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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3-bromophenylthio)pyridine-3-ol 263390-44-9 C11H8BrNOS
    2-(3-bromophenylthio)pyridine-3-ol
    —— 2,2-Dimethyl-[1,3]dithiole 128827-89-4 C5H8S2
    2,2-Dimethyl-[1,3]dithiole
    —— Dicyclopentyl-trithiocarbonat 1135-28-0 C11H18S3
    Dicyclopentyl-trithiocarbonat
    —— 5-oxo-6-(phenylthio)hexanol 173310-47-9 C12H16O2S
    5-oxo-6-(phenylthio)hexanol
    —— 2-(Methylsulfanyl)-5-(trichloromethyl)-1,3,4-thiadiazole 65439-49-8 C4H3Cl3N2S2
    2-(Methylsulfanyl)-5-(trichloromethyl)-1,3,4-thiadiazole
    —— dichloroanhydride of 2-chloro-2-phenyl-1-phenylthioethylphosphonic acid 88691-28-5 C14H12Cl3OPS
    dichloroanhydride of 2-chloro-2-phenyl-1-phenylthioethylphosphonic acid
    —— 5-(phenylthio)pentanoic acid 17742-53-9 C11H14O2S
    5-(phenylthio)pentanoic acid
    —— 2-diazomethanesulfonyl-2-methyl-propane 1538-99-4 C5H10N2O2S
    2-diazomethanesulfonyl-2-methyl-propane
    —— 5-Cyclopentylsulfanylpyrimidine 1240790-13-9 C9H12N2S
    5-Cyclopentylsulfanylpyrimidine
    —— 2,3-Dimethoxy-3-methyl-2,3-dihydro-1-benzothiophene 68452-02-8 C11H14O2S
    2,3-Dimethoxy-3-methyl-2,3-dihydro-1-benzothiophene
    —— 2-methyl-4-(2-(2-(2-methoxyethoxy)ethoxy)ethylsulfonyl)butan-2-amine 1373433-49-8 C12H27NO5S
    2-methyl-4-(2-(2-(2-methoxyethoxy)ethoxy)ethylsulfonyl)butan-2-amine
    —— N,N-dichloro-2-methyl-4-(2-(2-(2-methoxyethoxy)ethoxy)ethylsulfonyl)butan-2-amine 1373433-44-3 C12H25Cl2NO5S
    N,N-dichloro-2-methyl-4-(2-(2-(2-methoxyethoxy)ethoxy)ethylsulfonyl)butan-2-amine
    —— methyl [3-(cyclopentylthio)phenyl]acetate 851859-76-2 C14H18O2S
    methyl [3-(cyclopentylthio)phenyl]acetate
    —— 4,5-dihydro-5-propyl-4-oxo-4H-thieno[2,3-b]thiophene 133209-69-5 C9H10OS2
    4,5-dihydro-5-propyl-4-oxo-4H-thieno[2,3-b]thiophene
    —— S-(4-dimethylaminophenyl)-N,N-dimethylthiocarbamate 13512-02-2 C11H16N2OS
    S-(4-dimethylaminophenyl)-N,N-dimethylthiocarbamate
    —— 2-cyclopentylthio-6-(2,6-difluorophenylmethyl)-3,4-dihydrogyrimidin-4-(3H)-one 221122-06-1 C16H16F2N2OS
    2-cyclopentylthio-6-(2,6-difluorophenylmethyl)-3,4-dihydrogyrimidin-4-(3H)-one
    —— N-(3-phenylsulfanylpropyl)aniline 57342-58-2 C15H17NS
    N-(3-phenylsulfanylpropyl)aniline
    —— 2-propionylamino-5-(4-aminophenylthio)thiazole 133691-57-3 C12H13N3OS2
    2-propionylamino-5-(4-aminophenylthio)thiazole
    —— 2-amino-5-(4-acetylaminophenylthio)thiazole 133691-82-4 C11H11N3OS2
    2-amino-5-(4-acetylaminophenylthio)thiazole
    —— (1-formyl-propyl)-dimethyl-sulfonium betaine 367926-59-8 C6H12OS
    (1-formyl-propyl)-dimethyl-sulfonium betaine
    —— (2,4-dimethylphenyl)(4-methoxyphenyl)sulfane 1420042-86-9 C15H16OS
    (2,4-dimethylphenyl)(4-methoxyphenyl)sulfane
    —— α-(phenylthio)butanal 35874-97-6 C10H12OS
    α-(phenylthio)butanal
    —— 4,5-dihydro-4H-5-(2-methoxyethyl)-5-methyl-4-oxothieno[2,3-b]thiophene 133209-70-8 C10H12O2S2
    4,5-dihydro-4H-5-(2-methoxyethyl)-5-methyl-4-oxothieno[2,3-b]thiophene
    —— 2-acetylamino-5-(3-hydroxypyridin-2-ylthio)thiazole 133691-97-1 C10H9N3O2S2
    2-acetylamino-5-(3-hydroxypyridin-2-ylthio)thiazole
    —— 2-acetylamino-5-(pyridin-3-ylthio)thiazole 133692-00-9 C10H9N3OS2
    2-acetylamino-5-(pyridin-3-ylthio)thiazole
    —— 2-(3-bromo-thien-2-ylthio)-N-methyl-N-methoxy-valeramide 133209-59-3 C11H16BrNO2S2
    2-(3-bromo-thien-2-ylthio)-N-methyl-N-methoxy-valeramide
    —— methyl 2-((4-hydroxyphenyl)thio)-2-methylpropanoate 566189-18-2 C11H14O3S
    methyl 2-((4-hydroxyphenyl)thio)-2-methylpropanoate
    —— 2-amino-5-(2-imidazolylthio)thiazole 133691-96-0 C6H6N4S2
    2-amino-5-(2-imidazolylthio)thiazole
    —— methyl 2-(3-hydroxyphenylthio)isobutyrate 566189-20-6 C11H14O3S
    methyl 2-(3-hydroxyphenylthio)isobutyrate
    —— Methyl 2-[(3-aminophenyl)sulfanyl]-2-methylpropanoate 1191413-24-7 C11H15NO2S
    Methyl 2-[(3-aminophenyl)sulfanyl]-2-methylpropanoate
    —— 6-Benzyl-5-chloro-1-[(4-methoxyphenyl)methyl]-3-phenylsulfanylpyrazin-2-one 1015098-10-8 C25H21ClN2O2S
    6-Benzyl-5-chloro-1-[(4-methoxyphenyl)methyl]-3-phenylsulfanylpyrazin-2-one
    —— 2-(3-bromo-thien-2-ylthio)-4-methoxy-2-methyl-N-methoxy-N-methyl butyramide 133209-60-6 C12H18BrNO3S2
    2-(3-bromo-thien-2-ylthio)-4-methoxy-2-methyl-N-methoxy-N-methyl butyramide
    —— Ethanamine, 2,2a(2)-dithiobis[N-ethyl- 4432-79-5 C8H20N2S2
    Ethanamine, 2,2a(2)-dithiobis[N-ethyl-
    —— 5-Chloro-6-(4-methoxyphenyl)-1-[(4-methoxyphenyl)methyl]-3-phenylsulfanylpyrazin-2-one 1015098-09-5 C25H21ClN2O3S
    5-Chloro-6-(4-methoxyphenyl)-1-[(4-methoxyphenyl)methyl]-3-phenylsulfanylpyrazin-2-one
    —— 2-(4-methylsulfonylphenylthio)phenylacetic acid 16185-17-4 C15H14O4S2
    2-(4-methylsulfonylphenylthio)phenylacetic acid
    —— 5,5'-(propane-1,3-diyldisulfanediyl)bis(1,3,4-thiadiazol-2-amine) 98335-62-7 C7H10N6S4
    5,5'-(propane-1,3-diyldisulfanediyl)bis(1,3,4-thiadiazol-2-amine)
    —— 2-((3-bromopropyl)thio)thiophene 934536-26-2 C7H9BrS2
    2-((3-bromopropyl)thio)thiophene
    —— (3-bromopropyl)(2-chlorophenyl)sulfane 349671-89-2 C9H10BrClS
    (3-bromopropyl)(2-chlorophenyl)sulfane
    —— N,N'-Bis(dimethylphosphino)-S,S-diethylsulfodiimid 66435-87-8 C8H22N2P2S
    N,N'-Bis(dimethylphosphino)-S,S-diethylsulfodiimid
    —— allyl-thiocarbamic acid <i>S</i>-ethyl ester 39078-66-5 C6H11NOS
    allyl-thiocarbamic acid <i>S</i>-ethyl ester
    —— N,N'-Bis(dimethylphosphino)-S,S-dimethylsulfodiimid 35390-99-9 C6H18N2P2S
    N,N'-Bis(dimethylphosphino)-S,S-dimethylsulfodiimid
    —— S-Ethyl methyl(2-methylprop-2-en-1-yl)carbamothioate 67189-62-2 C8H15NOS
    S-Ethyl methyl(2-methylprop-2-en-1-yl)carbamothioate
    —— 3-bromophenyl-(3-bromopropyl)sulfide 1338795-86-0 C9H10Br2S
    3-bromophenyl-(3-bromopropyl)sulfide
    —— S-ethyl 2,2-dinitropropyl thiolcarbonate 71674-17-4 C6H10N2O6S
    S-ethyl 2,2-dinitropropyl thiolcarbonate
    —— 2,2'-(propane-1,3-diylbis(sulfanediyl))bis(4,6-dimethylnicotinonitrile) 532964-77-5 C19H20N4S2
    2,2'-(propane-1,3-diylbis(sulfanediyl))bis(4,6-dimethylnicotinonitrile)
    —— t-butoxy-S-ethyl thiocarbonate 35363-45-2 C7H14O2S
    t-butoxy-S-ethyl thiocarbonate
    —— prop-2-ynyl-propyl-thiocarbamic acid <i>S</i>-ethyl ester 59300-32-2 C9H15NOS
    prop-2-ynyl-propyl-thiocarbamic acid <i>S</i>-ethyl ester
    —— 2,2,2-Trichloroethyl ethylsulfanylformate 71674-20-9 C5H7Cl3O2S
    2,2,2-Trichloroethyl ethylsulfanylformate
    —— ethyl-propyl-thiocarbamic acid <i>S</i>-ethyl ester 88461-36-3 C8H17NOS
    ethyl-propyl-thiocarbamic acid <i>S</i>-ethyl ester
    —— S-ethyl 2-(trimethylsilyl)ethyl thiocarbonate 154876-19-4 C8H18O2SSi
    S-ethyl 2-(trimethylsilyl)ethyl thiocarbonate