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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1,3-Dithian-2-yliden)(phenylthio)acetonitril 139427-34-2 C12H11NS3
    (1,3-Dithian-2-yliden)(phenylthio)acetonitril
    —— 4-amino-5-(2-hydroxy-4,4-dimethyl-6-oxocyclohexenylmethyl)-1-methyl-2-(methylsulfanyl)pyrimidin-6(1H)-one 709036-74-8 C15H21N3O3S
    4-amino-5-(2-hydroxy-4,4-dimethyl-6-oxocyclohexenylmethyl)-1-methyl-2-(methylsulfanyl)pyrimidin-6(1H)-one
    —— 1-phenyl-2-(phenylthio)-3-(trimethylsilyl)propan-1-ol 61829-47-8 C18H24OSSi
    1-phenyl-2-(phenylthio)-3-(trimethylsilyl)propan-1-ol
    —— 1-Tert-butylsulfanyl-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene 1254322-48-9 C14H26S
    1-Tert-butylsulfanyl-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene
    —— 5-(dimethylaminosulfonylmethyl)-3-methylthio-1,2,4-triazine 114468-15-4 C7H12N4O2S2
    5-(dimethylaminosulfonylmethyl)-3-methylthio-1,2,4-triazine
    —— 6-Phenyl-1-phenylsulfanyl-hexan-3-one 83022-88-2 C18H20OS
    6-Phenyl-1-phenylsulfanyl-hexan-3-one
    —— 7-Methyl-1,4,10,13-tetrathia-7-phospha-dispiro[4.3.4.4]heptadecane 7-oxide 75401-30-8 C13H23OPS4
    7-Methyl-1,4,10,13-tetrathia-7-phospha-dispiro[4.3.4.4]heptadecane 7-oxide
    —— methyl 3-buten-1-yl sulfoxide 121564-26-9 C5H10OS
    methyl 3-buten-1-yl sulfoxide
    —— ethyl 3-phenyl-2-(phenylthio)-2-(trifluoromethyl)-4-pentenoate —— C20H19F3O2S
    ethyl 3-phenyl-2-(phenylthio)-2-(trifluoromethyl)-4-pentenoate
    —— 4-Tert-butylsulfanyl-1,2,3,3a,4,5,6,7,8,8a-decahydroazulene 1254322-47-8 C14H26S
    4-Tert-butylsulfanyl-1,2,3,3a,4,5,6,7,8,8a-decahydroazulene
    —— 2-(phenylthio)-3-(trimethysilyl)propionaldehyde 61829-52-5 C12H18OSSi
    2-(phenylthio)-3-(trimethysilyl)propionaldehyde
    —— 1-Cyclohexyl-3-<3-dimethylamino-propyl>-thioharnstoff 91689-64-4 C12H25N3S
    1-Cyclohexyl-3-<3-dimethylamino-propyl>-thioharnstoff
    —— Benzylmethylaminomethyl-phenylsulfid 51643-81-3 C15H17NS
    Benzylmethylaminomethyl-phenylsulfid
    —— 3-tert-Butylsulfanyl-6-methoxy-pyridazine 85591-49-7 C9H14N2OS
    3-tert-Butylsulfanyl-6-methoxy-pyridazine
    —— N-((2-(methylsulfanyl)phenyl)methylidene)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide 1402599-44-3 C17H17NO4S2
    N-((2-(methylsulfanyl)phenyl)methylidene)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide
    —— 1-(Phenylthio)-3-oxabicyclo[3.1.0]hexan-2-ol 80398-85-2 C11H12O2S
    1-(Phenylthio)-3-oxabicyclo[3.1.0]hexan-2-ol
    —— 2-methylsulfanyl-5-[[3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]phenyl]methylsulfanyl]-1,3,4-thiadiazole 82493-80-9 C14H14N4S6
    2-methylsulfanyl-5-[[3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]phenyl]methylsulfanyl]-1,3,4-thiadiazole
    —— trans-di(but-2-enyl)disulfide 83688-99-7 C8H14S2
    trans-di(but-2-enyl)disulfide
    —— ((1′S,7a′R)-7a′-methyl-1′,2′,3′,6′,7′,7a′-hexahydrospiro[[1,3]dithiolane-2,5′-inden]-1′-yl)methanol 150930-69-1 C14H22OS2
    ((1′S,7a′R)-7a′-methyl-1′,2′,3′,6′,7′,7a′-hexahydrospiro[[1,3]dithiolane-2,5′-inden]-1′-yl)methanol
    —— 5-<(4-methoxyphenyl)thio>-1H-1,2,3-triazole-4-carboxylic acid 81581-13-7 C10H9N3O3S
    5-<(4-methoxyphenyl)thio>-1H-1,2,3-triazole-4-carboxylic acid
    —— 7-Chloro-benzo[1,4,2]dithiazine 82946-26-7 C7H4ClNS2
    7-Chloro-benzo[1,4,2]dithiazine
    —— 1-(1-Methyl-5-phenylsulfanyl-1H-[1,2,3]triazol-4-yl)-ethanone 194209-28-4 C11H11N3OS
    1-(1-Methyl-5-phenylsulfanyl-1H-[1,2,3]triazol-4-yl)-ethanone
    —— thioindigo 3583-39-9 C16H8O2S2
    thioindigo
    —— N-[6-(pyridin-4-ylthio)-5-indanyl]methanesulfonamide 75360-62-2 C15H16N2O2S2
    N-[6-(pyridin-4-ylthio)-5-indanyl]methanesulfonamide
    —— cis-6-chloro-2,3-dihydro-2-(1H-imidazol-1-ylmethyl)benzo<b>thiophene-3-ol 83449-54-1 C12H11ClN2OS
    cis-6-chloro-2,3-dihydro-2-(1H-imidazol-1-ylmethyl)benzo<b>thiophene-3-ol
    —— 2-(2-Pentyl-1,3-dithian-2-yl)acetaldehyde 38293-03-7 C11H20OS2
    2-(2-Pentyl-1,3-dithian-2-yl)acetaldehyde
    —— 2-chloro-4-aminophenyl phenethyl sulfide hydrochloride 80019-85-8 C14H14ClNS*ClH
    2-chloro-4-aminophenyl phenethyl sulfide hydrochloride
    —— 1-(2-Methyl-1,3-dithian-2-yl)butan-1-one 121829-97-8 C9H16OS2
    1-(2-Methyl-1,3-dithian-2-yl)butan-1-one
    —— 2-chloro-3-(2-methyl-1,3-dithian-2-yl)pyrazine 1131041-56-9 C9H11ClN2S2
    2-chloro-3-(2-methyl-1,3-dithian-2-yl)pyrazine
    —— 2-methyl-2-(3'-methacrylate of propyl-1')-1,3-dithiane 211873-56-2 C12H20O2S2
    2-methyl-2-(3'-methacrylate of propyl-1')-1,3-dithiane
    —— syn-2-methyl-2-crotyl-1,3-dithiane 1-oxide 128062-26-0 C9H14O2S2
    syn-2-methyl-2-crotyl-1,3-dithiane 1-oxide
    —— (+/-)-2-(S)-propanoyl-2-methyl-1,3-dithiane 1-(R)-oxide 124004-42-8 C8H14O2S2
    (+/-)-2-(S)-propanoyl-2-methyl-1,3-dithiane 1-(R)-oxide
    —— 1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-4-ylethanol 936231-51-5 C12H17NOS2
    1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-4-ylethanol
    —— (2R)-1-[2-[(2S)-2-[tert-butyl(dimethyl)silyl]oxy-3-(2-methyl-1,3-dithian-2-yl)propyl]-1,3-dithian-2-yl]pent-4-en-2-ol 1431375-84-6 C23H44O2S4Si
    (2R)-1-[2-[(2S)-2-[tert-butyl(dimethyl)silyl]oxy-3-(2-methyl-1,3-dithian-2-yl)propyl]-1,3-dithian-2-yl]pent-4-en-2-ol
    —— trimethyl-[(1S,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane 1217293-22-5 C14H22OSSi
    trimethyl-[(1S,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane
    —— 6,6-Dimethyl-8-phenyl-7-oxa-1,4-dithia-spiro[4.4]non-8-ene 82448-31-5 C14H16OS2
    6,6-Dimethyl-8-phenyl-7-oxa-1,4-dithia-spiro[4.4]non-8-ene
    —— (2S)-1-[2-[tert-butyl(dimethyl)silyl]-1,3-dithian-2-yl]-3-(2-methyl-1,3-dithian-2-yl)propan-2-ol 875208-34-7 C18H36OS4Si
    (2S)-1-[2-[tert-butyl(dimethyl)silyl]-1,3-dithian-2-yl]-3-(2-methyl-1,3-dithian-2-yl)propan-2-ol
    —— 2-(((4-chlorophenyl)thio)methyl)pyridine, hydrochloride 81851-02-7 C12H10ClNS*ClH
    2-(((4-chlorophenyl)thio)methyl)pyridine, hydrochloride
    —— trimethyl-[(1R,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane 1217293-21-4 C14H22OSSi
    trimethyl-[(1R,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane
    —— 1-(3-Ethylphenyl)-1-(2-methyl-1,3-dithian-2-yl)ethanol 936231-65-1 C15H22OS2
    1-(3-Ethylphenyl)-1-(2-methyl-1,3-dithian-2-yl)ethanol
    —— 1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-3-ylethanol 936231-50-4 C12H17NOS2
    1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-3-ylethanol
    —— trimethyl-[(1S)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane 1217293-20-3 C13H20OSSi
    trimethyl-[(1S)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane
    —— 2-(2-Methyl-1,3-dithian-2-yl)butan-2-ol 936231-46-8 C9H18OS2
    2-(2-Methyl-1,3-dithian-2-yl)butan-2-ol
    —— trimethyl-[(1R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane 1217293-19-0 C13H20OSSi
    trimethyl-[(1R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane
    —— (Z)-methyl 2-phenylthiohex-2-enoate 86895-74-1 C13H16O2S
    (Z)-methyl 2-phenylthiohex-2-enoate
    —— 2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclohexan-1-one 81556-01-6 C14H14N2O2S
    2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclohexan-1-one
    —— 1-(Cyclopenten-1-yl)-1-(2-methyl-1,3-dithian-2-yl)ethanol 936231-49-1 C12H20OS2
    1-(Cyclopenten-1-yl)-1-(2-methyl-1,3-dithian-2-yl)ethanol
    —— tert-butyl-dimethyl-[(2R)-1-(2-methyl-1,3-dithian-2-yl)-3-[2-[(R)-(2-prop-2-enylphenyl)-trimethylsilyloxymethyl]-1,3-dithian-2-yl]propan-2-yl]oxysilane 1073174-90-9 C31H54O2S4Si2
    tert-butyl-dimethyl-[(2R)-1-(2-methyl-1,3-dithian-2-yl)-3-[2-[(R)-(2-prop-2-enylphenyl)-trimethylsilyloxymethyl]-1,3-dithian-2-yl]propan-2-yl]oxysilane
    —— 2-(1-hydroxybutyl)-2-methyl-1,3-dithiane 74637-04-0 C9H18OS2
    2-(1-hydroxybutyl)-2-methyl-1,3-dithiane
    —— (3aR,7aR)-N-[(R)-(2-methyl-1,3-dithian-2-yl)-phenylmethyl]-2-oxo-1,3-di(propan-2-yl)-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazaphosphol-2-amine 1281867-98-8 C24H40N3OPS2
    (3aR,7aR)-N-[(R)-(2-methyl-1,3-dithian-2-yl)-phenylmethyl]-2-oxo-1,3-di(propan-2-yl)-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazaphosphol-2-amine