-60-4 C16H25NOS
    3-acetamido-2-phenylthio-octane
    —— 1-<bis(phenylthio)acetyl>-2-ethenylpyrrolidine 146405-62-1 C20H21NOS2
    1-<bis(phenylthio)acetyl>-2-ethenylpyrrolidine