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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(phenethylthio)phenol 57401-02-2 C14H14OS
    4-(phenethylthio)phenol
    —— cyclohexyl [4-(hydroxyphenyl)sulfanyl]acetic acid 287392-99-8 C14H18O3S
    cyclohexyl [4-(hydroxyphenyl)sulfanyl]acetic acid
    —— ethyl isopropyl [4-(hydroxyphenyl)sulfanyl]acetate 287393-36-6 C13H18O3S
    ethyl isopropyl [4-(hydroxyphenyl)sulfanyl]acetate
    —— 4-((3-methylbut-2-en-1-yl)thio)phenol 127164-87-8 C11H14OS
    4-((3-methylbut-2-en-1-yl)thio)phenol
    —— 2-acetylamino-5-(4-hydroxyphenylthio)thiazole 133691-83-5 C11H10N2O2S2
    2-acetylamino-5-(4-hydroxyphenylthio)thiazole
    —— 4-(3-amino-propylsulfanyl)-phenol 69409-63-8 C9H13NOS
    4-(3-amino-propylsulfanyl)-phenol
    —— Methyl 2-hydroxy-3-(4-hydroxyphenylthio)-3-[2-(8-phenyloctyl)phenyl]propionate 120427-83-0 C30H36O4S
    Methyl 2-hydroxy-3-(4-hydroxyphenylthio)-3-[2-(8-phenyloctyl)phenyl]propionate
    —— 6-[(3,5-Dimethylphenyl)thio]-5-ethyl-1-[4-(methoxy-carbonyl)butyl]uracil 279220-25-6 C20H26N2O4S
    6-[(3,5-Dimethylphenyl)thio]-5-ethyl-1-[4-(methoxy-carbonyl)butyl]uracil
    —— 1-(4-carboxybutyl)-6-[(3,5-dimethylphenyl)thio]-5-ethyluracil 279220-26-7 C19H24N2O4S
    1-(4-carboxybutyl)-6-[(3,5-dimethylphenyl)thio]-5-ethyluracil
    —— 5-ethyl-6-(3,5-dimethylphenyl)thio-2,4-pyrimidinedione 171048-61-6 C14H16N2O2S
    5-ethyl-6-(3,5-dimethylphenyl)thio-2,4-pyrimidinedione
    —— 3-cyano-1-(4-hydroxybenzenethio)-2-isopropylindolizine 154190-19-9 C18H16N2OS
    3-cyano-1-(4-hydroxybenzenethio)-2-isopropylindolizine
    —— tert-Butyl 3-(4'-Hydroxyphenyl)mercaptopivaloate 150493-04-2 C15H22O3S
    tert-Butyl 3-(4'-Hydroxyphenyl)mercaptopivaloate
    —— 6-(3-(4-hydroxyphenylsulfanyl)indol-1-yl)-1,3-dihydro-1-hydroxy-2,1-benzoxaborole 1309068-66-3 C21H16BNO3S
    6-(3-(4-hydroxyphenylsulfanyl)indol-1-yl)-1,3-dihydro-1-hydroxy-2,1-benzoxaborole
    —— 4-{[(1H-Pyrazol-1-yl)methyl]sulfanyl}phenol 80200-19-7 C10H10N2OS
    4-{[(1H-Pyrazol-1-yl)methyl]sulfanyl}phenol
    —— ethyl 4-[(4-hydroxyphenyl)sulfanyl]butanoate 868850-02-6 C12H16O3S
    ethyl 4-[(4-hydroxyphenyl)sulfanyl]butanoate
    —— 4-<(4-hydroxyphenyl)thio>butyronitrile 125439-47-6 C10H11NOS
    4-<(4-hydroxyphenyl)thio>butyronitrile
    —— 4-(4-aminophenylsulfamyl)phenol 100062-94-0 C12H11NOS
    4-(4-aminophenylsulfamyl)phenol
    —— 4-(1,4-dibenzyl-1H-imidazol-2-ylthio)phenol 1202223-34-4 C23H20N2OS
    4-(1,4-dibenzyl-1H-imidazol-2-ylthio)phenol
    —— 3-(4-hydroxyphenyl)-thio-furan-2-carboxaldehyde 877176-26-6 C11H8O3S
    3-(4-hydroxyphenyl)-thio-furan-2-carboxaldehyde
    —— 4-(1,4-bis(4-methoxybenzyl)-1H-imidazol-2-ylthio)phenol 1202223-26-4 C25H24N2O3S
    4-(1,4-bis(4-methoxybenzyl)-1H-imidazol-2-ylthio)phenol
    —— 4-(5-(4-(benzyloxy)benzyl)-4-(4-methoxybenzyl)-1-methyl-1H-imidazol-2-ylthio)phenol 1202223-51-5 C32H30N2O3S
    4-(5-(4-(benzyloxy)benzyl)-4-(4-methoxybenzyl)-1-methyl-1H-imidazol-2-ylthio)phenol
    —— (Z)-3-(4-hydroxy-phenylsulfanyl)-acrylic acid ethyl ester 1234562-78-7 C11H12O3S
    (Z)-3-(4-hydroxy-phenylsulfanyl)-acrylic acid ethyl ester
    —— 4-[[2-phenyl-(2-oxazolin-4-yl)]methylthio]phenol 104005-03-0 C16H15NO2S
    4-[[2-phenyl-(2-oxazolin-4-yl)]methylthio]phenol
    —— 4-(4,5-dibenzyl-1-methyl-1H-imidazol-2-ylthio)phenol 1202223-43-5 C24H22N2OS
    4-(4,5-dibenzyl-1-methyl-1H-imidazol-2-ylthio)phenol
    —— 6-chloro-3-[(4-hydroxyphenyl)thio]-N-(1-methyl-1H-pyrazol-3-yl)pyridine-2-carboxamide 1164103-36-9 C16H13ClN4O2S
    6-chloro-3-[(4-hydroxyphenyl)thio]-N-(1-methyl-1H-pyrazol-3-yl)pyridine-2-carboxamide
    —— 2-(4-hydroxyphenylsulfanyl)octanoic acid ethyl ester 287392-78-3 C16H24O3S
    2-(4-hydroxyphenylsulfanyl)octanoic acid ethyl ester
    —— methyl 2-(4-hydroxyphenylthio)propionate 347162-60-1 C10H12O3S
    methyl 2-(4-hydroxyphenylthio)propionate
    —— 4-((3-(methyl(phenyl)amino)propyl)thio)phenol 1452855-71-8 C16H19NOS
    4-((3-(methyl(phenyl)amino)propyl)thio)phenol
    —— 3-[(4-hydroxyphenyl)sulfanyl]propanoic acid 30512-65-3 C9H10O3S
    3-[(4-hydroxyphenyl)sulfanyl]propanoic acid
    —— S-(2-tetrahydropyranyl)-4-hydroxythiophenol 527758-63-0 C11H14O2S
    S-(2-tetrahydropyranyl)-4-hydroxythiophenol
    —— 2-(4-(2,2-bis(4-hydroxyphenylthio)ethoxy)phenylthio)pyridine 866249-08-3 C25H21NO3S3
    2-(4-(2,2-bis(4-hydroxyphenylthio)ethoxy)phenylthio)pyridine
    —— 5,5-dimethyl-3-(phenylthio)cyclohex-2-enone 52735-51-0 C14H16OS
    5,5-dimethyl-3-(phenylthio)cyclohex-2-enone
    —— 4-(2-amino-4-nitro-phenylsulfanyl)-phenol 943773-76-0 C12H10N2O3S
    4-(2-amino-4-nitro-phenylsulfanyl)-phenol
    —— 2-(4-((1,3-dioxolane-2-yl)methoxy)phenylthio)pyridine 866249-07-2 C15H15NO3S
    2-(4-((1,3-dioxolane-2-yl)methoxy)phenylthio)pyridine
    —— 4-(4-hydroxyphenylthio)benzonitrile 53279-54-2 C13H9NOS
    4-(4-hydroxyphenylthio)benzonitrile
    —— 6-[(4-hydroxyphenyl)thio]-2,4(1H,3H)-pyrimidinedione 607710-37-2 C10H8N2O3S
    6-[(4-hydroxyphenyl)thio]-2,4(1H,3H)-pyrimidinedione
    —— 4-((2-(ethyl(phenyl)amino)ethyl)thio)phenol 1452855-70-7 C16H19NOS
    4-((2-(ethyl(phenyl)amino)ethyl)thio)phenol
    —— 4-(3-amino-4-nitrophenylthio)phenol 60014-04-2 C12H10N2O3S
    4-(3-amino-4-nitrophenylthio)phenol
    —— 5-(4-hydroxy-phenylsulfanyl methyl)-2-oxo-2,3-dihydro-1H-imidazole-4-carboxylic acid methyl ester 849454-46-2 C12H12N2O4S
    5-(4-hydroxy-phenylsulfanyl methyl)-2-oxo-2,3-dihydro-1H-imidazole-4-carboxylic acid methyl ester
    —— diphenylthioacetate de methyle 84406-07-5 C15H14O2S2
    diphenylthioacetate de methyle
    —— tert-butyl (2-((4-hydroxyphenyl)thio)ethyl)carbamate 195516-69-9 C13H19NO3S
    tert-butyl (2-((4-hydroxyphenyl)thio)ethyl)carbamate
    —— 3-(4-hydroxyphenylthio)phthalonitrile 1499237-75-0 C14H8N2OS
    3-(4-hydroxyphenylthio)phthalonitrile
    —— (4-bromophenyl)(3-methylbut-2-en-1-yl)sulfane 127164-82-3 C11H13BrS
    (4-bromophenyl)(3-methylbut-2-en-1-yl)sulfane
    —— 4-(4-hydroxyphenylthio)phthalonitrile 1499237-78-3 C14H8N2OS
    4-(4-hydroxyphenylthio)phthalonitrile
    —— 4-(4-amino-2-nitro-phenylsulfanyl)-phenol 530135-26-3 C12H10N2O3S
    4-(4-amino-2-nitro-phenylsulfanyl)-phenol
    —— 2,4-bis[4-(4-hydroxyphenylsulphanyl)phenyl]-6-phenyl-1,3,5-triazine 1357015-56-5 C33H23N3O2S2
    2,4-bis[4-(4-hydroxyphenylsulphanyl)phenyl]-6-phenyl-1,3,5-triazine
    —— Methyl 4,5-dimethyl-1,3-dithiole-2-carboxylate 177798-61-7 C7H10O2S2
    Methyl 4,5-dimethyl-1,3-dithiole-2-carboxylate
    —— Dithiobuttersaeuremethylester 13831-08-8 C5H10S2
    Dithiobuttersaeuremethylester
    —— Methyl 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-carboxylate 161088-14-8 C7H8O2S4
    Methyl 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-carboxylate
    —— (5,6-dicyano-pyrazin-2-ylsulfanyl)-acetic acid 72112-02-8 C8H4N4O2S
    (5,6-dicyano-pyrazin-2-ylsulfanyl)-acetic acid