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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(4-methoxy-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-yl)-aniline 21576-25-0 C13H12N4OS
    4-(4-methoxy-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-yl)-aniline
    —— 1,9,17-trithia-[2.2.2]orthocyclophane-2,10,18-trione 39264-06-7 C21H12O3S3
    1,9,17-trithia-[2.2.2]orthocyclophane-2,10,18-trione
    —— 4H-1,3-benzodithiin-4-one 1034249-74-5 C8H6OS2
    4H-1,3-benzodithiin-4-one
    —— 5,5'-disulfanediyldipentan-1-amine 15919-44-5 C10H24N2S2
    5,5'-disulfanediyldipentan-1-amine
    —— 6-(4-amino-phenyl)-4-methyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-2-ylamine 21576-23-8 C13H13N5S
    6-(4-amino-phenyl)-4-methyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-2-ylamine
    —— 3-(phenylthio)-2-methylenepropanal 86531-03-5 C10H10OS
    3-(phenylthio)-2-methylenepropanal
    —— 2,3-Dihydro-9-phenylthio-1H-pyrrolo[1,2-a]indol-1-one 143612-31-1 C17H13NOS
    2,3-Dihydro-9-phenylthio-1H-pyrrolo[1,2-a]indol-1-one
    —— 3-(phenylthio)-2-methylenepropionaldehyde diethyl acetal 401893-44-5 C14H20O2S
    3-(phenylthio)-2-methylenepropionaldehyde diethyl acetal
    —— 4-hydroxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-10-0 C8H8F3NO2S
    4-hydroxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— β-phenylthio-2,3-O-isopropylidene-D-ribofuranose 153362-34-6 C14H18O4S
    β-phenylthio-2,3-O-isopropylidene-D-ribofuranose
    —— 3-<4-(1-(methoxymethyl)-1H-2-(phenylthio)imidazol-5-yl)-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl>indole 219817-92-2 C23H18N4O3S
    3-<4-(1-(methoxymethyl)-1H-2-(phenylthio)imidazol-5-yl)-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl>indole
    —— (2RS,3SR)-ethyl N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>carbamate 127940-94-7 C19H29NO3S
    (2RS,3SR)-ethyl N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>carbamate
    —— 4-methoxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-11-1 C9H10F3NO2S
    4-methoxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— 2-Propan-2-ylsulfanyl-3-(2,2,2-trifluoroethoxy)pyridine 256473-05-9 C10H12F3NOS
    2-Propan-2-ylsulfanyl-3-(2,2,2-trifluoroethoxy)pyridine
    —— 1-<(benzyloxy)methyl>-6-(phenylthio)thymine 132774-43-7 C19H18N2O3S
    1-<(benzyloxy)methyl>-6-(phenylthio)thymine
    —— 5-({[4-(Butylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione 89000-14-6 C15H18N2O2S2
    5-({[4-(Butylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione
    —— 1,3-diaza-2-oxophenothiazine —— C10H7N3OS
    1,3-diaza-2-oxophenothiazine
    —— 4-methylthiomethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-13-3 C9H10F3NOS2
    4-methylthiomethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— 4,4'-bis(chloromethyl)diphenyl sulfide 1216-02-0 C14H12Cl2S
    4,4'-bis(chloromethyl)diphenyl sulfide
    —— 5-{[(Pyridin-2-yl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione 89000-16-8 C10H9N3O2S
    5-{[(Pyridin-2-yl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione
    —— 6-{[(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl]thio}-1,2,4-triazine-3,5(2H,4H)-dione 301208-18-4 C8H7N5O4S
    6-{[(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl]thio}-1,2,4-triazine-3,5(2H,4H)-dione
    —— 5-(4-bromophenylthiomethyl)uracil 89000-17-9 C11H9BrN2O2S
    5-(4-bromophenylthiomethyl)uracil
    —— 5-({[4-(Dimethylamino)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione 89000-15-7 C13H15N3O2S
    5-({[4-(Dimethylamino)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione
    —— 5-({[4-(Methylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione 89000-13-5 C12H12N2O2S2
    5-({[4-(Methylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione
    —— 5-{[(4-Fluorophenyl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione 89000-10-2 C11H9FN2O2S
    5-{[(4-Fluorophenyl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione
    —— 2-[2-(4-chlorophenylsulfanyl)prop-2-enyl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide 1000809-06-2 C14H18ClO3PS
    2-[2-(4-chlorophenylsulfanyl)prop-2-enyl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide
    —— 3-ethylthio-6-phenyl-1,2,4-triazine 117504-70-8 C11H11N3S
    3-ethylthio-6-phenyl-1,2,4-triazine
    —— 2-[6-amino-8-(7-chlorobenzothiazol-2-ylsulfanyl)-purin-9-yl]-ethanol 908355-56-6 C14H11ClN6OS2
    2-[6-amino-8-(7-chlorobenzothiazol-2-ylsulfanyl)-purin-9-yl]-ethanol
    —— acetic acid 2-[6-amino-8-(7-chlorobenzothiazol-2-ylsulfanyl)-purin-9-yl]-ethyl ester 908355-50-0 C16H13ClN6O2S2
    acetic acid 2-[6-amino-8-(7-chlorobenzothiazol-2-ylsulfanyl)-purin-9-yl]-ethyl ester
    —— 4-chloromethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-12-2 C8H7ClF3NOS
    4-chloromethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— 5-chloro-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-04-2 C7H5ClF3NOS
    5-chloro-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— 3,3'-bis(methylthio)-6,6'-bis-phenyl-5,5'-bi-1,2,4-triazine 83413-04-1 C20H16N6S2
    3,3'-bis(methylthio)-6,6'-bis-phenyl-5,5'-bi-1,2,4-triazine
    —— 7-methylsulfanyl-4-oxo-1,4-dihydro-pyrimido[4,5-<i>c</i>]pyridazine-3-carboxylic acid 55084-75-8 C8H6N4O3S
    7-methylsulfanyl-4-oxo-1,4-dihydro-pyrimido[4,5-<i>c</i>]pyridazine-3-carboxylic acid
    —— 1-chloro-10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazine 55271-64-2 C8H4ClN5S
    1-chloro-10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazine
    —— 1-Amyl-2-methyl-6,10-dithiaspiro[4.5]dec-1-en-3-one 91527-09-2 C14H22OS2
    1-Amyl-2-methyl-6,10-dithiaspiro[4.5]dec-1-en-3-one
    —— 1-(2-phenylsulfonylethyl)-2,3-diphenylthioindole 136506-30-4 C28H23NO2S3
    1-(2-phenylsulfonylethyl)-2,3-diphenylthioindole
    —— (1S,3aS,7aR)-3a-hydroxy-7a-methylspiro[1,2,3,4,6,7-hexahydroindene-5,2'-1,3-dithiane]-1-carbaldehyde 162240-25-7 C14H22O2S2
    (1S,3aS,7aR)-3a-hydroxy-7a-methylspiro[1,2,3,4,6,7-hexahydroindene-5,2'-1,3-dithiane]-1-carbaldehyde
    —— 4-chloro-10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazine 55271-63-1 C8H4ClN5S
    4-chloro-10<i>H</i>-dipyridazino[4,5-<i>b</i>;4',5'-<i>e</i>][1,4]thiazine
    —— Di(2-propenyl) N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate] 82986-17-2 C14H16F6N4O4S3
    Di(2-propenyl) N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate]
    —— 3-(3,6-dichloro-pyridazin-4-ylsulfanyl)-pyridazin-4-ylamine 55271-67-5 C8H5Cl2N5S
    3-(3,6-dichloro-pyridazin-4-ylsulfanyl)-pyridazin-4-ylamine
    —— 2-[2-(4-chlorophenylsulfanyl)prop-1-enyl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide 1000809-05-1 C14H18ClO3PS
    2-[2-(4-chlorophenylsulfanyl)prop-1-enyl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide
    —— 10H-8-chloro-7-methyl-3-nitropyrido[3,2-b][1,4]benzothiazine 191922-78-8 C12H8ClN3O2S
    10H-8-chloro-7-methyl-3-nitropyrido[3,2-b][1,4]benzothiazine
    —— 4-phenylsulfanyltricyclo[6.2.1.02,7]undec-9-ene-3,6-dione 97424-38-9 C17H16O2S
    4-phenylsulfanyltricyclo[6.2.1.02,7]undec-9-ene-3,6-dione
    —— ethyl 2-(4,6-bis(3-phenylpropoxy)pyrimidin-2-ylthio)hexanoate 1231733-93-9 C30H38N2O4S
    ethyl 2-(4,6-bis(3-phenylpropoxy)pyrimidin-2-ylthio)hexanoate
    —— 3,3-dimethyl-1-phenylthio-2-trimethylsiloxy-1-butene 83467-59-8 C15H24OSSi
    3,3-dimethyl-1-phenylthio-2-trimethylsiloxy-1-butene
    —— 1-Phenylsulfanylcyclohexanecarboxylic acid 101329-86-6 C13H16O2S
    1-Phenylsulfanylcyclohexanecarboxylic acid
    —— 5-Chloropentylsulfanylcyclohexane 115412-65-2 C11H21ClS
    5-Chloropentylsulfanylcyclohexane
    —— 1-Tert-butylsulfanyl-5-chloropentane 115412-64-1 C9H19ClS
    1-Tert-butylsulfanyl-5-chloropentane
    —— 1-chloro-6-ethylthiopentane 115412-61-8 C7H15ClS
    1-chloro-6-ethylthiopentane
    —— 1-Chloro-5-propylsulfanylpentane 115412-62-9 C8H17ClS
    1-Chloro-5-propylsulfanylpentane