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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (4,6-dimethyl-2-pyrimidinylsulfanylmethyl)acetate 54820-00-7 C9H12N2O2S
    methyl (4,6-dimethyl-2-pyrimidinylsulfanylmethyl)acetate
    —— 3-methanesulfinyl-5-methylsulfanyl-isothiazole-4-carbonitrile 25882-60-4 C6H6N2OS3
    3-methanesulfinyl-5-methylsulfanyl-isothiazole-4-carbonitrile
    —— 2-hydrazino-7-methyl-4H-pyrazolo[5,4-e]-1,3,4-thiadiazine 316188-73-5 C5H8N6S
    2-hydrazino-7-methyl-4H-pyrazolo[5,4-e]-1,3,4-thiadiazine
    —— (E)-phenyl(3,3,3-trifluoroprop-1-en-1-yl)sulfane 102687-66-1 C9H7F3S
    (E)-phenyl(3,3,3-trifluoroprop-1-en-1-yl)sulfane
    —— Methyl 2-(6-methyl-2-morpholin-4-ylpyrimidin-4-yl)sulfanylacetate 347343-81-1 C12H17N3O3S
    Methyl 2-(6-methyl-2-morpholin-4-ylpyrimidin-4-yl)sulfanylacetate
    —— 4-Isothiazolecarbonitrile, 5-((cyanomethyl)thio)-3-(methylthio)- 72436-95-4 C7H5N3S3
    4-Isothiazolecarbonitrile, 5-((cyanomethyl)thio)-3-(methylthio)-
    —— N-cyclohexanoylthiourea 1428451-09-5 C8H14N2OS
    N-cyclohexanoylthiourea
    —— 3-chloro-5-methylsulfanyl-isothiazole-4-carbonitrile 3889-65-4 C5H3ClN2S2
    3-chloro-5-methylsulfanyl-isothiazole-4-carbonitrile
    —— 1-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)carbothiohydrazide 135885-30-2 C4H8N6S2
    1-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)carbothiohydrazide
    —— 1-bromo-1-(ethylsulfonyl)ethane 6668-12-8 C4H9BrO2S
    1-bromo-1-(ethylsulfonyl)ethane
    —— β,β,β-Trichloroethyl S-3,6-Diisopropylpyrazin-2-ylthiolcarbonate 107292-16-0 C13H17Cl3N2O2S
    β,β,β-Trichloroethyl S-3,6-Diisopropylpyrazin-2-ylthiolcarbonate
    —— phenyl dithio-2-furoate 59014-94-7 C11H8OS2
    phenyl dithio-2-furoate
    —— 3-ethanesulfonyl-butan-2-one 800374-25-8 C6H12O3S
    3-ethanesulfonyl-butan-2-one
    —— 2-oxo-1-oxa-4-thiaspiro <4.4> nonan-3-ylacetic acid 134767-82-1 C9H12O4S
    2-oxo-1-oxa-4-thiaspiro <4.4> nonan-3-ylacetic acid
    —— 1-Phenylsulfanyl-3-(2,2,2-trichloroethoxy)propan-2-ol 115413-14-4 C11H13Cl3O2S
    1-Phenylsulfanyl-3-(2,2,2-trichloroethoxy)propan-2-ol
    —— <Ethylthio(thiocarbonyloxy)>essigsaeure 96594-23-9 C5H8O3S2
    <Ethylthio(thiocarbonyloxy)>essigsaeure
    —— 2-{4-[(Difluoromethyl)sulfanyl]phenyl}-5-propylpyrimidine 139030-66-3 C14H14F2N2S
    2-{4-[(Difluoromethyl)sulfanyl]phenyl}-5-propylpyrimidine
    —— (E)-9-methyl-1,5-dithiacyclonon-8-ene 144227-17-8 C8H14S2
    (E)-9-methyl-1,5-dithiacyclonon-8-ene
    —— <i>N</i>-fluorosulfonyl-<i>S</i>,<i>S</i>-dimethyl-sulfimide 19445-05-7 C2H6FNO2S2
    <i>N</i>-fluorosulfonyl-<i>S</i>,<i>S</i>-dimethyl-sulfimide
    —— Bicyclo<3.1.1>hept-1-yl-phenylthioether 142133-77-5 C13H16S
    Bicyclo<3.1.1>hept-1-yl-phenylthioether
    —— 1,1,3-trimethyl-3-(2-(1,3,3-trimethylthioureido)ethyl)thiourea 202073-21-0 C10H22N4S2
    1,1,3-trimethyl-3-(2-(1,3,3-trimethylthioureido)ethyl)thiourea
    —— (ethylthio)propoxymethane 88071-13-0 C6H14OS
    (ethylthio)propoxymethane
    —— 1-octylthiocyclohexene 4922-46-7 C14H26S
    1-octylthiocyclohexene
    —— S-ethyl O-(ethoxycarbonylmethyl) dithiocarbonate 153648-57-8 C7H12O3S2
    S-ethyl O-(ethoxycarbonylmethyl) dithiocarbonate
    —— thiocarbamoyloxy-acetic acid 861535-94-6 C3H5NO3S
    thiocarbamoyloxy-acetic acid
    —— 3-(3-(dodecylsulfonyl)propyl)-6-tert-butyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 133949-92-5 C23H42N4O2S2
    3-(3-(dodecylsulfonyl)propyl)-6-tert-butyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— p-tolyl benzodithioate 20876-81-7 C14H12S2
    p-tolyl benzodithioate
    —— 2-[(4-tert-butyl-1H-imidazol-2-yl)thio]acetamide 623547-73-9 C9H15N3OS
    2-[(4-tert-butyl-1H-imidazol-2-yl)thio]acetamide
    —— 6-(ethylthio)-1-hexanol 83705-78-6 C8H18OS
    6-(ethylthio)-1-hexanol
    —— 5,6-Difluoro-2-phenylsulfanyl-benzoimidazole-1-sulfonic acid dimethylamide 862180-00-5 C15H13F2N3O2S2
    5,6-Difluoro-2-phenylsulfanyl-benzoimidazole-1-sulfonic acid dimethylamide
    —— 5-cyano-5-isopropylsulphonylnorborn-2-ene 102329-70-4 C11H15NO2S
    5-cyano-5-isopropylsulphonylnorborn-2-ene
    —— 2,2'-thiobis<4-t-butylphenol> 3273-24-3 C20H26O2S
    2,2'-thiobis<4-t-butylphenol>
    —— 10-Methyl-10H-9-thia-10-sila-anthracene 76216-74-5 C13H12SSi
    10-Methyl-10H-9-thia-10-sila-anthracene
    —— 4,11-Dihydro-1-oxa-10-thia-4-aza-benzo[a]cyclopenta[e]cycloocten-5-one 139308-27-3 C12H9NO2S
    4,11-Dihydro-1-oxa-10-thia-4-aza-benzo[a]cyclopenta[e]cycloocten-5-one
    —— 6-(4,6-Dimethylpyrimidin-2-ylthio)hexan-1-ol 112641-04-0 C12H20N2OS
    6-(4,6-Dimethylpyrimidin-2-ylthio)hexan-1-ol
    —— 1-methanesulfinyl-1-methylsulfanyl-propene 51534-65-7 C5H10OS2
    1-methanesulfinyl-1-methylsulfanyl-propene
    —— 4,5-Dimethyl-2-methylmercapto-pyrimidin 17759-43-2 C7H10N2S
    4,5-Dimethyl-2-methylmercapto-pyrimidin
    —— (4-methoxyphenyl)(2-(trifluoromethyl)phenyl)sulfane 1190852-22-2 C14H11F3OS
    (4-methoxyphenyl)(2-(trifluoromethyl)phenyl)sulfane
    —— 4H,8H-2,3,6,7,4',5',4'',5''-octa(methoxycarbonyl)thiopyrano<3,2-b>thiopyran-4-spiro-2'-1',3'-dithiole-8-spiro-2''-1'',3''-dithiole 160593-44-2 C28H24O16S6
    4H,8H-2,3,6,7,4',5',4'',5''-octa(methoxycarbonyl)thiopyrano<3,2-b>thiopyran-4-spiro-2'-1',3'-dithiole-8-spiro-2''-1'',3''-dithiole
    —— 5-(bromomethyl)-4-methyl-2-(methylthio)pyrimidine 135645-54-4 C7H9BrN2S
    5-(bromomethyl)-4-methyl-2-(methylthio)pyrimidine
    —— 1-(1-hydroxycycloheptyl)-2-(p-tolylthio)-1-ethanone 134858-00-7 C16H22O2S
    1-(1-hydroxycycloheptyl)-2-(p-tolylthio)-1-ethanone
    —— 3,3-dimethylenedithio-5-(tetrahydropyranyl)oxypentanol 136400-73-2 C12H22O3S2
    3,3-dimethylenedithio-5-(tetrahydropyranyl)oxypentanol
    —— 3-Acetoxy-4-methyl-1-phenylthio-2-pentanon 69798-61-4 C14H18O3S
    3-Acetoxy-4-methyl-1-phenylthio-2-pentanon
    —— Dimethyl (2-benzyl-3-methylthio-2H-1,2,4-triazol-5-yl)iminodithiocarbonate 132395-59-6 C13H16N4S3
    Dimethyl (2-benzyl-3-methylthio-2H-1,2,4-triazol-5-yl)iminodithiocarbonate
    —— Dimethyl (1-benzyl-3-methylthio-1H-1,2,4-triazol-5-yl)iminodithiocarbonate 132395-51-8 C13H16N4S3
    Dimethyl (1-benzyl-3-methylthio-1H-1,2,4-triazol-5-yl)iminodithiocarbonate
    —— 4-(Bromomethyl)-5-methyl-2-(methylthio)pyrimidine 135645-55-5 C7H9BrN2S
    4-(Bromomethyl)-5-methyl-2-(methylthio)pyrimidine
    —— 4-[3-(4-Amino-phenyl sulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile 278183-71-4 C18H18N2OS
    4-[3-(4-Amino-phenyl sulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile
    —— 3-methyl-2-i-propyl-2-(phenylthio)acetic acid 140400-38-0 C12H16O2S
    3-methyl-2-i-propyl-2-(phenylthio)acetic acid
    —— 2-(2-(trifluoromethyl)phenylthio)-5-methylphenol 1254831-67-8 C14H11F3OS
    2-(2-(trifluoromethyl)phenylthio)-5-methylphenol
    —— 4-(tert-butyl)phenyl 2-trifluoromethylphenyl sulfide 1350928-11-8 C17H17F3S
    4-(tert-butyl)phenyl 2-trifluoromethylphenyl sulfide